Corrosivity

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Jessica N Cross - One of the best experts on this subject based on the ideXlab platform.

  • Calcium carbonate Corrosivity in an Alaskan inland sea
    Copernicus Publications, 2014
    Co-Authors: Wiley Evans, Jeremy T Mathis, Jessica N Cross
    Abstract:

    Ocean acidification is the hydrogen ion increase caused by the oceanic uptake of anthropogenic CO2, and is a focal point in marine biogeochemistry, in part, because this chemical reaction reduces calcium carbonate (CaCO3) saturation states (Ω) to levels that are corrosive (i.e., Ω ≤ 1) to shell-forming marine organisms. However, other processes can drive CaCO3 Corrosivity; specifically, the addition of tidewater glacial melt. Carbonate system data collected in May and September from 2009 through 2012 in Prince William Sound (PWS), a semienclosed inland sea located on the south-central coast of Alaska and ringed with fjords containing tidewater glaciers, reveal the unique impact of glacial melt on CaCO3 Corrosivity. Initial limited sampling was expanded in September 2011 to span large portions of the western and central sound, and included two fjords proximal to tidewater glaciers: Icy Bay and Columbia Bay. The observed conditions in these fjords affected CaCO3 Corrosivity in the upper water column (< 50 m) in PWS in two ways: (1) as spring-time formation sites of mode water with near-corrosive Ω levels seen below the mixed layer over a portion of the sound, and (2) as point sources for surface plumes of glacial melt with corrosive Ω levels (Ω for aragonite and calcite down to 0.60 and 1.02, respectively) and carbon dioxide partial pressures (pCO2) well below atmospheric levels. CaCO3 Corrosivity in glacial melt plumes is poorly reflected by pCO2 or pHT, indicating that either one of these carbonate parameters alone would fail to track Ω in PWS. The unique Ω and pCO2 conditions in the glacial melt plumes enhances atmospheric CO2 uptake, which, if not offset by mixing or primary productivity, would rapidly exacerbate CaCO3 Corrosivity in a positive feedback. The cumulative effects of glacial melt and air–sea gas exchange are likely responsible for the seasonal reduction of Ω in PWS, making PWS highly sensitive to increasing atmospheric CO2 and amplified CaCO3 Corrosivity

  • calcium carbonate Corrosivity in an alaskan inland sea
    AGU Fall Meeting Abstracts, 2013
    Co-Authors: Wiley Evans, Jeremy T Mathis, Jessica N Cross
    Abstract:

    Abstract. Ocean acidification is the hydrogen ion increase caused by the oceanic uptake of anthropogenic CO2, and is a focal point in marine biogeochemistry, in part, because this chemical reaction reduces calcium carbonate (CaCO3) saturation states (Ω) to levels that are corrosive (i.e., Ω ≤ 1) to shell-forming marine organisms. However, other processes can drive CaCO3 Corrosivity; specifically, the addition of tidewater glacial melt. Carbonate system data collected in May and September from 2009 through 2012 in Prince William Sound (PWS), a semienclosed inland sea located on the south-central coast of Alaska and ringed with fjords containing tidewater glaciers, reveal the unique impact of glacial melt on CaCO3 Corrosivity. Initial limited sampling was expanded in September 2011 to span large portions of the western and central sound, and included two fjords proximal to tidewater glaciers: Icy Bay and Columbia Bay. The observed conditions in these fjords affected CaCO3 Corrosivity in the upper water column (

  • calcium carbonate Corrosivity in an alaskan inland sea
    Biogeosciences, 2013
    Co-Authors: Wiley Evans, Jeremy T Mathis, Jessica N Cross
    Abstract:

    Ocean acidification is the hydrogen ion increase caused by the oceanic uptake of anthropogenic CO2, and is a focal point in marine biogeochemistry, in part, because this chemical reaction reduces calcium carbonate (CaCO3) saturation states (Ω) to levels that are corrosive (i.e., Ω ≤ 1) to shell-forming marine organisms. However, other processes can drive CaCO3 Corrosivity; specifically, the addition of tidewater glacial melt. Carbonate system data collected in May and September from 2009 through 2012 in Prince William Sound (PWS), a semienclosed inland sea located on the south-central coast of Alaska and ringed with fjords containing tidewater glaciers, reveal the unique impact of glacial melt on CaCO3 Corrosivity. Initial limited sampling was expanded in September 2011 to span large portions of the western and central sound, and included two fjords proximal to tidewater glaciers: Icy Bay and Columbia Bay. The observed conditions in these fjords affected CaCO3 Corrosivity in the upper water column (< 50 m) in PWS in two ways: (1) as spring-time formation sites of mode water with near-corrosive Ω levels seen below the mixed layer over a portion of the sound, and (2) as point sources for surface plumes of glacial melt with corrosive Ω levels (Ω for aragonite and calcite down to 0.60 and 1.02, respectively) and carbon dioxide partial pressures (pCO2) well below atmospheric levels. CaCO3 Corrosivity in glacial melt plumes is poorly reflected by pCO2 or pHT, indicating that either one of these carbonate parameters alone would fail to track Ω in PWS. The unique Ω and pCO2 conditions in the glacial melt plumes enhances atmospheric CO2 uptake, which, if not offset by mixing or primary productivity, would rapidly exacerbate CaCO3 Corrosivity in a positive feedback. The cumulative effects of glacial melt and air–sea gas exchange are likely responsible for the seasonal reduction of Ω in PWS, making PWS highly sensitive to increasing atmospheric CO2 and amplified CaCO3 Corrosivity.

Wiley Evans - One of the best experts on this subject based on the ideXlab platform.

  • Calcium carbonate Corrosivity in an Alaskan inland sea
    Copernicus Publications, 2014
    Co-Authors: Wiley Evans, Jeremy T Mathis, Jessica N Cross
    Abstract:

    Ocean acidification is the hydrogen ion increase caused by the oceanic uptake of anthropogenic CO2, and is a focal point in marine biogeochemistry, in part, because this chemical reaction reduces calcium carbonate (CaCO3) saturation states (Ω) to levels that are corrosive (i.e., Ω ≤ 1) to shell-forming marine organisms. However, other processes can drive CaCO3 Corrosivity; specifically, the addition of tidewater glacial melt. Carbonate system data collected in May and September from 2009 through 2012 in Prince William Sound (PWS), a semienclosed inland sea located on the south-central coast of Alaska and ringed with fjords containing tidewater glaciers, reveal the unique impact of glacial melt on CaCO3 Corrosivity. Initial limited sampling was expanded in September 2011 to span large portions of the western and central sound, and included two fjords proximal to tidewater glaciers: Icy Bay and Columbia Bay. The observed conditions in these fjords affected CaCO3 Corrosivity in the upper water column (< 50 m) in PWS in two ways: (1) as spring-time formation sites of mode water with near-corrosive Ω levels seen below the mixed layer over a portion of the sound, and (2) as point sources for surface plumes of glacial melt with corrosive Ω levels (Ω for aragonite and calcite down to 0.60 and 1.02, respectively) and carbon dioxide partial pressures (pCO2) well below atmospheric levels. CaCO3 Corrosivity in glacial melt plumes is poorly reflected by pCO2 or pHT, indicating that either one of these carbonate parameters alone would fail to track Ω in PWS. The unique Ω and pCO2 conditions in the glacial melt plumes enhances atmospheric CO2 uptake, which, if not offset by mixing or primary productivity, would rapidly exacerbate CaCO3 Corrosivity in a positive feedback. The cumulative effects of glacial melt and air–sea gas exchange are likely responsible for the seasonal reduction of Ω in PWS, making PWS highly sensitive to increasing atmospheric CO2 and amplified CaCO3 Corrosivity

  • calcium carbonate Corrosivity in an alaskan inland sea
    AGU Fall Meeting Abstracts, 2013
    Co-Authors: Wiley Evans, Jeremy T Mathis, Jessica N Cross
    Abstract:

    Abstract. Ocean acidification is the hydrogen ion increase caused by the oceanic uptake of anthropogenic CO2, and is a focal point in marine biogeochemistry, in part, because this chemical reaction reduces calcium carbonate (CaCO3) saturation states (Ω) to levels that are corrosive (i.e., Ω ≤ 1) to shell-forming marine organisms. However, other processes can drive CaCO3 Corrosivity; specifically, the addition of tidewater glacial melt. Carbonate system data collected in May and September from 2009 through 2012 in Prince William Sound (PWS), a semienclosed inland sea located on the south-central coast of Alaska and ringed with fjords containing tidewater glaciers, reveal the unique impact of glacial melt on CaCO3 Corrosivity. Initial limited sampling was expanded in September 2011 to span large portions of the western and central sound, and included two fjords proximal to tidewater glaciers: Icy Bay and Columbia Bay. The observed conditions in these fjords affected CaCO3 Corrosivity in the upper water column (

  • calcium carbonate Corrosivity in an alaskan inland sea
    Biogeosciences, 2013
    Co-Authors: Wiley Evans, Jeremy T Mathis, Jessica N Cross
    Abstract:

    Ocean acidification is the hydrogen ion increase caused by the oceanic uptake of anthropogenic CO2, and is a focal point in marine biogeochemistry, in part, because this chemical reaction reduces calcium carbonate (CaCO3) saturation states (Ω) to levels that are corrosive (i.e., Ω ≤ 1) to shell-forming marine organisms. However, other processes can drive CaCO3 Corrosivity; specifically, the addition of tidewater glacial melt. Carbonate system data collected in May and September from 2009 through 2012 in Prince William Sound (PWS), a semienclosed inland sea located on the south-central coast of Alaska and ringed with fjords containing tidewater glaciers, reveal the unique impact of glacial melt on CaCO3 Corrosivity. Initial limited sampling was expanded in September 2011 to span large portions of the western and central sound, and included two fjords proximal to tidewater glaciers: Icy Bay and Columbia Bay. The observed conditions in these fjords affected CaCO3 Corrosivity in the upper water column (< 50 m) in PWS in two ways: (1) as spring-time formation sites of mode water with near-corrosive Ω levels seen below the mixed layer over a portion of the sound, and (2) as point sources for surface plumes of glacial melt with corrosive Ω levels (Ω for aragonite and calcite down to 0.60 and 1.02, respectively) and carbon dioxide partial pressures (pCO2) well below atmospheric levels. CaCO3 Corrosivity in glacial melt plumes is poorly reflected by pCO2 or pHT, indicating that either one of these carbonate parameters alone would fail to track Ω in PWS. The unique Ω and pCO2 conditions in the glacial melt plumes enhances atmospheric CO2 uptake, which, if not offset by mixing or primary productivity, would rapidly exacerbate CaCO3 Corrosivity in a positive feedback. The cumulative effects of glacial melt and air–sea gas exchange are likely responsible for the seasonal reduction of Ω in PWS, making PWS highly sensitive to increasing atmospheric CO2 and amplified CaCO3 Corrosivity.

Jeremy T Mathis - One of the best experts on this subject based on the ideXlab platform.

  • Calcium carbonate Corrosivity in an Alaskan inland sea
    Copernicus Publications, 2014
    Co-Authors: Wiley Evans, Jeremy T Mathis, Jessica N Cross
    Abstract:

    Ocean acidification is the hydrogen ion increase caused by the oceanic uptake of anthropogenic CO2, and is a focal point in marine biogeochemistry, in part, because this chemical reaction reduces calcium carbonate (CaCO3) saturation states (Ω) to levels that are corrosive (i.e., Ω ≤ 1) to shell-forming marine organisms. However, other processes can drive CaCO3 Corrosivity; specifically, the addition of tidewater glacial melt. Carbonate system data collected in May and September from 2009 through 2012 in Prince William Sound (PWS), a semienclosed inland sea located on the south-central coast of Alaska and ringed with fjords containing tidewater glaciers, reveal the unique impact of glacial melt on CaCO3 Corrosivity. Initial limited sampling was expanded in September 2011 to span large portions of the western and central sound, and included two fjords proximal to tidewater glaciers: Icy Bay and Columbia Bay. The observed conditions in these fjords affected CaCO3 Corrosivity in the upper water column (< 50 m) in PWS in two ways: (1) as spring-time formation sites of mode water with near-corrosive Ω levels seen below the mixed layer over a portion of the sound, and (2) as point sources for surface plumes of glacial melt with corrosive Ω levels (Ω for aragonite and calcite down to 0.60 and 1.02, respectively) and carbon dioxide partial pressures (pCO2) well below atmospheric levels. CaCO3 Corrosivity in glacial melt plumes is poorly reflected by pCO2 or pHT, indicating that either one of these carbonate parameters alone would fail to track Ω in PWS. The unique Ω and pCO2 conditions in the glacial melt plumes enhances atmospheric CO2 uptake, which, if not offset by mixing or primary productivity, would rapidly exacerbate CaCO3 Corrosivity in a positive feedback. The cumulative effects of glacial melt and air–sea gas exchange are likely responsible for the seasonal reduction of Ω in PWS, making PWS highly sensitive to increasing atmospheric CO2 and amplified CaCO3 Corrosivity

  • calcium carbonate Corrosivity in an alaskan inland sea
    AGU Fall Meeting Abstracts, 2013
    Co-Authors: Wiley Evans, Jeremy T Mathis, Jessica N Cross
    Abstract:

    Abstract. Ocean acidification is the hydrogen ion increase caused by the oceanic uptake of anthropogenic CO2, and is a focal point in marine biogeochemistry, in part, because this chemical reaction reduces calcium carbonate (CaCO3) saturation states (Ω) to levels that are corrosive (i.e., Ω ≤ 1) to shell-forming marine organisms. However, other processes can drive CaCO3 Corrosivity; specifically, the addition of tidewater glacial melt. Carbonate system data collected in May and September from 2009 through 2012 in Prince William Sound (PWS), a semienclosed inland sea located on the south-central coast of Alaska and ringed with fjords containing tidewater glaciers, reveal the unique impact of glacial melt on CaCO3 Corrosivity. Initial limited sampling was expanded in September 2011 to span large portions of the western and central sound, and included two fjords proximal to tidewater glaciers: Icy Bay and Columbia Bay. The observed conditions in these fjords affected CaCO3 Corrosivity in the upper water column (

  • calcium carbonate Corrosivity in an alaskan inland sea
    Biogeosciences, 2013
    Co-Authors: Wiley Evans, Jeremy T Mathis, Jessica N Cross
    Abstract:

    Ocean acidification is the hydrogen ion increase caused by the oceanic uptake of anthropogenic CO2, and is a focal point in marine biogeochemistry, in part, because this chemical reaction reduces calcium carbonate (CaCO3) saturation states (Ω) to levels that are corrosive (i.e., Ω ≤ 1) to shell-forming marine organisms. However, other processes can drive CaCO3 Corrosivity; specifically, the addition of tidewater glacial melt. Carbonate system data collected in May and September from 2009 through 2012 in Prince William Sound (PWS), a semienclosed inland sea located on the south-central coast of Alaska and ringed with fjords containing tidewater glaciers, reveal the unique impact of glacial melt on CaCO3 Corrosivity. Initial limited sampling was expanded in September 2011 to span large portions of the western and central sound, and included two fjords proximal to tidewater glaciers: Icy Bay and Columbia Bay. The observed conditions in these fjords affected CaCO3 Corrosivity in the upper water column (< 50 m) in PWS in two ways: (1) as spring-time formation sites of mode water with near-corrosive Ω levels seen below the mixed layer over a portion of the sound, and (2) as point sources for surface plumes of glacial melt with corrosive Ω levels (Ω for aragonite and calcite down to 0.60 and 1.02, respectively) and carbon dioxide partial pressures (pCO2) well below atmospheric levels. CaCO3 Corrosivity in glacial melt plumes is poorly reflected by pCO2 or pHT, indicating that either one of these carbonate parameters alone would fail to track Ω in PWS. The unique Ω and pCO2 conditions in the glacial melt plumes enhances atmospheric CO2 uptake, which, if not offset by mixing or primary productivity, would rapidly exacerbate CaCO3 Corrosivity in a positive feedback. The cumulative effects of glacial melt and air–sea gas exchange are likely responsible for the seasonal reduction of Ω in PWS, making PWS highly sensitive to increasing atmospheric CO2 and amplified CaCO3 Corrosivity.

Guangling Song - One of the best experts on this subject based on the ideXlab platform.

  • improvement of intelligent Corrosivity detection and corrosion protection for reinforcing steel
    Corrosion Science, 2021
    Co-Authors: Guangling Song, Yixing Zhu, Lei Yan, Zhenliang Feng, Dajiang Zheng
    Abstract:

    Abstract A series of Mg-Al alloys were fabricated by means of magnetron-sputtering, aiming to improve the intelligence of Mg as a smart concrete Corrosivity-detector and corrosion-protector. The effect of Al alloying on Mg dissolution in a simulated concrete pore solution (SCPS) without and with Cl− contamination was systematically investigated. The results showed that proper Al alloying could significantly enhance the intelligence of Mg in Corrosivity-detection and corrosion-protection by reducing the self-dissolution, avoiding the over-protection, sensitively probing increased Corrosivity, and effectively protect the steel activated by chlorides.

  • Corrosivity of haze constituents to pure mg
    Journal of Magnesium and Alloys, 2020
    Co-Authors: Chen Zhao, Fuyong Cao, Guangling Song
    Abstract:

    Abstract The corrosion behavior of pure Magnesium (Mg) in a Mg(OH)2-saturated solution containing different individual constituents of PM2.5 in haze were studied by hydrogen evolution, weight loss and electrochemical experiments. The results indicated that the Corrosivity of these constituents to pure Mg decreased in the following order: (NH4)2SO4>Haze-contaminated-solution>NH4NO3>NH4Cl>NaCl ≈ KCl ≈ Na2SO4 ≈ MgCl2 ≈ CaSO4>Mg(OH)2 (basic solution) >Ca(NO3)2. Possible mechanisms behind the different corrosion behaviors of Mg in response to these constituents were also briefly discussed in this paper.

  • magnesium alloy anode as a smart Corrosivity detector and intelligent sacrificial anode protector for reinforced concrete
    Corrosion Science, 2019
    Co-Authors: Lei Yan, Guangling Song, Dajiang Zheng
    Abstract:

    Abstract Corrosivity of simulated concrete pore solution (SCPS) contaminated by chloride was automatically detected and corrosion of steel in SCPS was intelligently prevented by magnesium (Mg) alloy. Results indicated that Mg could act as effective sacrificial anode to cathodically protect steel from corrosion attack once the SCPS was polluted by chlorides. Al alloying could enhance the sensitivity of Mg anode to chloride contamination and further improve its cathodic protection effect, and thus enhanced its intelligence level as Corrosivity detector and corrosion protector. The automatic Corrosivity detection and intelligent cathodic protection of Mg and AZ91 for steel were also validated in concrete.

Abdessamad Faik - One of the best experts on this subject based on the ideXlab platform.

  • unexpected effect of nanoparticles doping on the Corrosivity of molten nitrate salt for thermal energy storage
    Solar Energy Materials and Solar Cells, 2018
    Co-Authors: Yaroslav Grosu, Luis Gonzalezfernandez, Nithiyanantham Udayashankar, Oleksandr Bondarchuk, Abdessamad Faik
    Abstract:

    Abstract Molten nitrate salts are currently the most common mature solution for thermal energy storage at the concentrated solar power (CSP) plants. Enhancing heat capacity and thermal conductivity of molten salts via doping by inorganic nanoparticles has attracted an explosively increasing interest due to the possibility of a considerable decrease of the investment costs for CSP technology. However, to the best of our knowledge there is almost no information on the effect of such doping on the Corrosivity of the molten salts. In this work we demonstrate that adding small amounts of nanoparticles into the molten nitrate HitecXL salt considerably increases its Corrosivity and modifies the corrosion mechanisms. A set of advanced techniques such as SEM-EDX, XPS and XRD are applied to get insights into the effect of inorganic nano-additives on the corrosion phenomenon.