The Experts below are selected from a list of 10023 Experts worldwide ranked by ideXlab platform
Al'bina I. Mikhaleva - One of the best experts on this subject based on the ideXlab platform.
-
transition metal free stereoselective α vinylation of cyclic ketones with arylacetylenes in the superbasic Catalytic Triad potassium hydroxide tert butyl alcohol dimethyl sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.
-
Transition Metal‐Free Stereoselective α‐Vinylation of Cyclic Ketones with Arylacetylenes in the Superbasic Catalytic Triad Potassium Hydroxide/tert‐Butyl Alcohol/Dimethyl Sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.
Boris A. Trofimov - One of the best experts on this subject based on the ideXlab platform.
-
transition metal free stereoselective α vinylation of cyclic ketones with arylacetylenes in the superbasic Catalytic Triad potassium hydroxide tert butyl alcohol dimethyl sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.
-
Transition Metal‐Free Stereoselective α‐Vinylation of Cyclic Ketones with Arylacetylenes in the Superbasic Catalytic Triad Potassium Hydroxide/tert‐Butyl Alcohol/Dimethyl Sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.
Igor A. Ushakov - One of the best experts on this subject based on the ideXlab platform.
-
transition metal free stereoselective α vinylation of cyclic ketones with arylacetylenes in the superbasic Catalytic Triad potassium hydroxide tert butyl alcohol dimethyl sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.
-
Transition Metal‐Free Stereoselective α‐Vinylation of Cyclic Ketones with Arylacetylenes in the Superbasic Catalytic Triad Potassium Hydroxide/tert‐Butyl Alcohol/Dimethyl Sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.
Nadezhda V. Zorina - One of the best experts on this subject based on the ideXlab platform.
-
transition metal free stereoselective α vinylation of cyclic ketones with arylacetylenes in the superbasic Catalytic Triad potassium hydroxide tert butyl alcohol dimethyl sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.
-
Transition Metal‐Free Stereoselective α‐Vinylation of Cyclic Ketones with Arylacetylenes in the Superbasic Catalytic Triad Potassium Hydroxide/tert‐Butyl Alcohol/Dimethyl Sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.
Elena Yu. Schmidt - One of the best experts on this subject based on the ideXlab platform.
-
transition metal free stereoselective α vinylation of cyclic ketones with arylacetylenes in the superbasic Catalytic Triad potassium hydroxide tert butyl alcohol dimethyl sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.
-
Transition Metal‐Free Stereoselective α‐Vinylation of Cyclic Ketones with Arylacetylenes in the Superbasic Catalytic Triad Potassium Hydroxide/tert‐Butyl Alcohol/Dimethyl Sulfoxide
Advanced Synthesis & Catalysis, 2012Co-Authors: Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Igor A. Ushakov, Elena Ivanova, Al'bina I. MikhalevaAbstract:A stereoselective α-vinylation of cycloaliphatic ketones with arylacetylenes under the transition metal-free conditions has been developed. The reaction is promoted by the superbasic Catalytic Triad potassium hydroxide/tert-butyl alcohol/dimethyl sulfoxide (80–110 °C, 1–2 h) to afford mainly (E)-β,γ-ethylenic ketones, their (E)-α,β-isomers being minor products, in up to 83% total yield.