The Experts below are selected from a list of 309 Experts worldwide ranked by ideXlab platform
Yang Liu - One of the best experts on this subject based on the ideXlab platform.
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Ionic liquids in surface Electrochemistry
Physical chemistry chemical physics : PCCP, 2010Co-Authors: Hongtao Liu, Yang LiuAbstract:Ionic liquids (IL) are widely used in Electrochemistry due to their excellent properties such as good ionic conductivity, wide electrochemical potential window, high viscosity, high thermal stability, wide liquid range and tunable solvent properties. In Electrochemistry, the performance of an electrochemical system is dependent on the properties of the interface at the IL/electrode. This review presents the surface Electrochemistry in ILs, and the interfacial structures of IL/electrode and heterogeneous electron-transfer kinetics are detailed. Finally, the updated researches on the electrochemical applications of ILs such as electrode deposition, electrosynthesis, electrocatalysis, electrochemical biosensing, electrochemical capacitor and lithium batteries are demonstrated.
Antonio Doménech-carbó - One of the best experts on this subject based on the ideXlab platform.
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Theoretical scenarios for the Electrochemistry of porous silicate-based materials: an overview
Journal of Solid State Electrochemistry, 2015Co-Authors: Antonio Doménech-carbóAbstract:The theoretical approaches on the Electrochemistry of silicate-based porous materials are reviewed with particular attention to the intrazeolite vs. extrazeolite debate in the context of zeolite Electrochemistry. It is discussed the Electrochemistry of different topological redox isomers for electroactive species encapsulated into nanocages via ship-in-a-bottle synthesis and that of structural species. It is emphasized the interest in describing diffusional problems in the light of existing modeling for ion-insertion solids directly dealing with the voltammetry of immobilized particles methodology. Theoretical approaches to describe the role of redox mediators and electrocatalysis are also presented.
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Electrochemistry supported by zeolites, clays, layered double hydroxides, ordered mesoporous (organo)silicas, and related materials
Journal of Solid State Electrochemistry, 2015Co-Authors: Antonio Doménech-carbó, Alain WalcariusAbstract:In the last decades, there is an increasingly growing interest in the Electrochemistry of a series of ordered solids based on zeolites, clays, layered double hydroxides, and other materials having in common a nanostructured porous inorganic matrix able to be permeated with organic and inorganic species. Such materials comprise a variety of nanoarchitectures in relation to the shape and size of the crystals and their cavities, pores, channels, etc., from microporous to mesoporous, and a variety of guest species, from neutral molecules to cationic and anionic guests. The synergistic combination of site isolation and ion exchange or adsorption capacity of these materials has motivated their exploitation in the Electrochemistry domain for catalysis, energy production and storage, and sensing. The current issue of Journal of Solid State Electrochemistry is devoted to present a picture of the state of the art in this field covering the different aspects directly dealing with the intersection between materials science and Electrochemistry.
Hongtao Liu - One of the best experts on this subject based on the ideXlab platform.
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Ionic liquids in surface Electrochemistry
Physical chemistry chemical physics : PCCP, 2010Co-Authors: Hongtao Liu, Yang LiuAbstract:Ionic liquids (IL) are widely used in Electrochemistry due to their excellent properties such as good ionic conductivity, wide electrochemical potential window, high viscosity, high thermal stability, wide liquid range and tunable solvent properties. In Electrochemistry, the performance of an electrochemical system is dependent on the properties of the interface at the IL/electrode. This review presents the surface Electrochemistry in ILs, and the interfacial structures of IL/electrode and heterogeneous electron-transfer kinetics are detailed. Finally, the updated researches on the electrochemical applications of ILs such as electrode deposition, electrosynthesis, electrocatalysis, electrochemical biosensing, electrochemical capacitor and lithium batteries are demonstrated.
Owen R. Lozman - One of the best experts on this subject based on the ideXlab platform.
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Synthesis of liquid crystalline anthraquinolyl-triphenylenes
Tetrahedron Letters, 2000Co-Authors: Graeme Cooke, Neetu Kaushal, Neville Boden, Richard J. Bushby, Owen R. LozmanAbstract:Abstract The synthesis, Electrochemistry and mesogenic properties of novel anthraquinolyl–triphenylenes are described. 1 H NMR, UV–vis, solution Electrochemistry and molecular modelling studies indicate that an intermolecular charge–transfer interaction occurs between the anthraquinone moiety and the triphenylene nucleus.
Richard M. Crooks - One of the best experts on this subject based on the ideXlab platform.
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Principles of Bipolar Electrochemistry
ChemElectroChem, 2016Co-Authors: Richard M. CrooksAbstract:This is a tutorial on the basic concepts underlying bipolar Electrochemistry. It is intended as an accompaniment to ChemElectroChem’s special issue on this topic. The guest editors of this special issue think it is worthwhile to introduce bipolar Electrochemistry to a broader (Electrochemistry) audience by explaining the similarities and differences between bipolar Electrochemistry and normal electrochemical methods. The work presented herein has been adapted from: S. E. Fosdick, K. N. Knust; K. Scida; R. M. Crooks “Bipolar Electrochemistry” Angew. Chem. Int. Ed. 2013, 52, 10438–10456 (DOI: 10.1002/anie.201300947); “Bipolare Elektrochemie” Angew. Chem. 2013, 125, 10632–10651 (DOI: 10.1002/ange.201300947).
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Bipolar Electrodes: A Useful Tool for Concentration, Separation, and Detection of Analytes in Microelectrochemical Systems
Analytical chemistry, 2010Co-Authors: François Mavré, Robbyn K. Anand, Derek R. Laws, Kwok-fan Chow, Byoung-yong Chang, John A. Crooks, Richard M. CrooksAbstract:Over the past decade, bipolar Electrochemistry has emerged from relative obscurity to provide a promising new means for integrating Electrochemistry into lab-on-a-chip systems. This article describes the fundamental operating principles of bipolar electrodes, as well as several interesting applications.