The Experts below are selected from a list of 147 Experts worldwide ranked by ideXlab platform
Scott D. Larsen - One of the best experts on this subject based on the ideXlab platform.
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Organic Syntheses - Hydroxylation of Enolates with Oxodiperoxymolybdenum(Pyridine)(Hexamethylphosphoric Triamide), MoO5·Py·HMPA(MoOPH): 3‐Hydroxy‐1,7,7‐Trimethylbicyclo[2.2.1]Heptan‐2‐one
Organic Syntheses, 2003Co-Authors: Edwin Vedejs, Scott D. LarsenAbstract:Hydroxylation of enolates with oxodiperoxymolybdenum(pyridine)(Hexamethylphosphoric Triamide), MoO5·Py·HMPA(MoOPH): 3-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one intermediate: Oxodiperoxymolybdenum(aqua)(Hexamethylphosphoric Triamide), MoO5·H2O·HMPA intermediate: Oxodiperoxymolybdenum(pyridine)(Hexamethylphosphoric Triamide) MoO5·Py·HMPAMoOPH product: 1,7,7-trimethyl-3-hydroxybicyclo[2.2.1]-heptan-2-one Keywords: hydroxylation; oxidation, CH2 CHOH and CHOR; lithium diisopropylamide (LDA), preparation of; pyridine; tetrahydrofuran; Hexamethylphosphoric Triamide (HMPA), toxicity; methanol; MoOPH
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hydroxylation of enolates with oxodiperoxymolybdenum pyridine Hexamethylphosphoric Triamide moo5 py hmpa mooph 3 hydroxy 1 7 7 trimethylbicyclo 2 2 1 heptan 2 one
Organic Syntheses, 2003Co-Authors: Edwin Vedejs, Scott D. LarsenAbstract:Hydroxylation of enolates with oxodiperoxymolybdenum(pyridine)(Hexamethylphosphoric Triamide), MoO5·Py·HMPA(MoOPH): 3-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one intermediate: Oxodiperoxymolybdenum(aqua)(Hexamethylphosphoric Triamide), MoO5·H2O·HMPA intermediate: Oxodiperoxymolybdenum(pyridine)(Hexamethylphosphoric Triamide) MoO5·Py·HMPAMoOPH product: 1,7,7-trimethyl-3-hydroxybicyclo[2.2.1]-heptan-2-one Keywords: hydroxylation; oxidation, CH2 CHOH and CHOR; lithium diisopropylamide (LDA), preparation of; pyridine; tetrahydrofuran; Hexamethylphosphoric Triamide (HMPA), toxicity; methanol; MoOPH
George M. Rubottom - One of the best experts on this subject based on the ideXlab platform.
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Organic Syntheses - N‐Alkylindoles from the Alkylation of Sodium Indolide in Hexamethylphosphoric Triamide: 1‐Benzylindole
Organic Syntheses, 2003Co-Authors: George M. Rubottom, John C. ChabalaAbstract:N-alkylindoles from the alkylation of sodium indolide in Hexamethylphosphoric Triamide: 1-benzylindole product: 1-benzylindole Keywords: alkylation, N-alkylation; Hexamethylphosphoric Triamide (HMPA), toxicity; distillation, apparatus, Kugelrohr distillation oven
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n alkylindoles from the alkylation of sodium indolide in Hexamethylphosphoric Triamide 1 benzylindole
Organic Syntheses, 2003Co-Authors: George M. Rubottom, John C. ChabalaAbstract:N-alkylindoles from the alkylation of sodium indolide in Hexamethylphosphoric Triamide: 1-benzylindole product: 1-benzylindole Keywords: alkylation, N-alkylation; Hexamethylphosphoric Triamide (HMPA), toxicity; distillation, apparatus, Kugelrohr distillation oven
John C. Chabala - One of the best experts on this subject based on the ideXlab platform.
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Organic Syntheses - N‐Alkylindoles from the Alkylation of Sodium Indolide in Hexamethylphosphoric Triamide: 1‐Benzylindole
Organic Syntheses, 2003Co-Authors: George M. Rubottom, John C. ChabalaAbstract:N-alkylindoles from the alkylation of sodium indolide in Hexamethylphosphoric Triamide: 1-benzylindole product: 1-benzylindole Keywords: alkylation, N-alkylation; Hexamethylphosphoric Triamide (HMPA), toxicity; distillation, apparatus, Kugelrohr distillation oven
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n alkylindoles from the alkylation of sodium indolide in Hexamethylphosphoric Triamide 1 benzylindole
Organic Syntheses, 2003Co-Authors: George M. Rubottom, John C. ChabalaAbstract:N-alkylindoles from the alkylation of sodium indolide in Hexamethylphosphoric Triamide: 1-benzylindole product: 1-benzylindole Keywords: alkylation, N-alkylation; Hexamethylphosphoric Triamide (HMPA), toxicity; distillation, apparatus, Kugelrohr distillation oven
Andrey V. Kustov - One of the best experts on this subject based on the ideXlab platform.
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volumetric properties of water Hexamethylphosphoric Triamide from 288 15 to 308 15 k
The Journal of Chemical Thermodynamics, 2010Co-Authors: Evgeniy V. Ivanov, Andrey V. KustovAbstract:Abstract Densities of (water + Hexamethylphosphoric Triamide) in the entire mole-fraction composition at five temperatures, from (288.15 to 308.15) K, and atmospheric pressure were measured by using a magnetic float densimeter with an error of ±1.1 · 10−5 g · cm−3. Excess molar volumes of the mixtures and apparent molar volumes of the components (down to their infinite dilution) were calculated. The volumetric effects of mixing being very large in magnitude present negative deviations from ideality and become decreasingly negative with increasing temperature. The apparent molar volume of organic co-solvent displays a clearly pronounced minimum in the water-rich region at all the temperatures studied. It has been shown that there is a thermodynamically substantiated interrelation between volume and enthalpy (heat capacity) properties of the mixtures considered.
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Volumetric properties of (water + Hexamethylphosphoric Triamide) from (288.15 to 308.15) K
The Journal of Chemical Thermodynamics, 2010Co-Authors: Evgeniy V. Ivanov, Andrey V. KustovAbstract:Abstract Densities of (water + Hexamethylphosphoric Triamide) in the entire mole-fraction composition at five temperatures, from (288.15 to 308.15) K, and atmospheric pressure were measured by using a magnetic float densimeter with an error of ±1.1 · 10−5 g · cm−3. Excess molar volumes of the mixtures and apparent molar volumes of the components (down to their infinite dilution) were calculated. The volumetric effects of mixing being very large in magnitude present negative deviations from ideality and become decreasingly negative with increasing temperature. The apparent molar volume of organic co-solvent displays a clearly pronounced minimum in the water-rich region at all the temperatures studied. It has been shown that there is a thermodynamically substantiated interrelation between volume and enthalpy (heat capacity) properties of the mixtures considered.
Edwin Vedejs - One of the best experts on this subject based on the ideXlab platform.
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Organic Syntheses - Hydroxylation of Enolates with Oxodiperoxymolybdenum(Pyridine)(Hexamethylphosphoric Triamide), MoO5·Py·HMPA(MoOPH): 3‐Hydroxy‐1,7,7‐Trimethylbicyclo[2.2.1]Heptan‐2‐one
Organic Syntheses, 2003Co-Authors: Edwin Vedejs, Scott D. LarsenAbstract:Hydroxylation of enolates with oxodiperoxymolybdenum(pyridine)(Hexamethylphosphoric Triamide), MoO5·Py·HMPA(MoOPH): 3-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one intermediate: Oxodiperoxymolybdenum(aqua)(Hexamethylphosphoric Triamide), MoO5·H2O·HMPA intermediate: Oxodiperoxymolybdenum(pyridine)(Hexamethylphosphoric Triamide) MoO5·Py·HMPAMoOPH product: 1,7,7-trimethyl-3-hydroxybicyclo[2.2.1]-heptan-2-one Keywords: hydroxylation; oxidation, CH2 CHOH and CHOR; lithium diisopropylamide (LDA), preparation of; pyridine; tetrahydrofuran; Hexamethylphosphoric Triamide (HMPA), toxicity; methanol; MoOPH
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hydroxylation of enolates with oxodiperoxymolybdenum pyridine Hexamethylphosphoric Triamide moo5 py hmpa mooph 3 hydroxy 1 7 7 trimethylbicyclo 2 2 1 heptan 2 one
Organic Syntheses, 2003Co-Authors: Edwin Vedejs, Scott D. LarsenAbstract:Hydroxylation of enolates with oxodiperoxymolybdenum(pyridine)(Hexamethylphosphoric Triamide), MoO5·Py·HMPA(MoOPH): 3-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one intermediate: Oxodiperoxymolybdenum(aqua)(Hexamethylphosphoric Triamide), MoO5·H2O·HMPA intermediate: Oxodiperoxymolybdenum(pyridine)(Hexamethylphosphoric Triamide) MoO5·Py·HMPAMoOPH product: 1,7,7-trimethyl-3-hydroxybicyclo[2.2.1]-heptan-2-one Keywords: hydroxylation; oxidation, CH2 CHOH and CHOR; lithium diisopropylamide (LDA), preparation of; pyridine; tetrahydrofuran; Hexamethylphosphoric Triamide (HMPA), toxicity; methanol; MoOPH