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Mari Sild - One of the best experts on this subject based on the ideXlab platform.

Milan Vondruska - One of the best experts on this subject based on the ideXlab platform.

S C Sharma - One of the best experts on this subject based on the ideXlab platform.

  • synthesis of nanocrystalline magnesium aluminate mgal2o4 spinel powder by the urea formaldehyde polymer gel Combustion route
    Materials Research Bulletin, 2009
    Co-Authors: K Prabhakaran, D S Patil, Rajiv Dayal, N M Gokhale, S C Sharma
    Abstract:

    Abstract Nanocrystalline MgAl 2 O 4 spinel powder was synthesized by the urea–formaldehyde (UF) polymer gel Combustion route. A transparent gel formed from magnesium nitrate, aluminium nitrate and UF after drying underwet self-sustained Combustion when initiated with a burning splinter. The Combustion Product on calcinations at 850 °C formed MgAl 2 O 4 spinel. Calcination of the Combustion Product resulted in particle coarsening. The powder obtained by planetary ball milling of the spinel had a median particle size of 1.58 μm. The spinel particles are agglomerates of nanocrystallites of size in the range 10–30 nm. The compacts prepared by uni-axial pressing of the spinel powder sintered to >99% TD at 1600 °C.

  • synthesis of nanocrystalline yttria doped ceria powder by urea formaldehyde polymer gel auto Combustion process
    Materials Research Bulletin, 2007
    Co-Authors: Mridula Biswas, K Prabhakaran, N M Gokhale, S C Sharma
    Abstract:

    Abstract Nanocrystalline yttria doped ceria powder has been prepared by auto-Combustion of a transparent gel formed by heating an aqueous acidic solution containing methylol urea, urea, cerium(III) nitrate and yttrium(III) nitrate. The TGA and DSC studies showed the Combustion reaction of the gel initiated at 225 °C and completed within a short period of time. XRD spectrum of the Combustion Product reveals the formation of phase pure cubic yttria doped ceria during the Combustion process. Loose agglomerate of yttria doped ceria particle obtained by the Combustion reaction could be easily deagglomerated by planetary ball milling and the powder obtained contains particles in the size range of 0.05–3.3 μm with D 50 value of 0.13 μm. The powder particles are aggregate of nanocrystallites with a wide size range of 14–105 nm. Pellets prepared by pressing the yttria doped ceria powder sintered to 95.2% TD at 1400 °C.

Vratislav Bednarik - One of the best experts on this subject based on the ideXlab platform.

K Prabhakaran - One of the best experts on this subject based on the ideXlab platform.

  • synthesis of nanocrystalline magnesium aluminate mgal2o4 spinel powder by the urea formaldehyde polymer gel Combustion route
    Materials Research Bulletin, 2009
    Co-Authors: K Prabhakaran, D S Patil, Rajiv Dayal, N M Gokhale, S C Sharma
    Abstract:

    Abstract Nanocrystalline MgAl 2 O 4 spinel powder was synthesized by the urea–formaldehyde (UF) polymer gel Combustion route. A transparent gel formed from magnesium nitrate, aluminium nitrate and UF after drying underwet self-sustained Combustion when initiated with a burning splinter. The Combustion Product on calcinations at 850 °C formed MgAl 2 O 4 spinel. Calcination of the Combustion Product resulted in particle coarsening. The powder obtained by planetary ball milling of the spinel had a median particle size of 1.58 μm. The spinel particles are agglomerates of nanocrystallites of size in the range 10–30 nm. The compacts prepared by uni-axial pressing of the spinel powder sintered to >99% TD at 1600 °C.

  • synthesis of nanocrystalline yttria doped ceria powder by urea formaldehyde polymer gel auto Combustion process
    Materials Research Bulletin, 2007
    Co-Authors: Mridula Biswas, K Prabhakaran, N M Gokhale, S C Sharma
    Abstract:

    Abstract Nanocrystalline yttria doped ceria powder has been prepared by auto-Combustion of a transparent gel formed by heating an aqueous acidic solution containing methylol urea, urea, cerium(III) nitrate and yttrium(III) nitrate. The TGA and DSC studies showed the Combustion reaction of the gel initiated at 225 °C and completed within a short period of time. XRD spectrum of the Combustion Product reveals the formation of phase pure cubic yttria doped ceria during the Combustion process. Loose agglomerate of yttria doped ceria particle obtained by the Combustion reaction could be easily deagglomerated by planetary ball milling and the powder obtained contains particles in the size range of 0.05–3.3 μm with D 50 value of 0.13 μm. The powder particles are aggregate of nanocrystallites with a wide size range of 14–105 nm. Pellets prepared by pressing the yttria doped ceria powder sintered to 95.2% TD at 1400 °C.