Invisible Ink

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Neelotpal Sen Sarma - One of the best experts on this subject based on the ideXlab platform.

  • stimuli responsive naphthalene diimide as Invisible Ink a rewritable fluorescent platform for anti counterfeiting
    Chemistry-an Asian Journal, 2020
    Co-Authors: Anamika Kalita, Akhtar Hussain Malik, Neelotpal Sen Sarma
    Abstract:

    Herein, we report an approach to combat counterfeiting and storage of valuable information based on the solid-state fluorescence switching behavior of isoniazid functionalized naphthalene diimide (ISO_NDI) in response to an external stimuli (i. e., HCl vapor). The unique feature of ISO_NDI is further utilized to develop an Invisible Ink (ISO_NDI-PVA) with commercial polymer polyvinyl alcohol (PVA). A solid-state fluorescence recovery was observed while loading with HCl vapors. This exclusive property of the material could be applied directly as a security Ink for confidential data storage purpose. Based on above strategy, we successfully realized the rewritable application by using ISO_NDI-PVA Ink and confirm its practical efficacy on various substrates by creating different patterns. The solid-state fluorescence switching behavior of ISO_NDI-PVA Ink exhibited reversible on/off signal for multiple cycles under the influence of HCl/NH3 vapors. Mechanistic investigation supports a clear participation of intermolecular charge transfer (ICT) phenomenon in the solid-state fluorescence switching property. The ease of fabricating the Ink with Invisible to visible characteristics in response to HCl vapors provides new opportunities for exploring the application of ISO_NDI-PVA as Invisible Ink for targeted security applications.

  • Stimuli‐Responsive Naphthalene Diimide as Invisible Ink: A Rewritable Fluorescent Platform for Anti‐Counterfeiting
    Chemistry an Asian journal, 2020
    Co-Authors: Anamika Kalita, Akhtar Hussain Malik, Neelotpal Sen Sarma
    Abstract:

    Herein, we report an approach to combat counterfeiting and storage of valuable information based on the solid-state fluorescence switching behavior of isoniazid functionalized naphthalene diimide (ISO_NDI) in response to an external stimuli (i. e., HCl vapor). The unique feature of ISO_NDI is further utilized to develop an Invisible Ink (ISO_NDI-PVA) with commercial polymer polyvinyl alcohol (PVA). A solid-state fluorescence recovery was observed while loading with HCl vapors. This exclusive property of the material could be applied directly as a security Ink for confidential data storage purpose. Based on above strategy, we successfully realized the rewritable application by using ISO_NDI-PVA Ink and confirm its practical efficacy on various substrates by creating different patterns. The solid-state fluorescence switching behavior of ISO_NDI-PVA Ink exhibited reversible on/off signal for multiple cycles under the influence of HCl/NH3 vapors. Mechanistic investigation supports a clear participation of intermolecular charge transfer (ICT) phenomenon in the solid-state fluorescence switching property. The ease of fabricating the Ink with Invisible to visible characteristics in response to HCl vapors provides new opportunities for exploring the application of ISO_NDI-PVA as Invisible Ink for targeted security applications.

Chih Chia Huang - One of the best experts on this subject based on the ideXlab platform.

  • Invisible-Ink-assisted pattern and written surface-enhanced Raman scattering substrates for versatile chem/biosensing platforms
    Green Chemistry, 2018
    Co-Authors: Chien-wei Lee, Shih Hui Gilbert Chang, Chih Chia Huang
    Abstract:

    In recent years, highly sensitive surface-enhanced Raman scattering (SERS) integrated with flexible substrates has drawn increasing attention for label-free detection. In this study, an Invisible Ink-inspired process was developed for the fabrication of plasmonic Au-based SERS substrates through an on-site redox strategy. Tannic acid (TNA), a common green reagent, was used not only for fabricating various SERS absorbents through a confinement reduction of a Au-TNA complex, but also for supplying an amphiphilic inorganic–organic surface structure for outstanding SERS enhancement at micromolar to nanomolar concentrations for a wide range of compounds. In addition to label-free sensing, this TNA/Au-based SERS substrate provides a versatile analysis platform for studies of chemical and biological reactions. A combination of TNA Ink with different metal ions allows for a reliable procedure for the synthesis of a bimetallic AuAg SERS substrate that further enhances the SERS intensity of analyte molecules and extends the lower limit of detection.

  • Invisible Ink assisted pattern and written surface enhanced raman scattering substrates for versatile chem biosensing platforms
    Green Chemistry, 2018
    Co-Authors: Chien-wei Lee, Shih Hui Gilbert Chang, Chih Chia Huang
    Abstract:

    In recent years, highly sensitive surface-enhanced Raman scattering (SERS) integrated with flexible substrates has drawn increasing attention for label-free detection. In this study, an Invisible Ink-inspired process was developed for the fabrication of plasmonic Au-based SERS substrates through an on-site redox strategy. Tannic acid (TNA), a common green reagent, was used not only for fabricating various SERS absorbents through a confinement reduction of a Au-TNA complex, but also for supplying an amphiphilic inorganic–organic surface structure for outstanding SERS enhancement at micromolar to nanomolar concentrations for a wide range of compounds. In addition to label-free sensing, this TNA/Au-based SERS substrate provides a versatile analysis platform for studies of chemical and biological reactions. A combination of TNA Ink with different metal ions allows for a reliable procedure for the synthesis of a bimetallic AuAg SERS substrate that further enhances the SERS intensity of analyte molecules and extends the lower limit of detection.

Anamika Kalita - One of the best experts on this subject based on the ideXlab platform.

  • stimuli responsive naphthalene diimide as Invisible Ink a rewritable fluorescent platform for anti counterfeiting
    Chemistry-an Asian Journal, 2020
    Co-Authors: Anamika Kalita, Akhtar Hussain Malik, Neelotpal Sen Sarma
    Abstract:

    Herein, we report an approach to combat counterfeiting and storage of valuable information based on the solid-state fluorescence switching behavior of isoniazid functionalized naphthalene diimide (ISO_NDI) in response to an external stimuli (i. e., HCl vapor). The unique feature of ISO_NDI is further utilized to develop an Invisible Ink (ISO_NDI-PVA) with commercial polymer polyvinyl alcohol (PVA). A solid-state fluorescence recovery was observed while loading with HCl vapors. This exclusive property of the material could be applied directly as a security Ink for confidential data storage purpose. Based on above strategy, we successfully realized the rewritable application by using ISO_NDI-PVA Ink and confirm its practical efficacy on various substrates by creating different patterns. The solid-state fluorescence switching behavior of ISO_NDI-PVA Ink exhibited reversible on/off signal for multiple cycles under the influence of HCl/NH3 vapors. Mechanistic investigation supports a clear participation of intermolecular charge transfer (ICT) phenomenon in the solid-state fluorescence switching property. The ease of fabricating the Ink with Invisible to visible characteristics in response to HCl vapors provides new opportunities for exploring the application of ISO_NDI-PVA as Invisible Ink for targeted security applications.

  • Stimuli‐Responsive Naphthalene Diimide as Invisible Ink: A Rewritable Fluorescent Platform for Anti‐Counterfeiting
    Chemistry an Asian journal, 2020
    Co-Authors: Anamika Kalita, Akhtar Hussain Malik, Neelotpal Sen Sarma
    Abstract:

    Herein, we report an approach to combat counterfeiting and storage of valuable information based on the solid-state fluorescence switching behavior of isoniazid functionalized naphthalene diimide (ISO_NDI) in response to an external stimuli (i. e., HCl vapor). The unique feature of ISO_NDI is further utilized to develop an Invisible Ink (ISO_NDI-PVA) with commercial polymer polyvinyl alcohol (PVA). A solid-state fluorescence recovery was observed while loading with HCl vapors. This exclusive property of the material could be applied directly as a security Ink for confidential data storage purpose. Based on above strategy, we successfully realized the rewritable application by using ISO_NDI-PVA Ink and confirm its practical efficacy on various substrates by creating different patterns. The solid-state fluorescence switching behavior of ISO_NDI-PVA Ink exhibited reversible on/off signal for multiple cycles under the influence of HCl/NH3 vapors. Mechanistic investigation supports a clear participation of intermolecular charge transfer (ICT) phenomenon in the solid-state fluorescence switching property. The ease of fabricating the Ink with Invisible to visible characteristics in response to HCl vapors provides new opportunities for exploring the application of ISO_NDI-PVA as Invisible Ink for targeted security applications.

Chien-wei Lee - One of the best experts on this subject based on the ideXlab platform.

  • Invisible-Ink-assisted pattern and written surface-enhanced Raman scattering substrates for versatile chem/biosensing platforms
    Green Chemistry, 2018
    Co-Authors: Chien-wei Lee, Shih Hui Gilbert Chang, Chih Chia Huang
    Abstract:

    In recent years, highly sensitive surface-enhanced Raman scattering (SERS) integrated with flexible substrates has drawn increasing attention for label-free detection. In this study, an Invisible Ink-inspired process was developed for the fabrication of plasmonic Au-based SERS substrates through an on-site redox strategy. Tannic acid (TNA), a common green reagent, was used not only for fabricating various SERS absorbents through a confinement reduction of a Au-TNA complex, but also for supplying an amphiphilic inorganic–organic surface structure for outstanding SERS enhancement at micromolar to nanomolar concentrations for a wide range of compounds. In addition to label-free sensing, this TNA/Au-based SERS substrate provides a versatile analysis platform for studies of chemical and biological reactions. A combination of TNA Ink with different metal ions allows for a reliable procedure for the synthesis of a bimetallic AuAg SERS substrate that further enhances the SERS intensity of analyte molecules and extends the lower limit of detection.

  • Invisible Ink assisted pattern and written surface enhanced raman scattering substrates for versatile chem biosensing platforms
    Green Chemistry, 2018
    Co-Authors: Chien-wei Lee, Shih Hui Gilbert Chang, Chih Chia Huang
    Abstract:

    In recent years, highly sensitive surface-enhanced Raman scattering (SERS) integrated with flexible substrates has drawn increasing attention for label-free detection. In this study, an Invisible Ink-inspired process was developed for the fabrication of plasmonic Au-based SERS substrates through an on-site redox strategy. Tannic acid (TNA), a common green reagent, was used not only for fabricating various SERS absorbents through a confinement reduction of a Au-TNA complex, but also for supplying an amphiphilic inorganic–organic surface structure for outstanding SERS enhancement at micromolar to nanomolar concentrations for a wide range of compounds. In addition to label-free sensing, this TNA/Au-based SERS substrate provides a versatile analysis platform for studies of chemical and biological reactions. A combination of TNA Ink with different metal ions allows for a reliable procedure for the synthesis of a bimetallic AuAg SERS substrate that further enhances the SERS intensity of analyte molecules and extends the lower limit of detection.

Akhtar Hussain Malik - One of the best experts on this subject based on the ideXlab platform.

  • stimuli responsive naphthalene diimide as Invisible Ink a rewritable fluorescent platform for anti counterfeiting
    Chemistry-an Asian Journal, 2020
    Co-Authors: Anamika Kalita, Akhtar Hussain Malik, Neelotpal Sen Sarma
    Abstract:

    Herein, we report an approach to combat counterfeiting and storage of valuable information based on the solid-state fluorescence switching behavior of isoniazid functionalized naphthalene diimide (ISO_NDI) in response to an external stimuli (i. e., HCl vapor). The unique feature of ISO_NDI is further utilized to develop an Invisible Ink (ISO_NDI-PVA) with commercial polymer polyvinyl alcohol (PVA). A solid-state fluorescence recovery was observed while loading with HCl vapors. This exclusive property of the material could be applied directly as a security Ink for confidential data storage purpose. Based on above strategy, we successfully realized the rewritable application by using ISO_NDI-PVA Ink and confirm its practical efficacy on various substrates by creating different patterns. The solid-state fluorescence switching behavior of ISO_NDI-PVA Ink exhibited reversible on/off signal for multiple cycles under the influence of HCl/NH3 vapors. Mechanistic investigation supports a clear participation of intermolecular charge transfer (ICT) phenomenon in the solid-state fluorescence switching property. The ease of fabricating the Ink with Invisible to visible characteristics in response to HCl vapors provides new opportunities for exploring the application of ISO_NDI-PVA as Invisible Ink for targeted security applications.

  • Stimuli‐Responsive Naphthalene Diimide as Invisible Ink: A Rewritable Fluorescent Platform for Anti‐Counterfeiting
    Chemistry an Asian journal, 2020
    Co-Authors: Anamika Kalita, Akhtar Hussain Malik, Neelotpal Sen Sarma
    Abstract:

    Herein, we report an approach to combat counterfeiting and storage of valuable information based on the solid-state fluorescence switching behavior of isoniazid functionalized naphthalene diimide (ISO_NDI) in response to an external stimuli (i. e., HCl vapor). The unique feature of ISO_NDI is further utilized to develop an Invisible Ink (ISO_NDI-PVA) with commercial polymer polyvinyl alcohol (PVA). A solid-state fluorescence recovery was observed while loading with HCl vapors. This exclusive property of the material could be applied directly as a security Ink for confidential data storage purpose. Based on above strategy, we successfully realized the rewritable application by using ISO_NDI-PVA Ink and confirm its practical efficacy on various substrates by creating different patterns. The solid-state fluorescence switching behavior of ISO_NDI-PVA Ink exhibited reversible on/off signal for multiple cycles under the influence of HCl/NH3 vapors. Mechanistic investigation supports a clear participation of intermolecular charge transfer (ICT) phenomenon in the solid-state fluorescence switching property. The ease of fabricating the Ink with Invisible to visible characteristics in response to HCl vapors provides new opportunities for exploring the application of ISO_NDI-PVA as Invisible Ink for targeted security applications.