Graphite Powder

14,000,000 Leading Edge Experts on the ideXlab platform

Scan Science and Technology

Contact Leading Edge Experts & Companies

Scan Science and Technology

Contact Leading Edge Experts & Companies

The Experts below are selected from a list of 9270 Experts worldwide ranked by ideXlab platform

Anton Setzer - One of the best experts on this subject based on the ideXlab platform.

Natalia P Ivleva - One of the best experts on this subject based on the ideXlab platform.

  • soot structure and reactivity analysis by raman microspectroscopy temperature programmed oxidation and high resolution transmission electron microscopy
    Journal of Physical Chemistry A, 2009
    Co-Authors: Markus Knauer, Manfred Erwin Schuster, Robert Schlogl, Reinhard Niessner, Natalia P Ivleva
    Abstract:

    Raman microspectroscopy (RM), temperature-programmed oxidation (TPO), high-resolution transmission electron microscopy (HRTEM), and electron energy loss spectroscopy (EELS) were combined to get comprehensive information on the relationship between structure and reactivity of soot in samples of spark discharge (GfG), heavy duty engine diesel (EURO VI and IV) soot, and Graphite Powder upon oxidation by oxygen at increasing temperatures. GfG soot and Graphite Powder represent the higher and lower reactivity limits. Raman microspectroscopic analysis was conducted by determination of spectral parameters using a five band fitting procedure (G, D1-D4) as well as by evaluation of the dispersive character of the D mode. The analysis of spectral parameters shows a higher degree of disorder and a higher amount of molecular carbon for untreated GfG soot samples than for samples of untreated EURO VI and EURO IV soot. The structural analysis based on the dispersive character of the D mode revealed substantial differences in ordering descending from Graphite Powder, EURO IV, VI to GfG soot. HRTEM images and EELS analysis of EURO IV and VI samples indicated a different morphology and a higher structural order as compared to GfG soot in full agreement with the Raman analysis. These findings are also confirmed by the reactivity of soot during oxidation (TPO), where GfG soot was found to be the most reactive and EURO IV and VI soot samples exhibited a moderate reactivity.

  • soot structure and reactivity analysis by raman microspectroscopy temperature programmed oxidation and high resolution transmission electron microscopy
    Journal of Physical Chemistry A, 2009
    Co-Authors: Markus Knauer, Manfred Erwin Schuster, Robert Schlogl, Reinhard Niessner, Dang Sheng Su, Natalia P Ivleva
    Abstract:

    Raman microspectroscopy (RM), temperature-programmed oxidation (TPO), high-resolution transmission electron microscopy (HRTEM), and electron energy loss spectroscopy (EELS) were combined to get comprehensive information on the relationship between structure and reactivity of soot in samples of spark discharge (GfG), heavy duty engine diesel (EURO VI and IV) soot, and Graphite Powder upon oxidation by oxygen at increasing temperatures. GfG soot and Graphite Powder represent the higher and lower reactivity limits. Raman microspectroscopic analysis was conducted by determination of spectral parameters using a five band fitting procedure (G, D1−D4) as well as by evaluation of the dispersive character of the D mode. The analysis of spectral parameters shows a higher degree of disorder and a higher amount of molecular carbon for untreated GfG soot samples than for samples of untreated EURO VI and EURO IV soot. The structural analysis based on the dispersive character of the D mode revealed substantial differenc...

T. Scheike - One of the best experts on this subject based on the ideXlab platform.

Markus Knauer - One of the best experts on this subject based on the ideXlab platform.

  • soot structure and reactivity analysis by raman microspectroscopy temperature programmed oxidation and high resolution transmission electron microscopy
    Journal of Physical Chemistry A, 2009
    Co-Authors: Markus Knauer, Manfred Erwin Schuster, Robert Schlogl, Reinhard Niessner, Natalia P Ivleva
    Abstract:

    Raman microspectroscopy (RM), temperature-programmed oxidation (TPO), high-resolution transmission electron microscopy (HRTEM), and electron energy loss spectroscopy (EELS) were combined to get comprehensive information on the relationship between structure and reactivity of soot in samples of spark discharge (GfG), heavy duty engine diesel (EURO VI and IV) soot, and Graphite Powder upon oxidation by oxygen at increasing temperatures. GfG soot and Graphite Powder represent the higher and lower reactivity limits. Raman microspectroscopic analysis was conducted by determination of spectral parameters using a five band fitting procedure (G, D1-D4) as well as by evaluation of the dispersive character of the D mode. The analysis of spectral parameters shows a higher degree of disorder and a higher amount of molecular carbon for untreated GfG soot samples than for samples of untreated EURO VI and EURO IV soot. The structural analysis based on the dispersive character of the D mode revealed substantial differences in ordering descending from Graphite Powder, EURO IV, VI to GfG soot. HRTEM images and EELS analysis of EURO IV and VI samples indicated a different morphology and a higher structural order as compared to GfG soot in full agreement with the Raman analysis. These findings are also confirmed by the reactivity of soot during oxidation (TPO), where GfG soot was found to be the most reactive and EURO IV and VI soot samples exhibited a moderate reactivity.

  • soot structure and reactivity analysis by raman microspectroscopy temperature programmed oxidation and high resolution transmission electron microscopy
    Journal of Physical Chemistry A, 2009
    Co-Authors: Markus Knauer, Manfred Erwin Schuster, Robert Schlogl, Reinhard Niessner, Dang Sheng Su, Natalia P Ivleva
    Abstract:

    Raman microspectroscopy (RM), temperature-programmed oxidation (TPO), high-resolution transmission electron microscopy (HRTEM), and electron energy loss spectroscopy (EELS) were combined to get comprehensive information on the relationship between structure and reactivity of soot in samples of spark discharge (GfG), heavy duty engine diesel (EURO VI and IV) soot, and Graphite Powder upon oxidation by oxygen at increasing temperatures. GfG soot and Graphite Powder represent the higher and lower reactivity limits. Raman microspectroscopic analysis was conducted by determination of spectral parameters using a five band fitting procedure (G, D1−D4) as well as by evaluation of the dispersive character of the D mode. The analysis of spectral parameters shows a higher degree of disorder and a higher amount of molecular carbon for untreated GfG soot samples than for samples of untreated EURO VI and EURO IV soot. The structural analysis based on the dispersive character of the D mode revealed substantial differenc...

Pablo Esquinazi - One of the best experts on this subject based on the ideXlab platform.