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  • Foreign imaging in Auger Spectroscopy: The Si 2p spectrum of silicon tetrafluoride.
    Physical review letters, 1993
    Co-Authors: Francesco Tarantelli, Lorenz S. Cederbaum
    Abstract:

    We performed Green's function calculations on the double ionization of SiF 4 in order to interpret its Si 2p Auger spectrum, which has caused controversy for a decade. We provide an accurate interpretation and a model of far wider generality in the Auger study of ionic species. Contrary to the usual self-imaging picture of Auger Spectroscopy, the silicon spectrum exhibits eight distinct bands reflecting a complete and precise image of the fluorine ligands, due to strong hole-localization effects. The generality of this foreign-imaging character of Auger Spectroscopy is discussed

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