The Experts below are selected from a list of 2397 Experts worldwide ranked by ideXlab platform
Olivier Guillou - One of the best experts on this subject based on the ideXlab platform.
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Lanthanide-Based Coordination Polymers with a 4,5-Dichlorophthalate Ligand Exhibiting Highly Tunable Luminescence: Toward Luminescent Bar Codes
2018Co-Authors: Albert-manga Badiane, Stéphane Freslon, Carole Daiguebonne, Yan Suffren, Kevin Bernot, Guillaume Calvez, Karine Costuas, Magatte Camara, Olivier GuillouAbstract:Reactions in water of 4,5-dichlorophthalate (dcpa2–) with the heaviest lanthanide ions lead to a family of Compounds with the general chemical formula [Ln2(dcpa)3(H2O)5·3H2O]∞, where Ln = Tb–Lu, Y. The synthesis, crystal structure, thermal behavior, and luminescent properties of this series of homonuclear Compounds are described. Additionally, this family can be extended to isostructural Heteronuclear Compounds that can contain some light lanthanide ions and therefore present some original photophysical properties. These Compounds show potential interest as multiemissive materials (visible and infrared light between 450 and 1600 nm) and could find application as luminescent bar codes
Guillou Olivier - One of the best experts on this subject based on the ideXlab platform.
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Lanthanide-Based Coordination Polymers with a 4,5-Dichlorophthalate Ligand Exhibiting Highly Tunable Luminescence Toward Luminescent Bar Codes
'American Chemical Society (ACS)', 2018Co-Authors: Badiane Albert-manga, Freslon Stéphane, Daiguebonne Carole, Suffren Yan, Bernot Kevin, Calvez Guillaume, Costuas Karine, Camara Magatte, Guillou OlivierAbstract:International audienceReactions in water of 4,5-dichlorophthalate (dcpa) with the heaviest lanthanide ions lead to a family of Compounds with the general chemical formula [Ln(dcpa)(HO)·3HO], where Ln = Tb-Lu, Y. The synthesis, crystal structure, thermal behavior, and luminescent properties of this series of homonuclear Compounds are described. Additionally, this family can be extended to isostructural Heteronuclear Compounds that can contain some light lanthanide ions and therefore present some original photophysical properties. These Compounds show potential interest as multiemissive materials (visible and infrared light between 450 and 1600 nm) and could find application as luminescent bar codes
Albert-manga Badiane - One of the best experts on this subject based on the ideXlab platform.
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Lanthanide-Based Coordination Polymers with a 4,5-Dichlorophthalate Ligand Exhibiting Highly Tunable Luminescence: Toward Luminescent Bar Codes
2018Co-Authors: Albert-manga Badiane, Stéphane Freslon, Carole Daiguebonne, Yan Suffren, Kevin Bernot, Guillaume Calvez, Karine Costuas, Magatte Camara, Olivier GuillouAbstract:Reactions in water of 4,5-dichlorophthalate (dcpa2–) with the heaviest lanthanide ions lead to a family of Compounds with the general chemical formula [Ln2(dcpa)3(H2O)5·3H2O]∞, where Ln = Tb–Lu, Y. The synthesis, crystal structure, thermal behavior, and luminescent properties of this series of homonuclear Compounds are described. Additionally, this family can be extended to isostructural Heteronuclear Compounds that can contain some light lanthanide ions and therefore present some original photophysical properties. These Compounds show potential interest as multiemissive materials (visible and infrared light between 450 and 1600 nm) and could find application as luminescent bar codes
Badiane Albert-manga - One of the best experts on this subject based on the ideXlab platform.
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Lanthanide-Based Coordination Polymers with a 4,5-Dichlorophthalate Ligand Exhibiting Highly Tunable Luminescence Toward Luminescent Bar Codes
'American Chemical Society (ACS)', 2018Co-Authors: Badiane Albert-manga, Freslon Stéphane, Daiguebonne Carole, Suffren Yan, Bernot Kevin, Calvez Guillaume, Costuas Karine, Camara Magatte, Guillou OlivierAbstract:International audienceReactions in water of 4,5-dichlorophthalate (dcpa) with the heaviest lanthanide ions lead to a family of Compounds with the general chemical formula [Ln(dcpa)(HO)·3HO], where Ln = Tb-Lu, Y. The synthesis, crystal structure, thermal behavior, and luminescent properties of this series of homonuclear Compounds are described. Additionally, this family can be extended to isostructural Heteronuclear Compounds that can contain some light lanthanide ions and therefore present some original photophysical properties. These Compounds show potential interest as multiemissive materials (visible and infrared light between 450 and 1600 nm) and could find application as luminescent bar codes
Marienoelle Collomb - One of the best experts on this subject based on the ideXlab platform.
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manganese calcium strontium heterometallic Compounds and their relevance for the oxygen evolving center of photosystem ii
Coordination Chemistry Reviews, 2016Co-Authors: Bertrand Gerey, Eric Goure, Jerome Fortage, Jacques Pecaut, Marienoelle CollombAbstract:Abstract Manganese–calcium and manganese–strontium Heteronuclear Compounds are of considerable current interest in the context of modeling the structure of the oxygen-evolving complex (OEC) of photosystem II (PSII), an oxygen-bridged Mn4CaO5 cluster stabilized by carboxylate ligands. This review surveys the structures of all Heteronuclear Mn–Ca and Mn–Sr complexes that have been synthesized and characterized by X-ray crystallography and establishes their relevance to the structure of the OEC. Polymers as well as discrete clusters from two up to fifteen metal ions were isolated in oxidation states ranging from +II to +IV, with various topologies and bridging ligands (µ-alkoxo, µ-hydroxo and µ-oxo). Although this area of research is relatively new, as most of the publications come from the last five years, impressive advances have been recently achieved with the isolation of two close synthetic structural mimics of the cubane subunit Mn3CaO4 of the OEC in 2011 and one mimic of the whole cluster in 2015.