The Experts below are selected from a list of 258 Experts worldwide ranked by ideXlab platform
Hansgeorg Stammler - One of the best experts on this subject based on the ideXlab platform.
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bis 2 4 6 tri tert butylphenyl germylene reinvestigated crystal structure lewis acid catalyzed c h insertion and oxidation to an unstable germanone
Organometallics, 1996Co-Authors: Peter Jutzi, Holger Schmidt, Beate Neumann, Hansgeorg StammlerAbstract:Bis(2,4,6-tri-tert-butylphenyl)germylene (1), which had been reported to undergo an insertion of the Germanium Atom into a C−H bond of an o-tert-butyl group at room temperature, was found to be qui...
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Bis(2,4,6-tri-tert-butylphenyl)germylene Reinvestigated: Crystal Structure, Lewis Acid Catalyzed C−H Insertion, and Oxidation to an Unstable Germanone
Organometallics, 1996Co-Authors: Peter Jutzi, Holger Schmidt, Beate Neumann, Hansgeorg StammlerAbstract:Bis(2,4,6-tri-tert-butylphenyl)germylene (1), which had been reported to undergo an insertion of the Germanium Atom into a C−H bond of an o-tert-butyl group at room temperature, was found to be qui...
Peter Jutzi - One of the best experts on this subject based on the ideXlab platform.
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bis 2 4 6 tri tert butylphenyl germylene reinvestigated crystal structure lewis acid catalyzed c h insertion and oxidation to an unstable germanone
Organometallics, 1996Co-Authors: Peter Jutzi, Holger Schmidt, Beate Neumann, Hansgeorg StammlerAbstract:Bis(2,4,6-tri-tert-butylphenyl)germylene (1), which had been reported to undergo an insertion of the Germanium Atom into a C−H bond of an o-tert-butyl group at room temperature, was found to be qui...
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Bis(2,4,6-tri-tert-butylphenyl)germylene Reinvestigated: Crystal Structure, Lewis Acid Catalyzed C−H Insertion, and Oxidation to an Unstable Germanone
Organometallics, 1996Co-Authors: Peter Jutzi, Holger Schmidt, Beate Neumann, Hansgeorg StammlerAbstract:Bis(2,4,6-tri-tert-butylphenyl)germylene (1), which had been reported to undergo an insertion of the Germanium Atom into a C−H bond of an o-tert-butyl group at room temperature, was found to be qui...
Holger Schmidt - One of the best experts on this subject based on the ideXlab platform.
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bis 2 4 6 tri tert butylphenyl germylene reinvestigated crystal structure lewis acid catalyzed c h insertion and oxidation to an unstable germanone
Organometallics, 1996Co-Authors: Peter Jutzi, Holger Schmidt, Beate Neumann, Hansgeorg StammlerAbstract:Bis(2,4,6-tri-tert-butylphenyl)germylene (1), which had been reported to undergo an insertion of the Germanium Atom into a C−H bond of an o-tert-butyl group at room temperature, was found to be qui...
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Bis(2,4,6-tri-tert-butylphenyl)germylene Reinvestigated: Crystal Structure, Lewis Acid Catalyzed C−H Insertion, and Oxidation to an Unstable Germanone
Organometallics, 1996Co-Authors: Peter Jutzi, Holger Schmidt, Beate Neumann, Hansgeorg StammlerAbstract:Bis(2,4,6-tri-tert-butylphenyl)germylene (1), which had been reported to undergo an insertion of the Germanium Atom into a C−H bond of an o-tert-butyl group at room temperature, was found to be qui...
Beate Neumann - One of the best experts on this subject based on the ideXlab platform.
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bis 2 4 6 tri tert butylphenyl germylene reinvestigated crystal structure lewis acid catalyzed c h insertion and oxidation to an unstable germanone
Organometallics, 1996Co-Authors: Peter Jutzi, Holger Schmidt, Beate Neumann, Hansgeorg StammlerAbstract:Bis(2,4,6-tri-tert-butylphenyl)germylene (1), which had been reported to undergo an insertion of the Germanium Atom into a C−H bond of an o-tert-butyl group at room temperature, was found to be qui...
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Bis(2,4,6-tri-tert-butylphenyl)germylene Reinvestigated: Crystal Structure, Lewis Acid Catalyzed C−H Insertion, and Oxidation to an Unstable Germanone
Organometallics, 1996Co-Authors: Peter Jutzi, Holger Schmidt, Beate Neumann, Hansgeorg StammlerAbstract:Bis(2,4,6-tri-tert-butylphenyl)germylene (1), which had been reported to undergo an insertion of the Germanium Atom into a C−H bond of an o-tert-butyl group at room temperature, was found to be qui...
Alexander C. Filippou - One of the best experts on this subject based on the ideXlab platform.
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Insertion of Cp*GeCl into a Tungsten−Chlorine Bond and Crystal Structures of the Germylenes Cp*GeCl, [Cp*GeBr]2, and [Cp*Ge][BF4] (Cp* = Pentamethylcyclopentadienyl)
Organometallics, 1998Co-Authors: Johannes G. Winter, Peter Portius, Gabriele Kociok-köhn, Ragnar Steck, Alexander C. FilippouAbstract:Insertion of the chlorogermylene Cp*GeCl (2) (Cp* = pentamethylcyclopentadienyl) into the W−Cl bond of CpW(CO)3Cl (1) (Cp = cyclopentadienyl) affords the germyl complex CpW(CO)3GeCl2Cp* (3). Treatment of GeCp*2 with 1 equiv of HBr gives the bromogermylene [Cp*GeBr]2 (5). The crystal structures of the halogermylenes 2 and 5 are described. 2 is monomeric in the solid-state, whereas 5 has a dimeric structure, which is characterized by two germylene units associated through asymmetric bromo bridges. In both compounds the pentamethylcyclopentadienyl group is bonded to the Germanium Atom in an asymmetric η2 fashion. In comparison, the crystal structure of [Cp*Ge][BF4] (6) reveals the presence of BF4 anions and Cp*Ge cations, in which the Cp* ligand is η5 bonded to the Germanium Atom.