The Experts below are selected from a list of 303 Experts worldwide ranked by ideXlab platform
Matthew J. Piggott - One of the best experts on this subject based on the ideXlab platform.
-
access to 1 2 3 4 tetraoxygenated benzenes via a double baeyer villiger reaction of Quinizarin dimethyl ether application to the synthesis of bioactive natural products from antrodia camphorata
Journal of Organic Chemistry, 2016Co-Authors: Harriet L Newson, Duncan A. Wild, Sing Yee Yeung, Brian W. Skelton, Gavin R. Flematti, Jane E. Allan, Matthew J. PiggottAbstract:The first systematic investigation into the Baeyer–Villiger reaction of an anthraquinone is presented. The double Baeyer–Villiger reaction of Quinizarin dimethyl ether is viable, directly providing the dibenzo[b,f][1,4]-dioxocin-6,11-dione ring-system, which is otherwise difficult to prepare. This methodology provides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the total synthesis of a natural occurring benzodioxole and its biphenyl dimer, which both display noteworthy biological activity. Interestingly, the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line.
-
Access to 1,2,3,4-Tetraoxygenated Benzenes via a Double Baeyer–Villiger Reaction of Quinizarin Dimethyl Ether: Application to the Synthesis of Bioactive Natural Products from Antrodia camphorata
2016Co-Authors: Harriet L. Newson, Duncan A. Wild, Sing Yee Yeung, Brian W. Skelton, Gavin R. Flematti, Jane E. Allan, Matthew J. PiggottAbstract:The first systematic investigation into the Baeyer–Villiger reaction of an anthraquinone is presented. The double Baeyer–Villiger reaction of Quinizarin dimethyl ether is viable, directly providing the dibenzo[b,f][1,4]-dioxocin-6,11-dione ring-system, which is otherwise difficult to prepare. This methodology provides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the total synthesis of a natural occurring benzodioxole and its biphenyl dimer, which both display noteworthy biological activity. Interestingly, the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line
Harriet L Newson - One of the best experts on this subject based on the ideXlab platform.
-
access to 1 2 3 4 tetraoxygenated benzenes via a double baeyer villiger reaction of Quinizarin dimethyl ether application to the synthesis of bioactive natural products from antrodia camphorata
Journal of Organic Chemistry, 2016Co-Authors: Harriet L Newson, Duncan A. Wild, Sing Yee Yeung, Brian W. Skelton, Gavin R. Flematti, Jane E. Allan, Matthew J. PiggottAbstract:The first systematic investigation into the Baeyer–Villiger reaction of an anthraquinone is presented. The double Baeyer–Villiger reaction of Quinizarin dimethyl ether is viable, directly providing the dibenzo[b,f][1,4]-dioxocin-6,11-dione ring-system, which is otherwise difficult to prepare. This methodology provides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the total synthesis of a natural occurring benzodioxole and its biphenyl dimer, which both display noteworthy biological activity. Interestingly, the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line.
Jane E. Allan - One of the best experts on this subject based on the ideXlab platform.
-
access to 1 2 3 4 tetraoxygenated benzenes via a double baeyer villiger reaction of Quinizarin dimethyl ether application to the synthesis of bioactive natural products from antrodia camphorata
Journal of Organic Chemistry, 2016Co-Authors: Harriet L Newson, Duncan A. Wild, Sing Yee Yeung, Brian W. Skelton, Gavin R. Flematti, Jane E. Allan, Matthew J. PiggottAbstract:The first systematic investigation into the Baeyer–Villiger reaction of an anthraquinone is presented. The double Baeyer–Villiger reaction of Quinizarin dimethyl ether is viable, directly providing the dibenzo[b,f][1,4]-dioxocin-6,11-dione ring-system, which is otherwise difficult to prepare. This methodology provides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the total synthesis of a natural occurring benzodioxole and its biphenyl dimer, which both display noteworthy biological activity. Interestingly, the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line.
-
Access to 1,2,3,4-Tetraoxygenated Benzenes via a Double Baeyer–Villiger Reaction of Quinizarin Dimethyl Ether: Application to the Synthesis of Bioactive Natural Products from Antrodia camphorata
2016Co-Authors: Harriet L. Newson, Duncan A. Wild, Sing Yee Yeung, Brian W. Skelton, Gavin R. Flematti, Jane E. Allan, Matthew J. PiggottAbstract:The first systematic investigation into the Baeyer–Villiger reaction of an anthraquinone is presented. The double Baeyer–Villiger reaction of Quinizarin dimethyl ether is viable, directly providing the dibenzo[b,f][1,4]-dioxocin-6,11-dione ring-system, which is otherwise difficult to prepare. This methodology provides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the total synthesis of a natural occurring benzodioxole and its biphenyl dimer, which both display noteworthy biological activity. Interestingly, the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line
Duncan A. Wild - One of the best experts on this subject based on the ideXlab platform.
-
access to 1 2 3 4 tetraoxygenated benzenes via a double baeyer villiger reaction of Quinizarin dimethyl ether application to the synthesis of bioactive natural products from antrodia camphorata
Journal of Organic Chemistry, 2016Co-Authors: Harriet L Newson, Duncan A. Wild, Sing Yee Yeung, Brian W. Skelton, Gavin R. Flematti, Jane E. Allan, Matthew J. PiggottAbstract:The first systematic investigation into the Baeyer–Villiger reaction of an anthraquinone is presented. The double Baeyer–Villiger reaction of Quinizarin dimethyl ether is viable, directly providing the dibenzo[b,f][1,4]-dioxocin-6,11-dione ring-system, which is otherwise difficult to prepare. This methodology provides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the total synthesis of a natural occurring benzodioxole and its biphenyl dimer, which both display noteworthy biological activity. Interestingly, the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line.
-
Access to 1,2,3,4-Tetraoxygenated Benzenes via a Double Baeyer–Villiger Reaction of Quinizarin Dimethyl Ether: Application to the Synthesis of Bioactive Natural Products from Antrodia camphorata
2016Co-Authors: Harriet L. Newson, Duncan A. Wild, Sing Yee Yeung, Brian W. Skelton, Gavin R. Flematti, Jane E. Allan, Matthew J. PiggottAbstract:The first systematic investigation into the Baeyer–Villiger reaction of an anthraquinone is presented. The double Baeyer–Villiger reaction of Quinizarin dimethyl ether is viable, directly providing the dibenzo[b,f][1,4]-dioxocin-6,11-dione ring-system, which is otherwise difficult to prepare. This methodology provides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the total synthesis of a natural occurring benzodioxole and its biphenyl dimer, which both display noteworthy biological activity. Interestingly, the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line
Sing Yee Yeung - One of the best experts on this subject based on the ideXlab platform.
-
access to 1 2 3 4 tetraoxygenated benzenes via a double baeyer villiger reaction of Quinizarin dimethyl ether application to the synthesis of bioactive natural products from antrodia camphorata
Journal of Organic Chemistry, 2016Co-Authors: Harriet L Newson, Duncan A. Wild, Sing Yee Yeung, Brian W. Skelton, Gavin R. Flematti, Jane E. Allan, Matthew J. PiggottAbstract:The first systematic investigation into the Baeyer–Villiger reaction of an anthraquinone is presented. The double Baeyer–Villiger reaction of Quinizarin dimethyl ether is viable, directly providing the dibenzo[b,f][1,4]-dioxocin-6,11-dione ring-system, which is otherwise difficult to prepare. This methodology provides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the total synthesis of a natural occurring benzodioxole and its biphenyl dimer, which both display noteworthy biological activity. Interestingly, the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line.
-
Access to 1,2,3,4-Tetraoxygenated Benzenes via a Double Baeyer–Villiger Reaction of Quinizarin Dimethyl Ether: Application to the Synthesis of Bioactive Natural Products from Antrodia camphorata
2016Co-Authors: Harriet L. Newson, Duncan A. Wild, Sing Yee Yeung, Brian W. Skelton, Gavin R. Flematti, Jane E. Allan, Matthew J. PiggottAbstract:The first systematic investigation into the Baeyer–Villiger reaction of an anthraquinone is presented. The double Baeyer–Villiger reaction of Quinizarin dimethyl ether is viable, directly providing the dibenzo[b,f][1,4]-dioxocin-6,11-dione ring-system, which is otherwise difficult to prepare. This methodology provides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the total synthesis of a natural occurring benzodioxole and its biphenyl dimer, which both display noteworthy biological activity. Interestingly, the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line
