The Experts below are selected from a list of 246 Experts worldwide ranked by ideXlab platform
Mark J Maclachlan - One of the best experts on this subject based on the ideXlab platform.
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Family of Cadmium Acetate Coordination Networks With Structurally Diverse [Cd4(OAc)9(μ3-OH)]2− Secondary Building Units
Inorganic Chemistry, 2011Co-Authors: Susan M Vickers, Peter D Frischmann, Mark J MaclachlanAbstract:By subtly varying crystallization conditions, four distinct Cadmium Acetate coordination networks with unit cell formulas Cd87(H2O)36(EtOH)18(OH)12(CH3CO2)162 (1), Cd87(H2O)72(OH)12(CH3CO2)162 (2), Cd10(H2O)6(OH)2(CH3CO2)18 (3), and Cd20(H2O)20(OH)4(CH3CO2)36 (4) have been isolated. The coordination networks exhibit interesting structural diversity and have been investigated by powder X-ray diffraction, elemental analysis, thermal gravimetric analysis, infrared spectroscopy, and single-crystal X-ray diffraction. All four complexes are composed of secondary building units with the general formula [Cd4(OAc)9(μ3-OH)]2−. Complexes 1 and 2 exhibit a remarkable three-dimensional network composed of aligned columns, each 4.5 nm long, containing three different Cadmium Acetate clusters. Complexes 3 and 4 extend in two-dimensions with each unit cell repeating a different linkage isomer of the [Cd4(OAc)9(μ3-OH)]2− cluster.
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family of Cadmium Acetate coordination networks with structurally diverse cd4 oac 9 μ3 oh 2 secondary building units
Inorganic Chemistry, 2011Co-Authors: Susan M Vickers, Peter D Frischmann, Mark J MaclachlanAbstract:By subtly varying crystallization conditions, four distinct Cadmium Acetate coordination networks with unit cell formulas Cd87(H2O)36(EtOH)18(OH)12(CH3CO2)162 (1), Cd87(H2O)72(OH)12(CH3CO2)162 (2), Cd10(H2O)6(OH)2(CH3CO2)18 (3), and Cd20(H2O)20(OH)4(CH3CO2)36 (4) have been isolated. The coordination networks exhibit interesting structural diversity and have been investigated by powder X-ray diffraction, elemental analysis, thermal gravimetric analysis, infrared spectroscopy, and single-crystal X-ray diffraction. All four complexes are composed of secondary building units with the general formula [Cd4(OAc)9(μ3-OH)]2−. Complexes 1 and 2 exhibit a remarkable three-dimensional network composed of aligned columns, each 4.5 nm long, containing three different Cadmium Acetate clusters. Complexes 3 and 4 extend in two-dimensions with each unit cell repeating a different linkage isomer of the [Cd4(OAc)9(μ3-OH)]2− cluster.
Susan M Vickers - One of the best experts on this subject based on the ideXlab platform.
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Family of Cadmium Acetate Coordination Networks With Structurally Diverse [Cd4(OAc)9(μ3-OH)]2− Secondary Building Units
Inorganic Chemistry, 2011Co-Authors: Susan M Vickers, Peter D Frischmann, Mark J MaclachlanAbstract:By subtly varying crystallization conditions, four distinct Cadmium Acetate coordination networks with unit cell formulas Cd87(H2O)36(EtOH)18(OH)12(CH3CO2)162 (1), Cd87(H2O)72(OH)12(CH3CO2)162 (2), Cd10(H2O)6(OH)2(CH3CO2)18 (3), and Cd20(H2O)20(OH)4(CH3CO2)36 (4) have been isolated. The coordination networks exhibit interesting structural diversity and have been investigated by powder X-ray diffraction, elemental analysis, thermal gravimetric analysis, infrared spectroscopy, and single-crystal X-ray diffraction. All four complexes are composed of secondary building units with the general formula [Cd4(OAc)9(μ3-OH)]2−. Complexes 1 and 2 exhibit a remarkable three-dimensional network composed of aligned columns, each 4.5 nm long, containing three different Cadmium Acetate clusters. Complexes 3 and 4 extend in two-dimensions with each unit cell repeating a different linkage isomer of the [Cd4(OAc)9(μ3-OH)]2− cluster.
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family of Cadmium Acetate coordination networks with structurally diverse cd4 oac 9 μ3 oh 2 secondary building units
Inorganic Chemistry, 2011Co-Authors: Susan M Vickers, Peter D Frischmann, Mark J MaclachlanAbstract:By subtly varying crystallization conditions, four distinct Cadmium Acetate coordination networks with unit cell formulas Cd87(H2O)36(EtOH)18(OH)12(CH3CO2)162 (1), Cd87(H2O)72(OH)12(CH3CO2)162 (2), Cd10(H2O)6(OH)2(CH3CO2)18 (3), and Cd20(H2O)20(OH)4(CH3CO2)36 (4) have been isolated. The coordination networks exhibit interesting structural diversity and have been investigated by powder X-ray diffraction, elemental analysis, thermal gravimetric analysis, infrared spectroscopy, and single-crystal X-ray diffraction. All four complexes are composed of secondary building units with the general formula [Cd4(OAc)9(μ3-OH)]2−. Complexes 1 and 2 exhibit a remarkable three-dimensional network composed of aligned columns, each 4.5 nm long, containing three different Cadmium Acetate clusters. Complexes 3 and 4 extend in two-dimensions with each unit cell repeating a different linkage isomer of the [Cd4(OAc)9(μ3-OH)]2− cluster.
Peter D Frischmann - One of the best experts on this subject based on the ideXlab platform.
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Family of Cadmium Acetate Coordination Networks With Structurally Diverse [Cd4(OAc)9(μ3-OH)]2− Secondary Building Units
Inorganic Chemistry, 2011Co-Authors: Susan M Vickers, Peter D Frischmann, Mark J MaclachlanAbstract:By subtly varying crystallization conditions, four distinct Cadmium Acetate coordination networks with unit cell formulas Cd87(H2O)36(EtOH)18(OH)12(CH3CO2)162 (1), Cd87(H2O)72(OH)12(CH3CO2)162 (2), Cd10(H2O)6(OH)2(CH3CO2)18 (3), and Cd20(H2O)20(OH)4(CH3CO2)36 (4) have been isolated. The coordination networks exhibit interesting structural diversity and have been investigated by powder X-ray diffraction, elemental analysis, thermal gravimetric analysis, infrared spectroscopy, and single-crystal X-ray diffraction. All four complexes are composed of secondary building units with the general formula [Cd4(OAc)9(μ3-OH)]2−. Complexes 1 and 2 exhibit a remarkable three-dimensional network composed of aligned columns, each 4.5 nm long, containing three different Cadmium Acetate clusters. Complexes 3 and 4 extend in two-dimensions with each unit cell repeating a different linkage isomer of the [Cd4(OAc)9(μ3-OH)]2− cluster.
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family of Cadmium Acetate coordination networks with structurally diverse cd4 oac 9 μ3 oh 2 secondary building units
Inorganic Chemistry, 2011Co-Authors: Susan M Vickers, Peter D Frischmann, Mark J MaclachlanAbstract:By subtly varying crystallization conditions, four distinct Cadmium Acetate coordination networks with unit cell formulas Cd87(H2O)36(EtOH)18(OH)12(CH3CO2)162 (1), Cd87(H2O)72(OH)12(CH3CO2)162 (2), Cd10(H2O)6(OH)2(CH3CO2)18 (3), and Cd20(H2O)20(OH)4(CH3CO2)36 (4) have been isolated. The coordination networks exhibit interesting structural diversity and have been investigated by powder X-ray diffraction, elemental analysis, thermal gravimetric analysis, infrared spectroscopy, and single-crystal X-ray diffraction. All four complexes are composed of secondary building units with the general formula [Cd4(OAc)9(μ3-OH)]2−. Complexes 1 and 2 exhibit a remarkable three-dimensional network composed of aligned columns, each 4.5 nm long, containing three different Cadmium Acetate clusters. Complexes 3 and 4 extend in two-dimensions with each unit cell repeating a different linkage isomer of the [Cd4(OAc)9(μ3-OH)]2− cluster.
Jing-song You - One of the best experts on this subject based on the ideXlab platform.
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Crystal Water of Cadmium Acetate-Dependent Formation of One-Dimensional Channel Structure Based on 4,4′-Bis(1-Imidazolyl)biphenyl
Crystal Growth & Design, 2008Co-Authors: Shiyong Zhang, † Jing-bo Lan, ‡ Zhi-hua Mao, † Ru-gang Xie, Jing-song YouAbstract:A novel metal-organic framework with one-dimensional channels {[Cd(3)(CH3COO)2(H2O)2] (CH3CN)x(CH3OH)y} (5), based on conformationally restricted linear 4,4′-bis(1-imidazolyl)biphenyl (3) and Cadmium Acetate dihydrate, has been synthesized. It crystallizes in the triclinic system, space group P1 with a = 5.6528(11) A, b = 9.887(3) A, c = 12.924(3) A, and Z = 1. The experimental results demonstrate that coordinated crystal water molecules may play a key role in the formation of the metal-organic frameworks.
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crystal water of Cadmium Acetate dependent formation of one dimensional channel structure based on 4 4 bis 1 imidazolyl biphenyl
Crystal Growth & Design, 2008Co-Authors: Shiyong Zhang, Jingbo Lan, Zhihua Mao, Rugang Xie, Jing-song YouAbstract:A novel metal-organic framework with one-dimensional channels {[Cd(3)(CH3COO)2(H2O)2] (CH3CN)x(CH3OH)y} (5), based on conformationally restricted linear 4,4′-bis(1-imidazolyl)biphenyl (3) and Cadmium Acetate dihydrate, has been synthesized. It crystallizes in the triclinic system, space group P1 with a = 5.6528(11) A, b = 9.887(3) A, c = 12.924(3) A, and Z = 1. The experimental results demonstrate that coordinated crystal water molecules may play a key role in the formation of the metal-organic frameworks.
P. Sagayaraj - One of the best experts on this subject based on the ideXlab platform.
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Growth and characterization of pure and doped bis(thiourea) Cadmium Acetate single crystals
Materials Chemistry and Physics, 2007Co-Authors: S. Selvakumar, S.m. Ravi Kumar, Ginson P. Joseph, K. Rajarajan, Jagannathan Madhavan, S.a. Rajasekar, P. SagayarajAbstract:Abstract Single crystals of pure and Zn2+ doped bis(thiourea) Cadmium Acetate (BTCA) were grown by slow solvent evaporation technique. The grown crystals were confirmed by single crystal XRD. The metal coordination with thiourea through sulphur in both pure and doped BTCA was ascertained by FTIR studies. The optical transmission spectra of pure and doped BTCA crystals were recorded and the results are discussed. The thermal decomposition of pure and doped BTCA crystals was investigated by means of thermogravimetric analysis (TGA). The dielectric response and photoconducting nature of the crystals were also investigated and reported.
