The Experts below are selected from a list of 6 Experts worldwide ranked by ideXlab platform
Ernesto Suarez - One of the best experts on this subject based on the ideXlab platform.
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fragmentation of carbohydrate anomeric alkoxyl radicals a new synthesis of 1 1 difluoro 1 iodo alditols
Organic Letters, 2003Co-Authors: Cosme G Francisco, Concepcion C Gonzalez, Nieves R Paz, Ernesto SuarezAbstract:The β-fragmentation of 2,2-difluoro-saccharide anomeric alkoxyl radicals, generated under oxidative condition by treatment of the respective alcohols with (diacetoxyiodo)benzene (DIB) and iodine, afforded 1,1-difluoro-1-iodo alditols in high yield. The reactivity of the fluorinated radical generated by rupture of the C−I bond has been preliminarily assessed by reductive deiodination with tributyltin hydride/AIBN and intermolecular allylation using the Keck Reaction.
Cosme G Francisco - One of the best experts on this subject based on the ideXlab platform.
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fragmentation of carbohydrate anomeric alkoxyl radicals a new synthesis of 1 1 difluoro 1 iodo alditols
Organic Letters, 2003Co-Authors: Cosme G Francisco, Concepcion C Gonzalez, Nieves R Paz, Ernesto SuarezAbstract:The β-fragmentation of 2,2-difluoro-saccharide anomeric alkoxyl radicals, generated under oxidative condition by treatment of the respective alcohols with (diacetoxyiodo)benzene (DIB) and iodine, afforded 1,1-difluoro-1-iodo alditols in high yield. The reactivity of the fluorinated radical generated by rupture of the C−I bond has been preliminarily assessed by reductive deiodination with tributyltin hydride/AIBN and intermolecular allylation using the Keck Reaction.
Concepcion C Gonzalez - One of the best experts on this subject based on the ideXlab platform.
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fragmentation of carbohydrate anomeric alkoxyl radicals a new synthesis of 1 1 difluoro 1 iodo alditols
Organic Letters, 2003Co-Authors: Cosme G Francisco, Concepcion C Gonzalez, Nieves R Paz, Ernesto SuarezAbstract:The β-fragmentation of 2,2-difluoro-saccharide anomeric alkoxyl radicals, generated under oxidative condition by treatment of the respective alcohols with (diacetoxyiodo)benzene (DIB) and iodine, afforded 1,1-difluoro-1-iodo alditols in high yield. The reactivity of the fluorinated radical generated by rupture of the C−I bond has been preliminarily assessed by reductive deiodination with tributyltin hydride/AIBN and intermolecular allylation using the Keck Reaction.
Nieves R Paz - One of the best experts on this subject based on the ideXlab platform.
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fragmentation of carbohydrate anomeric alkoxyl radicals a new synthesis of 1 1 difluoro 1 iodo alditols
Organic Letters, 2003Co-Authors: Cosme G Francisco, Concepcion C Gonzalez, Nieves R Paz, Ernesto SuarezAbstract:The β-fragmentation of 2,2-difluoro-saccharide anomeric alkoxyl radicals, generated under oxidative condition by treatment of the respective alcohols with (diacetoxyiodo)benzene (DIB) and iodine, afforded 1,1-difluoro-1-iodo alditols in high yield. The reactivity of the fluorinated radical generated by rupture of the C−I bond has been preliminarily assessed by reductive deiodination with tributyltin hydride/AIBN and intermolecular allylation using the Keck Reaction.
Suárez Ernesto - One of the best experts on this subject based on the ideXlab platform.
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Fragmentation of carbohydrate anomeric alkoxyl radicals: a new synthesis of 1,1-difluoro-1-iodo alditols
'American Chemical Society (ACS)', 2003Co-Authors: Francisco, Cosme G., González Martín, Concepción C., Rodríguez Paz Nieves, Suárez ErnestoAbstract:3 pages, 1 table, 2 schemes.-- PMID: 14572277 [PubMed].-- Printed version published Oct 30, 2003.-- Supporting information available at: http://pubs.acs.org/doi/suppl/10.1021/ol035611lThe β-fragmentation of 2,2-difluoro-saccharide anomeric alkoxyl radicals, generated under oxidative condition by treatment of the respective alcohols with (diacetoxyiodo)benzene (DIB) and iodine, afforded 1,1-difluoro-1-iodo alditols in high yield. The reactivity of the fluorinated radical generated by rupture of the C−I bond has been preliminarily assessed by reductive deiodination with tributyltin hydride/AIBN and intermolecular allylation using the Keck Reaction