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Ben Bradshaw - One of the best experts on this subject based on the ideXlab platform.
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synthesis of cis hydrindan 2 4 diones bearing an all carbon quaternary center by a Danheiser Annulation
Beilstein Journal of Organic Chemistry, 2018Co-Authors: Gisela V Saborit, Carlos Cativiela, Ana I Jimenez, Josep Bonjoch, Ben BradshawAbstract:: A straightforward synthetic entry to functionalized hydrindane compounds based on a rapid assembly of the core nucleus by a Danheiser cycloaddition is reported. Valuable bicyclic building blocks containing the fused five and six-membered carbocyclic ring system can be achieved in only four steps from a simple acyclic β-keto ester.
Gisela V Saborit - One of the best experts on this subject based on the ideXlab platform.
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synthesis of cis hydrindan 2 4 diones bearing an all carbon quaternary center by a Danheiser Annulation
Beilstein Journal of Organic Chemistry, 2018Co-Authors: Gisela V Saborit, Carlos Cativiela, Ana I Jimenez, Josep Bonjoch, Ben BradshawAbstract:: A straightforward synthetic entry to functionalized hydrindane compounds based on a rapid assembly of the core nucleus by a Danheiser cycloaddition is reported. Valuable bicyclic building blocks containing the fused five and six-membered carbocyclic ring system can be achieved in only four steps from a simple acyclic β-keto ester.
Jie Jack Li - One of the best experts on this subject based on the ideXlab platform.
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Name Reactions A Collection of Detailed Mechanisms and Synthetic Applications
2020Co-Authors: Jie Jack LiAbstract:Alder ene reaction -- Aldol condensation -- Algar-Flynn-Oyamada Reaction -- Allan-Robinson reaction -- Appel reaction -- Arndt-Eistert homologation -- Baeyer-Villiger oxidation -- Baker-Venkataraman rearrangement -- Bamberger rearrangement -- Bamford-Stevens reaction -- Barbier coupling reaction -- Bargellini reaction -- Bartoli indole synthesis -- Barton radical decarboxylation -- Barton-McCombie deoxygenation -- Barton nitrite photolysis -- Barton-Zard reaction -- Batcho-Leimgruber indole synthesis -- Baylis-Hillman reaction -- Beckmann rearrangement -- Beirut reaction -- Benzilic acid rearrangement -- Benzoin condensation -- Bergman cyclization -- Biginelli pyrimidone synthesis -- Birch reduction -- Bischler-Mohlau indole synthesis -- Bischler-Napieralski reaction -- Blaise reaction -- Blanc chloromethylation -- Blum aziridine synthesis -- Boekelheide reaction -- Boger pyridine synthesis -- Borch reductive amination -- Borsche-Drechsel cyclization -- Boulton-Katritzky rearrangement -- Bouveault aldehyde synthesis -- Bouveault-Blanc reduction -- Boyland-Sims oxidation -- Bradsher reaction -- Brook rearrangement -- Brown hydroboration -- Bucherer carbazole synthesis -- Bucherer reaction -- Bucherer-Bergs reaction -- Buchner-Curtius-Schlotterbeck reaction -- Buchner method of ring expansion -- Buchwald-Hartwig C-N and C-O bond formation reactions -- Burgess dehydrating reagent -- Cadiot-Chodkiewicz coupling -- Camps quinolinol synthesis -- Cannizzaro disproportionation -- Carroll rearrangement -- Castro-Stephens coupling -- Chan alkyne reduction -- Chan-Lam coupling reaction -- Chapman rearrangement -- Chichibabin pyridine synthesis -- Chugaev elimination -- Ciamician-Dennsted rearrangement -- Claisen condensation -- Claisen isoxazole synthesis -- Claisen rearrangements -- Clemmensen reduction -- Combes quinoline synthesis -- Conrad-Limpach reaction -- Cope elimination reaction -- Cope rearrangement -- Corey-Bakshi-Shibata (CBS) reduction -- Corey-Chaykovsky reaction -- Corey-Fuchs reaction -- Corey-Kim oxidation -- Corey-Nicolaou macrolactonization -- Corey-Seebach reaction -- Corey-Winter olefin synthesis -- Criegee glycol cleavage -- Criegee mechanism of ozonolysis -- Curtius rearrangement -- Dakin oxidation -- Dakin-West reaction -- Danheiser Annulation -- Darzens glycidic ester condensation -- Davis chiral oxaziridine reagents -- Delepine amine synthesis -- de Mayo reaction -- Demjanov rearrangement -- Dess-Martin periodinane oxidation -- Dieckmann condensation -- Diels-Alder reaction -- Dienone-phenol rearrangement -- Di-?-methane rearrangement -- Doebner quinoline synthesis -- Dotz reaction -- Dowd-Beckwith ring expansion -- Erlenmeyer-Plochl azlactone synthesis -- Eschenmoser-Tanabe fragmentation -- Eschweiler-Clarke reductive alkylation of amines -- Evans aldol reaction -- Favorskii rearrangement and quasi-Favorskii rearrangement -- Feist-Benary furan synthesis -- Ferrier carbocyclization -- Ferrier glycal allylic rearrangement -- Fiesselmann thiophene synthesis -- Fischer indole synthesis -- Fischer oxazole synthesis -- Fleming-Kumada oxidation -- Friedel-Crafts reaction -- Friedlander quinoline synthesis -- Fries rearrangement -- Fukuyama amine synthesis -- Fukuyama reduction -- Gabriel synthesis -- Gabriel-Colman rearrangement -- Gassman indole synthesis -- Gattermann-Koch reaction -- Gewald aminothiophene synthesis -- Glaser coupling -- Gomberg-Bachmann reaction -- Gould-Jacobs reaction -- Grignard reaction -- Grob fragmentation -- Guareschi-Thorpe condensation -- Hajos-Wiechert reaction -- Haller-Bauer reaction -- Hantzsch dihydropyridine synthesis -- Hantzsch pyrrole synthesis -- Heck reaction -- Hegedus indole synthesis -- Hell-Volhard-Zelinsky reaction -- Henry nitroaldol reaction -- Hinsberg synthesis of thiophene derivatives -- Hiyama cross-coupling reaction -- Hofmann rearrangement -- Hofmann-Loffler-Freytag reaction -- Horner-Wadsworth-Emmons reaction -- Houben-Hoesch reaction -- Hunsdiecker-Borodin reaction -- Hurd-Mori 1,2,3-thiadiazole synthesis -- Jacobsen-Katsuki epoxidation -- Japp-Klingemann hydrazone synthesis -- Jones oxidation -- Julia-Kocienski olefination -- Julia-Lythgoe olefination -- Kahne-Crich glycosidation -- Keck macrolactonization -- Knoevenagel condensation -- Knorr pyrazole synthesis -- Koch-Haaf carbonylation -- Koenig-Knorr glycosidation -- Kolbe-Schmitt reaction -- Kostanecki reaction -- Krohnke pyridine synthesis -- Kumada cross-coupling reaction -- Lawesson’s reagent -- Leuckart-Wallach reaction -- Lossen rearrangement -- McFadyen-Stevens reduction -- McMurry coupling -- MacMillan catalyst -- Mannich reaction -- Marshall boronate fragmentation -- Martin’s sulfurane dehydrating reagent -- Masamune-Roush conditions -- Meerwein-Ponndorf-Verley reduction -- Meisenheimer complex -- [1,2]-Meisenheimer rearrangement -- [2,3]-Meisenheimer rearrangement -- Meth-Cohn quinoline synthesis -- Meyers oxazoline method -- Meyer-Schuster rearrangement -- Michael addition -- Michaelis-Arbuzov phosphonate synthesis -- Midland reduction -- Mislow-Evans rearrangement -- Mitsunobu reaction -- Miyaura borylation -- Moffatt oxidation -- Montgomery coupling -- Morgan-Walls reaction -- Mori-Ban indole synthesis -- Mukaiyama aldol reaction -- Mukaiyama Michael addition -- Mukaiyama reagent -- Myers-Saito cyclization -- Nazarov cyclization -- Neber rearrangement -- Nef reaction -- Negishi cross-coupling reaction -- Nenitzescu indole synthesis -- Nicholas reaction -- Nicolaou dehydrogenation -- Nicolaou hydroxy-dithioketal cyclization -- Nicolaou hydroxy-ketone reductive cyclic ether formation -- Nicolaou oxyselenation -- Noyori asymmetric hydrogenation -- Nozaki-Hiyama-Kishi reaction -- Oppenauer oxidation -- Overman rearrangement -- Paal thiophene synthesis -- Paal-Knorr furan synthesis -- Parham cyclization -- Passerini reaction -- Paterno-Buchi reaction -- Pauson-Khand cyclopentenone synthesis -- Payne rearrangement -- Pechmann coumarin synthesis -- Perkin reaction -- Petasis reaction -- Peterson olefination -- Pictet-Gams isoquinoline synthesis -- Pictet-Spengler tetrahydroisoquinoline synthesis -- Pinacol rearrangement -- Pinner reaction -- Polonovski reaction -- Polonovski-Potier reaction -- Pomeranz-Fritsch reaction -- Prevost trans-dihydroxylation -- Prins reaction -- Pschorr cyclization -- Pummerer rearrangement -- Ramberg-Backlund reaction -- Reformatsky reaction -- Regitz diazo synthesis -- Reimer-Tiemann reaction -- Reissert aldehyde synthesis -- Reissert indole synthesis -- Ring-closing metathesis (RCM) -- Ritter reaction -- Robinson Annulation -- Robinson-Gabriel synthesis -- Robinson-Schopf reaction -- Rosenmund reduction -- Rubottom oxidation -- Rupe rearrangement -- Saegusa oxidation -- Sakurai allylation reaction -- Sandmeyer reaction -- Schiemann reaction -- Schmidt reaction -- Schmidt’s trichloroacetimidate glycosidation reaction -- Shapiro reaction -- Sharpless asymmetric amino hydroxylation -- Sharpless asymmetric epoxidation -- Sharpless asymmetric dihydroxylation -- Sharpless olefin synthesis -- Simmons-Smith reaction -- Skraup quinoline synthesis -- Smiles rearrangement -- Sommelet reaction -- Sommelet-Hauser rearrangement -- Sonogashira reaction -- Staudinger ketene cycloaddition -- Staudinger reduction -- Sternbach benzodiazepine synthesis -- Stetter reaction -- Still-Gennari phosphonate reaction -- Stille coupling -- Stille-Kelly reaction -- Stobbe condensation -- Stork enamine reaction -- Strecker amino acid synthesis -- Suzuki coupling -- Swern oxidation -- Takai iodoalkene synthesis -- Tebbe olefination -- TEMPO-mediated oxidation -- Thorpe-Ziegler reaction -- Tsuji-Trost reaction -- Ugi reaction -- Ullmann reaction -- van Leusen oxazole synthesis -- Vilsmeier-Haack reaction -- Vilsmeier mechanism for acid chloride formation -- Vinylcyclopropane-cyclopentene rearrangement -- von Braun reaction -- Wacker oxidation -- Wagner-Meerwein rearrangement -- Weiss-Cook reaction -- Wharton oxygen transposition reaction -- Willgerodt-Kindler reaction -- Wittig reaction -- [1,2]-Wittig rearrangement -- [2,3]-Wittig rearrangement -- Wohl-Ziegler reaction -- Wolff rearrangement -- Wolff-Kishner reduction -- Yamaguchi esterification -- Zincke reaction.
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Name Reactions: A Collection of Detailed Reaction Mechanisms
2002Co-Authors: Jie Jack LiAbstract:Alder ene reaction -- Aldol condensation -- Algar-Flynn-Oyamada Reaction -- Allan-Robinson reaction -- Appel reaction -- Arndt-Eistert homologation -- Baeyer-Villiger oxidation -- Baker-Venkataraman rearrangement -- Bamberger rearrangement -- Bamford-Stevens reaction -- Barbier coupling reaction -- Bargellini reaction -- Bartoli indole synthesis -- Barton radical decarboxylation -- Barton-McCombie deoxygenation -- Barton nitrite photolysis -- Barton-Zard reaction -- Batcho-Leimgruber indole synthesis -- Baylis-Hillman reaction -- Beckmann rearrangement -- Beirut reaction -- Benzilic acid rearrangement -- Benzoin condensation -- Bergman cyclization -- Biginelli pyrimidone synthesis -- Birch reduction -- Bischler-Mohlau indole synthesis -- Bischler-Napieralski reaction -- Blaise reaction -- Blanc chloromethylation -- Blum aziridine synthesis -- Boekelheide reaction -- Boger pyridine synthesis -- Borch reductive amination -- Borsche-Drechsel cyclization -- Boulton-Katritzky rearrangement -- Bouveault aldehyde synthesis -- Bouveault-Blanc reduction -- Boyland-Sims oxidation -- Bradsher reaction -- Brook rearrangement -- Brown hydroboration -- Bucherer carbazole synthesis -- Bucherer reaction -- Bucherer-Bergs reaction -- Buchner-Curtius-Schlotterbeck reaction -- Buchner method of ring expansion -- Buchwald-Hartwig C-N and C-O bond formation reactions -- Burgess dehydrating reagent -- Cadiot-Chodkiewicz coupling -- Camps quinolinol synthesis -- Cannizzaro disproportionation -- Carroll rearrangement -- Castro-Stephens coupling -- Chan alkyne reduction -- Chan-Lam coupling reaction -- Chapman rearrangement -- Chichibabin pyridine synthesis -- Chugaev elimination -- Ciamician-Dennsted rearrangement -- Claisen condensation -- Claisen isoxazole synthesis -- Claisen rearrangements -- Clemmensen reduction -- Combes quinoline synthesis -- Conrad-Limpach reaction -- Cope elimination reaction -- Cope rearrangement -- Corey-Bakshi-Shibata (CBS) reduction -- Corey-Chaykovsky reaction -- Corey-Fuchs reaction -- Corey-Kim oxidation -- Corey-Nicolaou macrolactonization -- Corey-Seebach reaction -- Corey-Winter olefin synthesis -- Criegee glycol cleavage -- Criegee mechanism of ozonolysis -- Curtius rearrangement -- Dakin oxidation -- Dakin-West reaction -- Danheiser Annulation -- Darzens glycidic ester condensation -- Davis chiral oxaziridine reagents -- Delepine amine synthesis -- de Mayo reaction -- Demjanov rearrangement -- Dess-Martin periodinane oxidation -- Dieckmann condensation -- Diels-Alder reaction -- Dienone-phenol rearrangement -- Di-?-methane rearrangement -- Doebner quinoline synthesis -- Dotz reaction -- Dowd-Beckwith ring expansion -- Erlenmeyer-Plochl azlactone synthesis -- Eschenmoser-Tanabe fragmentation -- Eschweiler-Clarke reductive alkylation of amines -- Evans aldol reaction -- Favorskii rearrangement and quasi-Favorskii rearrangement -- Feist-Benary furan synthesis -- Ferrier carbocyclization -- Ferrier glycal allylic rearrangement -- Fiesselmann thiophene synthesis -- Fischer indole synthesis -- Fischer oxazole synthesis -- Fleming-Kumada oxidation -- Friedel-Crafts reaction -- Friedlander quinoline synthesis -- Fries rearrangement -- Fukuyama amine synthesis -- Fukuyama reduction -- Gabriel synthesis -- Gabriel-Colman rearrangement -- Gassman indole synthesis -- Gattermann-Koch reaction -- Gewald aminothiophene synthesis -- Glaser coupling -- Gomberg-Bachmann reaction -- Gould-Jacobs reaction -- Grignard reaction -- Grob fragmentation -- Guareschi-Thorpe condensation -- Hajos-Wiechert reaction -- Haller-Bauer reaction -- Hantzsch dihydropyridine synthesis -- Hantzsch pyrrole synthesis -- Heck reaction -- Hegedus indole synthesis -- Hell-Volhard-Zelinsky reaction -- Henry nitroaldol reaction -- Hinsberg synthesis of thiophene derivatives -- Hiyama cross-coupling reaction -- Hofmann rearrangement -- Hofmann-Loffler-Freytag reaction -- Horner-Wadsworth-Emmons reaction -- Houben-Hoesch reaction -- Hunsdiecker-Borodin reaction -- Hurd-Mori 1,2,3-thiadiazole synthesis -- Jacobsen-Katsuki epoxidation -- Japp-Klingemann hydrazone synthesis -- Jones oxidation -- Julia-Kocienski olefination -- Julia-Lythgoe olefination -- Kahne-Crich glycosidation -- Keck macrolactonization -- Knoevenagel condensation -- Knorr pyrazole synthesis -- Koch-Haaf carbonylation -- Koenig-Knorr glycosidation -- Kolbe-Schmitt reaction -- Kostanecki reaction -- Krohnke pyridine synthesis -- Kumada cross-coupling reaction -- Lawesson’s reagent -- Leuckart-Wallach reaction -- Lossen rearrangement -- McFadyen-Stevens reduction -- McMurry coupling -- MacMillan catalyst -- Mannich reaction -- Marshall boronate fragmentation -- Martin’s sulfurane dehydrating reagent -- Masamune-Roush conditions -- Meerwein-Ponndorf-Verley reduction -- Meisenheimer complex -- [1,2]-Meisenheimer rearrangement -- [2,3]-Meisenheimer rearrangement -- Meth-Cohn quinoline synthesis -- Meyers oxazoline method -- Meyer-Schuster rearrangement -- Michael addition -- Michaelis-Arbuzov phosphonate synthesis -- Midland reduction -- Mislow-Evans rearrangement -- Mitsunobu reaction -- Miyaura borylation -- Moffatt oxidation -- Montgomery coupling -- Morgan-Walls reaction -- Mori-Ban indole synthesis -- Mukaiyama aldol reaction -- Mukaiyama Michael addition -- Mukaiyama reagent -- Myers-Saito cyclization -- Nazarov cyclization -- Neber rearrangement -- Nef reaction -- Negishi cross-coupling reaction -- Nenitzescu indole synthesis -- Nicholas reaction -- Nicolaou dehydrogenation -- Nicolaou hydroxy-dithioketal cyclization -- Nicolaou hydroxy-ketone reductive cyclic ether formation -- Nicolaou oxyselenation -- Noyori asymmetric hydrogenation -- Nozaki-Hiyama-Kishi reaction -- Oppenauer oxidation -- Overman rearrangement -- Paal thiophene synthesis -- Paal-Knorr furan synthesis -- Parham cyclization -- Passerini reaction -- Paterno-Buchi reaction -- Pauson-Khand cyclopentenone synthesis -- Payne rearrangement -- Pechmann coumarin synthesis -- Perkin reaction -- Petasis reaction -- Peterson olefination -- Pictet-Gams isoquinoline synthesis -- Pictet-Spengler tetrahydroisoquinoline synthesis -- Pinacol rearrangement -- Pinner reaction -- Polonovski reaction -- Polonovski-Potier reaction -- Pomeranz-Fritsch reaction -- Prevost trans-dihydroxylation -- Prins reaction -- Pschorr cyclization -- Pummerer rearrangement -- Ramberg-Backlund reaction -- Reformatsky reaction -- Regitz diazo synthesis -- Reimer-Tiemann reaction -- Reissert aldehyde synthesis -- Reissert indole synthesis -- Ring-closing metathesis (RCM) -- Ritter reaction -- Robinson Annulation -- Robinson-Gabriel synthesis -- Robinson-Schopf reaction -- Rosenmund reduction -- Rubottom oxidation -- Rupe rearrangement -- Saegusa oxidation -- Sakurai allylation reaction -- Sandmeyer reaction -- Schiemann reaction -- Schmidt reaction -- Schmidt’s trichloroacetimidate glycosidation reaction -- Shapiro reaction -- Sharpless asymmetric amino hydroxylation -- Sharpless asymmetric epoxidation -- Sharpless asymmetric dihydroxylation -- Sharpless olefin synthesis -- Simmons-Smith reaction -- Skraup quinoline synthesis -- Smiles rearrangement -- Sommelet reaction -- Sommelet-Hauser rearrangement -- Sonogashira reaction -- Staudinger ketene cycloaddition -- Staudinger reduction -- Sternbach benzodiazepine synthesis -- Stetter reaction -- Still-Gennari phosphonate reaction -- Stille coupling -- Stille-Kelly reaction -- Stobbe condensation -- Stork enamine reaction -- Strecker amino acid synthesis -- Suzuki coupling -- Swern oxidation -- Takai iodoalkene synthesis -- Tebbe olefination -- TEMPO-mediated oxidation -- Thorpe-Ziegler reaction -- Tsuji-Trost reaction -- Ugi reaction -- Ullmann reaction -- van Leusen oxazole synthesis -- Vilsmeier-Haack reaction -- Vilsmeier mechanism for acid chloride formation -- Vinylcyclopropane-cyclopentene rearrangement -- von Braun reaction -- Wacker oxidation -- Wagner-Meerwein rearrangement -- Weiss-Cook reaction -- Wharton oxygen transposition reaction -- Willgerodt-Kindler reaction -- Wittig reaction -- [1,2]-Wittig rearrangement -- [2,3]-Wittig rearrangement -- Wohl-Ziegler reaction -- Wolff rearrangement -- Wolff-Kishner reduction -- Yamaguchi esterification -- Zincke reaction.
Carlos Cativiela - One of the best experts on this subject based on the ideXlab platform.
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synthesis of cis hydrindan 2 4 diones bearing an all carbon quaternary center by a Danheiser Annulation
Beilstein Journal of Organic Chemistry, 2018Co-Authors: Gisela V Saborit, Carlos Cativiela, Ana I Jimenez, Josep Bonjoch, Ben BradshawAbstract:: A straightforward synthetic entry to functionalized hydrindane compounds based on a rapid assembly of the core nucleus by a Danheiser cycloaddition is reported. Valuable bicyclic building blocks containing the fused five and six-membered carbocyclic ring system can be achieved in only four steps from a simple acyclic β-keto ester.
Ana I Jimenez - One of the best experts on this subject based on the ideXlab platform.
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synthesis of cis hydrindan 2 4 diones bearing an all carbon quaternary center by a Danheiser Annulation
Beilstein Journal of Organic Chemistry, 2018Co-Authors: Gisela V Saborit, Carlos Cativiela, Ana I Jimenez, Josep Bonjoch, Ben BradshawAbstract:: A straightforward synthetic entry to functionalized hydrindane compounds based on a rapid assembly of the core nucleus by a Danheiser cycloaddition is reported. Valuable bicyclic building blocks containing the fused five and six-membered carbocyclic ring system can be achieved in only four steps from a simple acyclic β-keto ester.
