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Patrick Simon - One of the best experts on this subject based on the ideXlab platform.
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) supersolvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damp...
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually-neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state, but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) super-solvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damping effect. This change can determine as well a change in the thermodynamic driving force of the superheated solution towards bubble nucleation. A more complex than usual picture of the aqueous solution physical chemistry emerges from this study.
Lionel Mercury - One of the best experts on this subject based on the ideXlab platform.
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) supersolvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damp...
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually-neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state, but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) super-solvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damping effect. This change can determine as well a change in the thermodynamic driving force of the superheated solution towards bubble nucleation. A more complex than usual picture of the aqueous solution physical chemistry emerges from this study.
Kirill I. Shmulovich - One of the best experts on this subject based on the ideXlab platform.
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) supersolvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damp...
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually-neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state, but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) super-solvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damping effect. This change can determine as well a change in the thermodynamic driving force of the superheated solution towards bubble nucleation. A more complex than usual picture of the aqueous solution physical chemistry emerges from this study.
Isabelle Bergonzi - One of the best experts on this subject based on the ideXlab platform.
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) supersolvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damp...
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually-neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state, but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) super-solvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damping effect. This change can determine as well a change in the thermodynamic driving force of the superheated solution towards bubble nucleation. A more complex than usual picture of the aqueous solution physical chemistry emerges from this study.
Aurélien Canizares - One of the best experts on this subject based on the ideXlab platform.
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) supersolvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damp...
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Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect
Journal of Physical Chemistry C, 2016Co-Authors: Lionel Mercury, Kirill I. Shmulovich, Isabelle Bergonzi, Aurélien Canizares, Patrick SimonAbstract:Negative pressure in liquids is both an Experimental Fact and a usually-neglected state of condensed matter. Using synthetic fluid inclusions, namely closed vacuoles fabricated inside one solid host by hydrothermal processes, a Raman study was performed to examine how a superheated solvent (under negative pressure) interacts with its dissolved solutes. As a result, this contribution not only illustrates this well-known tensile state, but also displays evidence that a stretched solvent is able to pull on its dissolved solutes and put them also under a stretched state. The dielectric continuum hypothesis may lead to expect a stretching effect in solutes similar to the solvent’s, but our measurements evidence a damping mechanical effect (growing with tension), most probably related to solvation shells. One practical consequence is that the (Experimentally known) super-solvent properties of superheated solutions are certainly related to the change of the chemical potential of solutes which results from the damping effect. This change can determine as well a change in the thermodynamic driving force of the superheated solution towards bubble nucleation. A more complex than usual picture of the aqueous solution physical chemistry emerges from this study.
