The Experts below are selected from a list of 92598 Experts worldwide ranked by ideXlab platform

Nigel J Cairns - One of the best experts on this subject based on the ideXlab platform.

Richard A. Armstrong - One of the best experts on this subject based on the ideXlab platform.

Adam P Willard - One of the best experts on this subject based on the ideXlab platform.

  • modeling the influence of correlated Molecular Disorder on the dynamics of excitons in organic Molecular semiconductors
    Journal of Physical Chemistry C, 2019
    Co-Authors: Chee Kong Lee, Liang Shi, Adam P Willard
    Abstract:

    In this paper, we investigate the role of correlated Molecular Disorder on the dynamics of excitons in oligothiophene-based organic semiconductors. We simulate exciton dynamics using the Frenkel ex...

  • modeling the effects of Molecular Disorder on the properties of frenkel excitons in organic Molecular semiconductors
    Journal of Chemical Physics, 2018
    Co-Authors: Liang Shi, Adam P Willard
    Abstract:

    The Frenkel exciton model provides a convenient framework for simulating electronic excitations in organic conjugated systems that are too large to address with atomistic level electronic structure methods. Parameterization of this model is typically based on analytical expressions that incompletely describe the spatial and temporal correlations that are inherent to many condensed phase Molecular systems. In this manuscript, we present a general procedure for including these correlations in the Frenkel exciton model, by mapping them directly from all-atom Molecular configurations, for instance from classical Molecular dynamics. Regardless of system morphology, this mapping automatically captures the spatial and temporal Molecular correlations that are otherwise difficult or impossible to represent in terms of low-dimensional correlation functions. We apply this procedure to study the excited state properties of condensed phase materials made up of thiophene oligomers. We show that Frenkel model parameters can be mapped from a series of single molecule electronic structure calculations, and that for these materials efficient semi-empirical methods are sufficient to accurately reproduce experimental spectral measurements. By analyzing the statistics of model parameters derived from materials with different characteristic morphologies, we highlight failures in some assumptions that are commonly applied when generating model parameters. Finally, by simulating exciton dynamics on a mapped Frenekel exciton model, we demonstrate the ability to quantify the effect of material morphology on the dynamic properties of excitons.

Jianping Lang - One of the best experts on this subject based on the ideXlab platform.

  • how does a non c3 symmetry guest molecule fit into a c3 symmetry host cavity
    Crystal Growth & Design, 2010
    Co-Authors: Wenhua Zhang, Dong Liu, Zhigang Ren, Yong Zhang, Jianping Lang
    Abstract:

    Reactions of (NH4)2[MoOS3] with [Cu(MeCN)4](ClO4) and bis(3,5-dimethylpyrazolyl)methane (dmpzm) (molar ratio = 1:3:3) in MeCN produced a cationic cluster [MoOS3Cu3(dmpzm)3](ClO4) (1). 1 consists of a unique 3D hydrogen-bonded network with empty C3-symmetry cavities. A set of C3 (cyclohexane) or non-C3-symmetry solvent molecules (aniline, N,N′-dimethylformamide, formamide, and water) could recognize these C3-symmetry cavities and smartly fit themselves into them by converting themselves into C3-symmetry species through intriguing ways of symmetry-oriented Molecular Disorder and trimerlization.

Liang Shi - One of the best experts on this subject based on the ideXlab platform.

  • modeling the influence of correlated Molecular Disorder on the dynamics of excitons in organic Molecular semiconductors
    Journal of Physical Chemistry C, 2019
    Co-Authors: Chee Kong Lee, Liang Shi, Adam P Willard
    Abstract:

    In this paper, we investigate the role of correlated Molecular Disorder on the dynamics of excitons in oligothiophene-based organic semiconductors. We simulate exciton dynamics using the Frenkel ex...

  • modeling the effects of Molecular Disorder on the properties of frenkel excitons in organic Molecular semiconductors
    Journal of Chemical Physics, 2018
    Co-Authors: Liang Shi, Adam P Willard
    Abstract:

    The Frenkel exciton model provides a convenient framework for simulating electronic excitations in organic conjugated systems that are too large to address with atomistic level electronic structure methods. Parameterization of this model is typically based on analytical expressions that incompletely describe the spatial and temporal correlations that are inherent to many condensed phase Molecular systems. In this manuscript, we present a general procedure for including these correlations in the Frenkel exciton model, by mapping them directly from all-atom Molecular configurations, for instance from classical Molecular dynamics. Regardless of system morphology, this mapping automatically captures the spatial and temporal Molecular correlations that are otherwise difficult or impossible to represent in terms of low-dimensional correlation functions. We apply this procedure to study the excited state properties of condensed phase materials made up of thiophene oligomers. We show that Frenkel model parameters can be mapped from a series of single molecule electronic structure calculations, and that for these materials efficient semi-empirical methods are sufficient to accurately reproduce experimental spectral measurements. By analyzing the statistics of model parameters derived from materials with different characteristic morphologies, we highlight failures in some assumptions that are commonly applied when generating model parameters. Finally, by simulating exciton dynamics on a mapped Frenekel exciton model, we demonstrate the ability to quantify the effect of material morphology on the dynamic properties of excitons.