The Experts below are selected from a list of 18918 Experts worldwide ranked by ideXlab platform
Jiri Hromadka - One of the best experts on this subject based on the ideXlab platform.
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highly sensitive volatile organic compounds vapour measurements using a long period grating optical fibre sensor coated with metal organic framework zif 8
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique by mixing freshly prepared 12.5 mM zinc nitrate hexahydrate and 25 mM 2-metyl-imidazole solutions in methanol. A concentration specific response to acetone, ethanol and methanol vapour was obtained over the high concentration range up to tens thousands ppm. The LPG based sensor works at phase-matching turning point (PMTP) and such operates at the highest sensitivity. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The optimized sensor shows a sensitivity of 0.015 ± 0.001 and 0.018 ± 0.0015 nm/ppm and limit of detection (LOD) of 6.67 and 5.56 ppm for acetone and ethanol respectively.
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carbon dioxide measurements using long period grating optical fibre sensor coated with metal organic framework hkust 1
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based carbon dioxide (CO2) sensor coated with HKUST-1, a material from the metal organic framework family, functional coating is presented. In-situ Crystallization and layer by layer (LbL) Techniques of HKUST-1 thin film synthesis are compared in terms of the feasibility of the deposition procedure (time and cost efficiency) and the sensitivity of the film to carbon dioxide. The sensing mechanism is based on the measurement of the change of the refractive index (RI) of the coating that is induced by the penetration of CO2 molecules into the HKUST-1 pores. The HKUST-1 film was characterized by scanning electron microscopy (SEM). The thickness and refractive index (RI) of the 10, 20 and 40 layers thick films were determined using ellipsoetry. The crystallinity of the films was examined by X-ray diffraction pattern (XRD). While no response to CO2 was observed for the sensor coated using the in-situ Crystallization Technique, an LPG modified with 10, 20 and 40 layers of HKUST-1 films using LbL method upon exposure to CO2 in the range of 500 ppm to 40,000 ppm showed good sensitivity. The film containing 40 layers exhibited the highest sensitivity to CO2 with an obtained detection limit of 401 ppm.
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Highly sensitive ethanol vapour measurements using a fibre optic sensor coated with metal organic framework ZIF-8
2017 IEEE SENSORS, 2017Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique. A concentration specific response to ethanol was obtained over the range from 62 to 666 ppm. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The sensor shows a sensitivity of 0.018±0.0015 nm/ppm and limit of detection (LOD) of 5.56 ppm for ethanol vapour in air.
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optical fibre long period grating gas sensor modified with metal organic framework thin films
Sensors and Actuators B-chemical, 2015Co-Authors: Jiri Hromadka, Begum Tokay, Sergiy Korposh, Stephen W James, Ralph P TatamAbstract:An optical fibre long period grating (LPG) modified with a thin film of ZIF-8, zeolitic immidazol framework material, a subgroup of metal organic framework (MOF) family, was employed for the detection of organic vapours. ZIF-8 film was deposited onto the surface of the LPG using in-situ Crystallization Technique by mixing freshly prepared 12.5 mM zinc nitrate hexahydrate and 25 mM of 2-metyl-imidazole solutions in methanol. ZIF-8 film was characterized by scanning electron microscope (SEM) images, thickness and refractive index (RI) has been calculated with use of ellipsometer for films containing of 1,2,3,5 and 10 growth cycles. The crystallinity of the film was confirmed by x-ray diffraction pattern (XRD). The LPG sensor was designed to operate at the phase matching turning point to provide the highest sensitivity. The sensing mechanism is based on the measurement of the RI change induced by the penetration of the chemical molecules into the ZIF-8 pores. LPG modified with 2 and 5 growth cycles of ZIF-8 responded to exposure to methanol, ethanol, 2-propanol and acetone. The sensitivity of the measurements to humidity as an interfering parameter was also investigated.
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detection of volatile organic compounds using optical fibre long period grating modified with metal organic framework thin films
International Conference on Optical Fibre Sensors (OFS24), 2015Co-Authors: Jiri Hromadka, Begum Tokay, Sergiy Korposh, Stephen W James, Ralph P TatamAbstract:An optical fibre long period grating (LPG) modified with a thin film of ZIF-8, a zeolitic immidazol framework (ZIF) material, a subgroup of the metal organic framework (MOF) family, was employed for the detection of organic vapours. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique. The sensing mechanism is based on the measurement of the refractive index (RI) change induced by the penetration of the chemical molecules into the ZIF-8 pores. An LPG modified with 5 growth cycles of ZIF-8 responded to exposure to methanol and ethanol vapours.
Sergiy Korposh - One of the best experts on this subject based on the ideXlab platform.
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highly sensitive volatile organic compounds vapour measurements using a long period grating optical fibre sensor coated with metal organic framework zif 8
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique by mixing freshly prepared 12.5 mM zinc nitrate hexahydrate and 25 mM 2-metyl-imidazole solutions in methanol. A concentration specific response to acetone, ethanol and methanol vapour was obtained over the high concentration range up to tens thousands ppm. The LPG based sensor works at phase-matching turning point (PMTP) and such operates at the highest sensitivity. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The optimized sensor shows a sensitivity of 0.015 ± 0.001 and 0.018 ± 0.0015 nm/ppm and limit of detection (LOD) of 6.67 and 5.56 ppm for acetone and ethanol respectively.
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carbon dioxide measurements using long period grating optical fibre sensor coated with metal organic framework hkust 1
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based carbon dioxide (CO2) sensor coated with HKUST-1, a material from the metal organic framework family, functional coating is presented. In-situ Crystallization and layer by layer (LbL) Techniques of HKUST-1 thin film synthesis are compared in terms of the feasibility of the deposition procedure (time and cost efficiency) and the sensitivity of the film to carbon dioxide. The sensing mechanism is based on the measurement of the change of the refractive index (RI) of the coating that is induced by the penetration of CO2 molecules into the HKUST-1 pores. The HKUST-1 film was characterized by scanning electron microscopy (SEM). The thickness and refractive index (RI) of the 10, 20 and 40 layers thick films were determined using ellipsoetry. The crystallinity of the films was examined by X-ray diffraction pattern (XRD). While no response to CO2 was observed for the sensor coated using the in-situ Crystallization Technique, an LPG modified with 10, 20 and 40 layers of HKUST-1 films using LbL method upon exposure to CO2 in the range of 500 ppm to 40,000 ppm showed good sensitivity. The film containing 40 layers exhibited the highest sensitivity to CO2 with an obtained detection limit of 401 ppm.
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Highly sensitive ethanol vapour measurements using a fibre optic sensor coated with metal organic framework ZIF-8
2017 IEEE SENSORS, 2017Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique. A concentration specific response to ethanol was obtained over the range from 62 to 666 ppm. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The sensor shows a sensitivity of 0.018±0.0015 nm/ppm and limit of detection (LOD) of 5.56 ppm for ethanol vapour in air.
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optical fibre long period grating gas sensor modified with metal organic framework thin films
Sensors and Actuators B-chemical, 2015Co-Authors: Jiri Hromadka, Begum Tokay, Sergiy Korposh, Stephen W James, Ralph P TatamAbstract:An optical fibre long period grating (LPG) modified with a thin film of ZIF-8, zeolitic immidazol framework material, a subgroup of metal organic framework (MOF) family, was employed for the detection of organic vapours. ZIF-8 film was deposited onto the surface of the LPG using in-situ Crystallization Technique by mixing freshly prepared 12.5 mM zinc nitrate hexahydrate and 25 mM of 2-metyl-imidazole solutions in methanol. ZIF-8 film was characterized by scanning electron microscope (SEM) images, thickness and refractive index (RI) has been calculated with use of ellipsometer for films containing of 1,2,3,5 and 10 growth cycles. The crystallinity of the film was confirmed by x-ray diffraction pattern (XRD). The LPG sensor was designed to operate at the phase matching turning point to provide the highest sensitivity. The sensing mechanism is based on the measurement of the RI change induced by the penetration of the chemical molecules into the ZIF-8 pores. LPG modified with 2 and 5 growth cycles of ZIF-8 responded to exposure to methanol, ethanol, 2-propanol and acetone. The sensitivity of the measurements to humidity as an interfering parameter was also investigated.
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detection of volatile organic compounds using optical fibre long period grating modified with metal organic framework thin films
International Conference on Optical Fibre Sensors (OFS24), 2015Co-Authors: Jiri Hromadka, Begum Tokay, Sergiy Korposh, Stephen W James, Ralph P TatamAbstract:An optical fibre long period grating (LPG) modified with a thin film of ZIF-8, a zeolitic immidazol framework (ZIF) material, a subgroup of the metal organic framework (MOF) family, was employed for the detection of organic vapours. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique. The sensing mechanism is based on the measurement of the refractive index (RI) change induced by the penetration of the chemical molecules into the ZIF-8 pores. An LPG modified with 5 growth cycles of ZIF-8 responded to exposure to methanol and ethanol vapours.
Begum Tokay - One of the best experts on this subject based on the ideXlab platform.
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highly sensitive volatile organic compounds vapour measurements using a long period grating optical fibre sensor coated with metal organic framework zif 8
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique by mixing freshly prepared 12.5 mM zinc nitrate hexahydrate and 25 mM 2-metyl-imidazole solutions in methanol. A concentration specific response to acetone, ethanol and methanol vapour was obtained over the high concentration range up to tens thousands ppm. The LPG based sensor works at phase-matching turning point (PMTP) and such operates at the highest sensitivity. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The optimized sensor shows a sensitivity of 0.015 ± 0.001 and 0.018 ± 0.0015 nm/ppm and limit of detection (LOD) of 6.67 and 5.56 ppm for acetone and ethanol respectively.
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carbon dioxide measurements using long period grating optical fibre sensor coated with metal organic framework hkust 1
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based carbon dioxide (CO2) sensor coated with HKUST-1, a material from the metal organic framework family, functional coating is presented. In-situ Crystallization and layer by layer (LbL) Techniques of HKUST-1 thin film synthesis are compared in terms of the feasibility of the deposition procedure (time and cost efficiency) and the sensitivity of the film to carbon dioxide. The sensing mechanism is based on the measurement of the change of the refractive index (RI) of the coating that is induced by the penetration of CO2 molecules into the HKUST-1 pores. The HKUST-1 film was characterized by scanning electron microscopy (SEM). The thickness and refractive index (RI) of the 10, 20 and 40 layers thick films were determined using ellipsoetry. The crystallinity of the films was examined by X-ray diffraction pattern (XRD). While no response to CO2 was observed for the sensor coated using the in-situ Crystallization Technique, an LPG modified with 10, 20 and 40 layers of HKUST-1 films using LbL method upon exposure to CO2 in the range of 500 ppm to 40,000 ppm showed good sensitivity. The film containing 40 layers exhibited the highest sensitivity to CO2 with an obtained detection limit of 401 ppm.
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Highly sensitive ethanol vapour measurements using a fibre optic sensor coated with metal organic framework ZIF-8
2017 IEEE SENSORS, 2017Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique. A concentration specific response to ethanol was obtained over the range from 62 to 666 ppm. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The sensor shows a sensitivity of 0.018±0.0015 nm/ppm and limit of detection (LOD) of 5.56 ppm for ethanol vapour in air.
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optical fibre long period grating gas sensor modified with metal organic framework thin films
Sensors and Actuators B-chemical, 2015Co-Authors: Jiri Hromadka, Begum Tokay, Sergiy Korposh, Stephen W James, Ralph P TatamAbstract:An optical fibre long period grating (LPG) modified with a thin film of ZIF-8, zeolitic immidazol framework material, a subgroup of metal organic framework (MOF) family, was employed for the detection of organic vapours. ZIF-8 film was deposited onto the surface of the LPG using in-situ Crystallization Technique by mixing freshly prepared 12.5 mM zinc nitrate hexahydrate and 25 mM of 2-metyl-imidazole solutions in methanol. ZIF-8 film was characterized by scanning electron microscope (SEM) images, thickness and refractive index (RI) has been calculated with use of ellipsometer for films containing of 1,2,3,5 and 10 growth cycles. The crystallinity of the film was confirmed by x-ray diffraction pattern (XRD). The LPG sensor was designed to operate at the phase matching turning point to provide the highest sensitivity. The sensing mechanism is based on the measurement of the RI change induced by the penetration of the chemical molecules into the ZIF-8 pores. LPG modified with 2 and 5 growth cycles of ZIF-8 responded to exposure to methanol, ethanol, 2-propanol and acetone. The sensitivity of the measurements to humidity as an interfering parameter was also investigated.
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detection of volatile organic compounds using optical fibre long period grating modified with metal organic framework thin films
International Conference on Optical Fibre Sensors (OFS24), 2015Co-Authors: Jiri Hromadka, Begum Tokay, Sergiy Korposh, Stephen W James, Ralph P TatamAbstract:An optical fibre long period grating (LPG) modified with a thin film of ZIF-8, a zeolitic immidazol framework (ZIF) material, a subgroup of the metal organic framework (MOF) family, was employed for the detection of organic vapours. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique. The sensing mechanism is based on the measurement of the refractive index (RI) change induced by the penetration of the chemical molecules into the ZIF-8 pores. An LPG modified with 5 growth cycles of ZIF-8 responded to exposure to methanol and ethanol vapours.
Stephen P Morgan - One of the best experts on this subject based on the ideXlab platform.
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highly sensitive volatile organic compounds vapour measurements using a long period grating optical fibre sensor coated with metal organic framework zif 8
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique by mixing freshly prepared 12.5 mM zinc nitrate hexahydrate and 25 mM 2-metyl-imidazole solutions in methanol. A concentration specific response to acetone, ethanol and methanol vapour was obtained over the high concentration range up to tens thousands ppm. The LPG based sensor works at phase-matching turning point (PMTP) and such operates at the highest sensitivity. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The optimized sensor shows a sensitivity of 0.015 ± 0.001 and 0.018 ± 0.0015 nm/ppm and limit of detection (LOD) of 6.67 and 5.56 ppm for acetone and ethanol respectively.
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carbon dioxide measurements using long period grating optical fibre sensor coated with metal organic framework hkust 1
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based carbon dioxide (CO2) sensor coated with HKUST-1, a material from the metal organic framework family, functional coating is presented. In-situ Crystallization and layer by layer (LbL) Techniques of HKUST-1 thin film synthesis are compared in terms of the feasibility of the deposition procedure (time and cost efficiency) and the sensitivity of the film to carbon dioxide. The sensing mechanism is based on the measurement of the change of the refractive index (RI) of the coating that is induced by the penetration of CO2 molecules into the HKUST-1 pores. The HKUST-1 film was characterized by scanning electron microscopy (SEM). The thickness and refractive index (RI) of the 10, 20 and 40 layers thick films were determined using ellipsoetry. The crystallinity of the films was examined by X-ray diffraction pattern (XRD). While no response to CO2 was observed for the sensor coated using the in-situ Crystallization Technique, an LPG modified with 10, 20 and 40 layers of HKUST-1 films using LbL method upon exposure to CO2 in the range of 500 ppm to 40,000 ppm showed good sensitivity. The film containing 40 layers exhibited the highest sensitivity to CO2 with an obtained detection limit of 401 ppm.
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Highly sensitive ethanol vapour measurements using a fibre optic sensor coated with metal organic framework ZIF-8
2017 IEEE SENSORS, 2017Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique. A concentration specific response to ethanol was obtained over the range from 62 to 666 ppm. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The sensor shows a sensitivity of 0.018±0.0015 nm/ppm and limit of detection (LOD) of 5.56 ppm for ethanol vapour in air.
Ricardo Correia - One of the best experts on this subject based on the ideXlab platform.
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highly sensitive volatile organic compounds vapour measurements using a long period grating optical fibre sensor coated with metal organic framework zif 8
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique by mixing freshly prepared 12.5 mM zinc nitrate hexahydrate and 25 mM 2-metyl-imidazole solutions in methanol. A concentration specific response to acetone, ethanol and methanol vapour was obtained over the high concentration range up to tens thousands ppm. The LPG based sensor works at phase-matching turning point (PMTP) and such operates at the highest sensitivity. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The optimized sensor shows a sensitivity of 0.015 ± 0.001 and 0.018 ± 0.0015 nm/ppm and limit of detection (LOD) of 6.67 and 5.56 ppm for acetone and ethanol respectively.
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carbon dioxide measurements using long period grating optical fibre sensor coated with metal organic framework hkust 1
Sensors and Actuators B-chemical, 2018Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based carbon dioxide (CO2) sensor coated with HKUST-1, a material from the metal organic framework family, functional coating is presented. In-situ Crystallization and layer by layer (LbL) Techniques of HKUST-1 thin film synthesis are compared in terms of the feasibility of the deposition procedure (time and cost efficiency) and the sensitivity of the film to carbon dioxide. The sensing mechanism is based on the measurement of the change of the refractive index (RI) of the coating that is induced by the penetration of CO2 molecules into the HKUST-1 pores. The HKUST-1 film was characterized by scanning electron microscopy (SEM). The thickness and refractive index (RI) of the 10, 20 and 40 layers thick films were determined using ellipsoetry. The crystallinity of the films was examined by X-ray diffraction pattern (XRD). While no response to CO2 was observed for the sensor coated using the in-situ Crystallization Technique, an LPG modified with 10, 20 and 40 layers of HKUST-1 films using LbL method upon exposure to CO2 in the range of 500 ppm to 40,000 ppm showed good sensitivity. The film containing 40 layers exhibited the highest sensitivity to CO2 with an obtained detection limit of 401 ppm.
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Highly sensitive ethanol vapour measurements using a fibre optic sensor coated with metal organic framework ZIF-8
2017 IEEE SENSORS, 2017Co-Authors: Jiri Hromadka, Begum Tokay, Ricardo Correia, Stephen P Morgan, Sergiy KorposhAbstract:An optical fibre long period grating (LPG) based volatile organic compound (VOC) sensor coated with ZIF-8, a material from the zeolite imidazolate framework (ZIF) family, functional coating is presented. ZIF-8 film was deposited onto the surface of the LPG using an in-situ Crystallization Technique. A concentration specific response to ethanol was obtained over the range from 62 to 666 ppm. A novel approach for the data analysis based on the measurement of the bandwidth of the U-shaped attenuation band of the LPG is introduced. The sensor shows a sensitivity of 0.018±0.0015 nm/ppm and limit of detection (LOD) of 5.56 ppm for ethanol vapour in air.