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Santos Otin - One of the best experts on this subject based on the ideXlab platform.
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vapour liquid equilibrium at t 308 15 k for binary systems dibromomethane n heptane Bromotrichloromethane n heptane Bromotrichloromethane dibromomethane Bromotrichloromethane bromochloromethane and dibromomethane bromochloromethane experimental data
Fluid Phase Equilibria, 2015Co-Authors: Lourdes Martinezbanos, Jose Munoz Embid, Santos Otin, Manuela ArtalAbstract:Abstract In this paper, the isothermal vapour–liquid equilibrium (VLE) at T = 308.15 K have been measured for liquid binary systems dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane by a dynamic method. The VLE data have been reduced using the Redlich–Kister equation taking into consideration the vapour phase imperfection in terms of 2nd molar virial coefficients and molar excess Gibbs energies, G m E , have been calculated. The experimental G m E is positive for all systems presenting the greatest value for dibromomethane + n-heptane and a negligible value for dibromomethane + bromochloromethane system. From our experimental data and those reported in the literature, phase and volumetric behaviour of the binary systems containing dibromomethane, bromochloromethane, Bromotrichloromethane or n-heptane have been modelled. Two equations of state, EoS, of different formulation have been used obtaining a good agreement for all systems. The mean relative deviations for the studied properties are MRD (P) = 1.57%, AAD (y) = 0.0116 and MRD (ρ) = 0.55% for Peng–Robinson EoS, and MRD (P) = 1.20%, AAD (y) = 0.0093 and MRD (ρ) = 0.38% for PC-SAFT EoS.
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Vapour–liquid equilibrium at T = 308.15 K for binary systems: Dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane. E
Fluid Phase Equilibria, 2015Co-Authors: Lourdes Martínez-baños, Jose Munoz Embid, Santos Otin, Manuela ArtalAbstract:Abstract In this paper, the isothermal vapour–liquid equilibrium (VLE) at T = 308.15 K have been measured for liquid binary systems dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane by a dynamic method. The VLE data have been reduced using the Redlich–Kister equation taking into consideration the vapour phase imperfection in terms of 2nd molar virial coefficients and molar excess Gibbs energies, G m E , have been calculated. The experimental G m E is positive for all systems presenting the greatest value for dibromomethane + n-heptane and a negligible value for dibromomethane + bromochloromethane system. From our experimental data and those reported in the literature, phase and volumetric behaviour of the binary systems containing dibromomethane, bromochloromethane, Bromotrichloromethane or n-heptane have been modelled. Two equations of state, EoS, of different formulation have been used obtaining a good agreement for all systems. The mean relative deviations for the studied properties are MRD (P) = 1.57%, AAD (y) = 0.0116 and MRD (ρ) = 0.55% for Peng–Robinson EoS, and MRD (P) = 1.20%, AAD (y) = 0.0093 and MRD (ρ) = 0.38% for PC-SAFT EoS.
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Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martínez-baños, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochloromethane were measured over the entire range of composition in the temperature range from T = 293.15 K to T = 313.15 K. Excess molar volumes and deviation in isentropic compressibility have been calculated from experimental measurements and fitted to a Redlich–Kister equation to derive binary coefficients and the standard deviation.
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Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martínez-baños, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochlorometh...
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excess molar volumes and speed of sound in Bromotrichloromethane n heptane dibromomethane n heptane Bromotrichloromethane dibromomethane and Bromotrichloromethane bromochloromethane at temperatures from 293 15 to 313 15 k
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martinezbanos, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochlorometh...
Jose Munoz Embid - One of the best experts on this subject based on the ideXlab platform.
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vapour liquid equilibrium at t 308 15 k for binary systems dibromomethane n heptane Bromotrichloromethane n heptane Bromotrichloromethane dibromomethane Bromotrichloromethane bromochloromethane and dibromomethane bromochloromethane experimental data
Fluid Phase Equilibria, 2015Co-Authors: Lourdes Martinezbanos, Jose Munoz Embid, Santos Otin, Manuela ArtalAbstract:Abstract In this paper, the isothermal vapour–liquid equilibrium (VLE) at T = 308.15 K have been measured for liquid binary systems dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane by a dynamic method. The VLE data have been reduced using the Redlich–Kister equation taking into consideration the vapour phase imperfection in terms of 2nd molar virial coefficients and molar excess Gibbs energies, G m E , have been calculated. The experimental G m E is positive for all systems presenting the greatest value for dibromomethane + n-heptane and a negligible value for dibromomethane + bromochloromethane system. From our experimental data and those reported in the literature, phase and volumetric behaviour of the binary systems containing dibromomethane, bromochloromethane, Bromotrichloromethane or n-heptane have been modelled. Two equations of state, EoS, of different formulation have been used obtaining a good agreement for all systems. The mean relative deviations for the studied properties are MRD (P) = 1.57%, AAD (y) = 0.0116 and MRD (ρ) = 0.55% for Peng–Robinson EoS, and MRD (P) = 1.20%, AAD (y) = 0.0093 and MRD (ρ) = 0.38% for PC-SAFT EoS.
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Vapour–liquid equilibrium at T = 308.15 K for binary systems: Dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane. E
Fluid Phase Equilibria, 2015Co-Authors: Lourdes Martínez-baños, Jose Munoz Embid, Santos Otin, Manuela ArtalAbstract:Abstract In this paper, the isothermal vapour–liquid equilibrium (VLE) at T = 308.15 K have been measured for liquid binary systems dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane by a dynamic method. The VLE data have been reduced using the Redlich–Kister equation taking into consideration the vapour phase imperfection in terms of 2nd molar virial coefficients and molar excess Gibbs energies, G m E , have been calculated. The experimental G m E is positive for all systems presenting the greatest value for dibromomethane + n-heptane and a negligible value for dibromomethane + bromochloromethane system. From our experimental data and those reported in the literature, phase and volumetric behaviour of the binary systems containing dibromomethane, bromochloromethane, Bromotrichloromethane or n-heptane have been modelled. Two equations of state, EoS, of different formulation have been used obtaining a good agreement for all systems. The mean relative deviations for the studied properties are MRD (P) = 1.57%, AAD (y) = 0.0116 and MRD (ρ) = 0.55% for Peng–Robinson EoS, and MRD (P) = 1.20%, AAD (y) = 0.0093 and MRD (ρ) = 0.38% for PC-SAFT EoS.
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Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martínez-baños, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochloromethane were measured over the entire range of composition in the temperature range from T = 293.15 K to T = 313.15 K. Excess molar volumes and deviation in isentropic compressibility have been calculated from experimental measurements and fitted to a Redlich–Kister equation to derive binary coefficients and the standard deviation.
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Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martínez-baños, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochlorometh...
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excess molar volumes and speed of sound in Bromotrichloromethane n heptane dibromomethane n heptane Bromotrichloromethane dibromomethane and Bromotrichloromethane bromochloromethane at temperatures from 293 15 to 313 15 k
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martinezbanos, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochlorometh...
Manuela Artal - One of the best experts on this subject based on the ideXlab platform.
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vapour liquid equilibrium at t 308 15 k for binary systems dibromomethane n heptane Bromotrichloromethane n heptane Bromotrichloromethane dibromomethane Bromotrichloromethane bromochloromethane and dibromomethane bromochloromethane experimental data
Fluid Phase Equilibria, 2015Co-Authors: Lourdes Martinezbanos, Jose Munoz Embid, Santos Otin, Manuela ArtalAbstract:Abstract In this paper, the isothermal vapour–liquid equilibrium (VLE) at T = 308.15 K have been measured for liquid binary systems dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane by a dynamic method. The VLE data have been reduced using the Redlich–Kister equation taking into consideration the vapour phase imperfection in terms of 2nd molar virial coefficients and molar excess Gibbs energies, G m E , have been calculated. The experimental G m E is positive for all systems presenting the greatest value for dibromomethane + n-heptane and a negligible value for dibromomethane + bromochloromethane system. From our experimental data and those reported in the literature, phase and volumetric behaviour of the binary systems containing dibromomethane, bromochloromethane, Bromotrichloromethane or n-heptane have been modelled. Two equations of state, EoS, of different formulation have been used obtaining a good agreement for all systems. The mean relative deviations for the studied properties are MRD (P) = 1.57%, AAD (y) = 0.0116 and MRD (ρ) = 0.55% for Peng–Robinson EoS, and MRD (P) = 1.20%, AAD (y) = 0.0093 and MRD (ρ) = 0.38% for PC-SAFT EoS.
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Vapour–liquid equilibrium at T = 308.15 K for binary systems: Dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane. E
Fluid Phase Equilibria, 2015Co-Authors: Lourdes Martínez-baños, Jose Munoz Embid, Santos Otin, Manuela ArtalAbstract:Abstract In this paper, the isothermal vapour–liquid equilibrium (VLE) at T = 308.15 K have been measured for liquid binary systems dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane by a dynamic method. The VLE data have been reduced using the Redlich–Kister equation taking into consideration the vapour phase imperfection in terms of 2nd molar virial coefficients and molar excess Gibbs energies, G m E , have been calculated. The experimental G m E is positive for all systems presenting the greatest value for dibromomethane + n-heptane and a negligible value for dibromomethane + bromochloromethane system. From our experimental data and those reported in the literature, phase and volumetric behaviour of the binary systems containing dibromomethane, bromochloromethane, Bromotrichloromethane or n-heptane have been modelled. Two equations of state, EoS, of different formulation have been used obtaining a good agreement for all systems. The mean relative deviations for the studied properties are MRD (P) = 1.57%, AAD (y) = 0.0116 and MRD (ρ) = 0.55% for Peng–Robinson EoS, and MRD (P) = 1.20%, AAD (y) = 0.0093 and MRD (ρ) = 0.38% for PC-SAFT EoS.
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Temperature and pressure dependence of the volumetric properties of binary mixtures containing polyhaloalkanes
Canadian Journal of Chemistry, 1999Co-Authors: Carmen Jarne, Jose Munoz Embid, Manuela Artal, Inmaculada Velasco, Santos OtinAbstract:Densities of binary mixtures of 1,1,2-trichlorotrifluoroethane + dibromomethane, + bromochloromethane, or + Bromotrichloromethane were measured over their entire composition ranges at 288.15 and 308.15 K. Thermal expansion coefficients (α) and excess molar volumes (VEm) were calculated. Moreover, densities at 298.15 K and pressures up to 80 bar (1 bar = 100 kPa) were determined for these same mixtures. Isothermal compressibilities (KT) of the pure liquids and their mixtures were obtained.Key words: density, excess volume, thermal expansion coefficient, isothermal compressibility.
Lourdes Martínez-baños - One of the best experts on this subject based on the ideXlab platform.
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Vapour–liquid equilibrium at T = 308.15 K for binary systems: Dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane. E
Fluid Phase Equilibria, 2015Co-Authors: Lourdes Martínez-baños, Jose Munoz Embid, Santos Otin, Manuela ArtalAbstract:Abstract In this paper, the isothermal vapour–liquid equilibrium (VLE) at T = 308.15 K have been measured for liquid binary systems dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane by a dynamic method. The VLE data have been reduced using the Redlich–Kister equation taking into consideration the vapour phase imperfection in terms of 2nd molar virial coefficients and molar excess Gibbs energies, G m E , have been calculated. The experimental G m E is positive for all systems presenting the greatest value for dibromomethane + n-heptane and a negligible value for dibromomethane + bromochloromethane system. From our experimental data and those reported in the literature, phase and volumetric behaviour of the binary systems containing dibromomethane, bromochloromethane, Bromotrichloromethane or n-heptane have been modelled. Two equations of state, EoS, of different formulation have been used obtaining a good agreement for all systems. The mean relative deviations for the studied properties are MRD (P) = 1.57%, AAD (y) = 0.0116 and MRD (ρ) = 0.55% for Peng–Robinson EoS, and MRD (P) = 1.20%, AAD (y) = 0.0093 and MRD (ρ) = 0.38% for PC-SAFT EoS.
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Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martínez-baños, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochloromethane were measured over the entire range of composition in the temperature range from T = 293.15 K to T = 313.15 K. Excess molar volumes and deviation in isentropic compressibility have been calculated from experimental measurements and fitted to a Redlich–Kister equation to derive binary coefficients and the standard deviation.
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Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martínez-baños, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochlorometh...
Lourdes Martinezbanos - One of the best experts on this subject based on the ideXlab platform.
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vapour liquid equilibrium at t 308 15 k for binary systems dibromomethane n heptane Bromotrichloromethane n heptane Bromotrichloromethane dibromomethane Bromotrichloromethane bromochloromethane and dibromomethane bromochloromethane experimental data
Fluid Phase Equilibria, 2015Co-Authors: Lourdes Martinezbanos, Jose Munoz Embid, Santos Otin, Manuela ArtalAbstract:Abstract In this paper, the isothermal vapour–liquid equilibrium (VLE) at T = 308.15 K have been measured for liquid binary systems dibromomethane + n-heptane, Bromotrichloromethane + n-heptane, Bromotrichloromethane + dibromomethane, Bromotrichloromethane + bromochloromethane and dibromomethane + bromochloromethane by a dynamic method. The VLE data have been reduced using the Redlich–Kister equation taking into consideration the vapour phase imperfection in terms of 2nd molar virial coefficients and molar excess Gibbs energies, G m E , have been calculated. The experimental G m E is positive for all systems presenting the greatest value for dibromomethane + n-heptane and a negligible value for dibromomethane + bromochloromethane system. From our experimental data and those reported in the literature, phase and volumetric behaviour of the binary systems containing dibromomethane, bromochloromethane, Bromotrichloromethane or n-heptane have been modelled. Two equations of state, EoS, of different formulation have been used obtaining a good agreement for all systems. The mean relative deviations for the studied properties are MRD (P) = 1.57%, AAD (y) = 0.0116 and MRD (ρ) = 0.55% for Peng–Robinson EoS, and MRD (P) = 1.20%, AAD (y) = 0.0093 and MRD (ρ) = 0.38% for PC-SAFT EoS.
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excess molar volumes and speed of sound in Bromotrichloromethane n heptane dibromomethane n heptane Bromotrichloromethane dibromomethane and Bromotrichloromethane bromochloromethane at temperatures from 293 15 to 313 15 k
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martinezbanos, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochlorometh...
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excess molar volumes and speed of sound in Bromotrichloromethane n heptane dibromomethane n heptane Bromotrichloromethane dibromomethane and Bromotrichloromethane bromochloromethane at temperatures from 293 15 to 313 15 k
Journal of Chemical & Engineering Data, 2013Co-Authors: Lourdes Martinezbanos, Clara Rivas, Jose Munoz Embid, Santos OtinAbstract:Density and speed of sound of four binary mixtures Bromotrichloromethane + n-heptane, dibromomethane + n-heptane, Bromotrichloromethane + dibromomethane, and Bromotrichloromethane + bromochloromethane were measured over the entire range of composition in the temperature range from T = 293.15 K to T = 313.15 K. Excess molar volumes and deviation in isentropic compressibility have been calculated from experimental measurements and fitted to a Redlich–Kister equation to derive binary coefficients and the standard deviation.
