The Experts below are selected from a list of 165 Experts worldwide ranked by ideXlab platform
Dennis P Curran - One of the best experts on this subject based on the ideXlab platform.
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synthesis of tris 2 perfluorohexylethyl tin hydride a highly fluorinated tin hydride with advantageous features of easy purification
Organic Syntheses, 2003Co-Authors: Aimee Crombie, Sunyoung Kim, Sabine Hadida, Dennis P CurranAbstract:Tris (2-perfluorohexylethyl-tin hydride R Phenyltin trichloride I Tris (2-perfluorohexylethyl)phenyltin 1 Bromotris [2-(perfluorohexyl)ethyl]tin 2 P Tris (2-perfluorohexylethyl-tin hydride Keywords: organometallic Compounds, magnesium; metalation reactions, magnesium; Halogen Compounds, fluorine Compounds; Halogen Compounds, iodine Compounds; Halogen Compounds, fluorine Compounds; metalation reactions, tin; organometallic Compounds, tin; organometallic Compounds, tin; Halogenation, bromination; Halogen Compounds, bromine Compounds; replacement reactions, miscellaneous; reduction, CX CH; organometallic Compounds, tin; replacement reactions, Halogen by hydrogen; replacement reactions, miscellaneous; Halogen Compounds, fluorine Compounds; metalation reactions, tin
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Organic Syntheses - Synthesis of tris(2-perfluorohexylethyl)tin hydride: A highly fluorinated tin hydride with advantageous features of easy purification
Organic Syntheses, 2003Co-Authors: Aimee Crombie, Sunyoung Kim, Sabine Hadida, Dennis P CurranAbstract:Tris (2-perfluorohexylethyl-tin hydride R Phenyltin trichloride I Tris (2-perfluorohexylethyl)phenyltin 1 Bromotris [2-(perfluorohexyl)ethyl]tin 2 P Tris (2-perfluorohexylethyl-tin hydride Keywords: organometallic Compounds, magnesium; metalation reactions, magnesium; Halogen Compounds, fluorine Compounds; Halogen Compounds, iodine Compounds; Halogen Compounds, fluorine Compounds; metalation reactions, tin; organometallic Compounds, tin; organometallic Compounds, tin; Halogenation, bromination; Halogen Compounds, bromine Compounds; replacement reactions, miscellaneous; reduction, CX CH; organometallic Compounds, tin; replacement reactions, Halogen by hydrogen; replacement reactions, miscellaneous; Halogen Compounds, fluorine Compounds; metalation reactions, tin
Aimee Crombie - One of the best experts on this subject based on the ideXlab platform.
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synthesis of tris 2 perfluorohexylethyl tin hydride a highly fluorinated tin hydride with advantageous features of easy purification
Organic Syntheses, 2003Co-Authors: Aimee Crombie, Sunyoung Kim, Sabine Hadida, Dennis P CurranAbstract:Tris (2-perfluorohexylethyl-tin hydride R Phenyltin trichloride I Tris (2-perfluorohexylethyl)phenyltin 1 Bromotris [2-(perfluorohexyl)ethyl]tin 2 P Tris (2-perfluorohexylethyl-tin hydride Keywords: organometallic Compounds, magnesium; metalation reactions, magnesium; Halogen Compounds, fluorine Compounds; Halogen Compounds, iodine Compounds; Halogen Compounds, fluorine Compounds; metalation reactions, tin; organometallic Compounds, tin; organometallic Compounds, tin; Halogenation, bromination; Halogen Compounds, bromine Compounds; replacement reactions, miscellaneous; reduction, CX CH; organometallic Compounds, tin; replacement reactions, Halogen by hydrogen; replacement reactions, miscellaneous; Halogen Compounds, fluorine Compounds; metalation reactions, tin
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Organic Syntheses - Synthesis of tris(2-perfluorohexylethyl)tin hydride: A highly fluorinated tin hydride with advantageous features of easy purification
Organic Syntheses, 2003Co-Authors: Aimee Crombie, Sunyoung Kim, Sabine Hadida, Dennis P CurranAbstract:Tris (2-perfluorohexylethyl-tin hydride R Phenyltin trichloride I Tris (2-perfluorohexylethyl)phenyltin 1 Bromotris [2-(perfluorohexyl)ethyl]tin 2 P Tris (2-perfluorohexylethyl-tin hydride Keywords: organometallic Compounds, magnesium; metalation reactions, magnesium; Halogen Compounds, fluorine Compounds; Halogen Compounds, iodine Compounds; Halogen Compounds, fluorine Compounds; metalation reactions, tin; organometallic Compounds, tin; organometallic Compounds, tin; Halogenation, bromination; Halogen Compounds, bromine Compounds; replacement reactions, miscellaneous; reduction, CX CH; organometallic Compounds, tin; replacement reactions, Halogen by hydrogen; replacement reactions, miscellaneous; Halogen Compounds, fluorine Compounds; metalation reactions, tin
Sabine Hadida - One of the best experts on this subject based on the ideXlab platform.
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synthesis of tris 2 perfluorohexylethyl tin hydride a highly fluorinated tin hydride with advantageous features of easy purification
Organic Syntheses, 2003Co-Authors: Aimee Crombie, Sunyoung Kim, Sabine Hadida, Dennis P CurranAbstract:Tris (2-perfluorohexylethyl-tin hydride R Phenyltin trichloride I Tris (2-perfluorohexylethyl)phenyltin 1 Bromotris [2-(perfluorohexyl)ethyl]tin 2 P Tris (2-perfluorohexylethyl-tin hydride Keywords: organometallic Compounds, magnesium; metalation reactions, magnesium; Halogen Compounds, fluorine Compounds; Halogen Compounds, iodine Compounds; Halogen Compounds, fluorine Compounds; metalation reactions, tin; organometallic Compounds, tin; organometallic Compounds, tin; Halogenation, bromination; Halogen Compounds, bromine Compounds; replacement reactions, miscellaneous; reduction, CX CH; organometallic Compounds, tin; replacement reactions, Halogen by hydrogen; replacement reactions, miscellaneous; Halogen Compounds, fluorine Compounds; metalation reactions, tin
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Organic Syntheses - Synthesis of tris(2-perfluorohexylethyl)tin hydride: A highly fluorinated tin hydride with advantageous features of easy purification
Organic Syntheses, 2003Co-Authors: Aimee Crombie, Sunyoung Kim, Sabine Hadida, Dennis P CurranAbstract:Tris (2-perfluorohexylethyl-tin hydride R Phenyltin trichloride I Tris (2-perfluorohexylethyl)phenyltin 1 Bromotris [2-(perfluorohexyl)ethyl]tin 2 P Tris (2-perfluorohexylethyl-tin hydride Keywords: organometallic Compounds, magnesium; metalation reactions, magnesium; Halogen Compounds, fluorine Compounds; Halogen Compounds, iodine Compounds; Halogen Compounds, fluorine Compounds; metalation reactions, tin; organometallic Compounds, tin; organometallic Compounds, tin; Halogenation, bromination; Halogen Compounds, bromine Compounds; replacement reactions, miscellaneous; reduction, CX CH; organometallic Compounds, tin; replacement reactions, Halogen by hydrogen; replacement reactions, miscellaneous; Halogen Compounds, fluorine Compounds; metalation reactions, tin
Sunyoung Kim - One of the best experts on this subject based on the ideXlab platform.
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synthesis of tris 2 perfluorohexylethyl tin hydride a highly fluorinated tin hydride with advantageous features of easy purification
Organic Syntheses, 2003Co-Authors: Aimee Crombie, Sunyoung Kim, Sabine Hadida, Dennis P CurranAbstract:Tris (2-perfluorohexylethyl-tin hydride R Phenyltin trichloride I Tris (2-perfluorohexylethyl)phenyltin 1 Bromotris [2-(perfluorohexyl)ethyl]tin 2 P Tris (2-perfluorohexylethyl-tin hydride Keywords: organometallic Compounds, magnesium; metalation reactions, magnesium; Halogen Compounds, fluorine Compounds; Halogen Compounds, iodine Compounds; Halogen Compounds, fluorine Compounds; metalation reactions, tin; organometallic Compounds, tin; organometallic Compounds, tin; Halogenation, bromination; Halogen Compounds, bromine Compounds; replacement reactions, miscellaneous; reduction, CX CH; organometallic Compounds, tin; replacement reactions, Halogen by hydrogen; replacement reactions, miscellaneous; Halogen Compounds, fluorine Compounds; metalation reactions, tin
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Organic Syntheses - Synthesis of tris(2-perfluorohexylethyl)tin hydride: A highly fluorinated tin hydride with advantageous features of easy purification
Organic Syntheses, 2003Co-Authors: Aimee Crombie, Sunyoung Kim, Sabine Hadida, Dennis P CurranAbstract:Tris (2-perfluorohexylethyl-tin hydride R Phenyltin trichloride I Tris (2-perfluorohexylethyl)phenyltin 1 Bromotris [2-(perfluorohexyl)ethyl]tin 2 P Tris (2-perfluorohexylethyl-tin hydride Keywords: organometallic Compounds, magnesium; metalation reactions, magnesium; Halogen Compounds, fluorine Compounds; Halogen Compounds, iodine Compounds; Halogen Compounds, fluorine Compounds; metalation reactions, tin; organometallic Compounds, tin; organometallic Compounds, tin; Halogenation, bromination; Halogen Compounds, bromine Compounds; replacement reactions, miscellaneous; reduction, CX CH; organometallic Compounds, tin; replacement reactions, Halogen by hydrogen; replacement reactions, miscellaneous; Halogen Compounds, fluorine Compounds; metalation reactions, tin
Christian Klinke - One of the best experts on this subject based on the ideXlab platform.
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Shape Evolution of CdSe Nanoparticles controlled by Halogen Compounds
Chemistry of Materials, 2014Co-Authors: Michaela Meyns, Fabiola Iacono, Cristina Palencia, Jan Geweke, Mauricio D. Coderch, Ursula E. A. Fittschen, José M. Gallego, Roberto Otero, Beatriz H. Juárez, Christian KlinkeAbstract:Halogen Compounds are capable of playing an important role in the manipulation of nanoparticle shapes and properties. In a new approach, we examined the shape evolution of CdSe nanorods to hexagonal pyramids in a hot-injection synthesis under the influence of Halogenated additives in the form of organic chlorine, bromine and iodine Compounds. Supported by DFT calculations, this shape evolution is explained as a result of X-type ligand coordination to sloped and flat Cd-rich facets and an equilibrium shape strongly influenced by halides. Synchrotron XPS measurements and TXRF results show that the shape evolution is accompanied by a modification in the chemical composition of the ligand sphere. Our experimental results suggest that the molecular structure of the Halogenated compound is related to the degree of the effect on both rod growth and further shape evolution. This presents a new degree of freedom in nanoparticle shape control and highlights the role of additives in nanoparticle synthesis and their possible in situ formation of ligands.
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shape evolution of cdse nanoparticles controlled by Halogen Compounds
Chemistry of Materials, 2014Co-Authors: Michaela Meyns, Fabiola Iacono, Cristina Palencia, Jan Geweke, Mauricio D. Coderch, Ursula E. A. Fittschen, Roberto Otero, Beatriz H. Juárez, Jose Gallego, Christian KlinkeAbstract:Halogen Compounds are capable of playing an important role in the manipulation of nanoparticle shapes and properties. In a new approach, we examined the shape evolution of CdSe nanorods to hexagonal pyramids in a hot-injection synthesis under the influence of Halogenated additives in the form of organic chlorine, bromine and iodine Compounds. Supported by density functional theory calculations, this shape evolution is explained as a result of X-type ligand coordination to sloped and flat Cd-rich facets and an equilibrium shape strongly influenced by halides. Synchrotron XPS measurements and TXRF results show that the shape evolution is accompanied by a modification in the chemical composition of the ligand sphere. Our experimental results suggest that the molecular structure of the Halogenated compound is related to the degree of the effect on both rod growth and further shape evolution. This presents a new degree of freedom in nanoparticle shape control and highlights the role of additives in nanoparticle synthesis and their possible in situ formation of ligands.
