Radiometric Dating

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Xiaofang Wang - One of the best experts on this subject based on the ideXlab platform.

  • la icp ms u pb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U-Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U-Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U-Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U-Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88– 104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U-Pb age of 228 ± 10 Ma) and blocky calcites (U-Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U-Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U-Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U-Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.

  • la icp ms upb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88–104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U Pb age of 228 ± 10 Ma) and blocky calcites (U Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.

Anjiang Shen - One of the best experts on this subject based on the ideXlab platform.

  • la icp ms u pb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U-Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U-Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U-Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U-Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88– 104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U-Pb age of 228 ± 10 Ma) and blocky calcites (U-Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U-Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U-Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U-Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.

  • la icp ms upb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88–104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U Pb age of 228 ± 10 Ma) and blocky calcites (U Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.

Anping Hu - One of the best experts on this subject based on the ideXlab platform.

  • la icp ms u pb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U-Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U-Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U-Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U-Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88– 104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U-Pb age of 228 ± 10 Ma) and blocky calcites (U-Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U-Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U-Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U-Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.

  • la icp ms upb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88–104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U Pb age of 228 ± 10 Ma) and blocky calcites (U Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.

Feng Liang - One of the best experts on this subject based on the ideXlab platform.

  • la icp ms u pb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U-Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U-Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U-Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U-Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88– 104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U-Pb age of 228 ± 10 Ma) and blocky calcites (U-Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U-Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U-Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U-Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.

  • la icp ms upb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88–104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U Pb age of 228 ± 10 Ma) and blocky calcites (U Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.

Yuexing Feng - One of the best experts on this subject based on the ideXlab platform.

  • la icp ms u pb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U-Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U-Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U-Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U-Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88– 104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U-Pb age of 228 ± 10 Ma) and blocky calcites (U-Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U-Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U-Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U-Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.

  • la icp ms upb geochronology and clumped isotope constraints on the formation and evolution of an ancient dolomite reservoir the middle permian of northwest sichuan basin sw china
    Sedimentary Geology, 2020
    Co-Authors: Anjiang Shen, Anping Hu, Feng Liang, Jianxin Zhao, Xiaofang Wang, Yuexing Feng
    Abstract:

    Abstract Recent advances in laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) in-situ U Pb Radiometric Dating and clumped isotope thermometry (Δ47) of carbonate minerals provide potential for refining the fluid flow and diagenetic history of carbonate successions. In this study, the Middle Permian dolomites proximal to the Longmenshan fold and thrust belt in northwest Sichuan Basin, southwest China, were investigated using combined U Pb geochronology, clumped isotope thermometry, and routine isotopic (δ13C, δ18O and 87Sr/86Sr) and elemental geochemistry, in an attempt to reveal the possible relevance of carbonate diagenesis and porosity evolution to the basin-scale tectonic/fluid flow events in the framework of absolute time. Overall, formation and evolution of these dolomites temporally correlated well with major tectonic episodes of the Longmenshan fold and thrust belt. Contrary to the previously-assumed volcanic-related model, U Pb Dating and Δ47 analyses suggest a mid- to late-Triassic replacive dolomitization event (U Pb ages of 240 ± 12 Ma to 233.8 ± 6.4 Ma) by a hot (Δ47 temperatures 88–104 °C) basinal brine, which was likely driven by thrust-related compression of the Longmenshan fold and thrust belt during the Triassic. Replacive dolomitization was immediately followed by cementation of euhedral dolomites (U Pb age of 228 ± 10 Ma) and blocky calcites (U Pb ages of 224.8 ± 1.8 Ma to 213.4 ± 3.3 Ma) precipitated from the basinal brine in the same tectonic regime. Afterwards, there was long-term cessation of diagenesis that was coincident with, and thus may well be attributed to, tectono-thermal quiescence during most of the Mesozoic Era and Paleogene. Finally, saddle dolomite cements yield Miocene ages (U Pb ages of 16.40 ± 0.74 Ma to 12.3 ± 1.2 Ma) and precipitated in pre-existing vugs, representing a hydrothermal fluid flow event (Δ47 temperatures up to 170 °C) during the reactivation of thrusting. In addition, similarities in U Pb ages and geochemical signatures between host rocks (replacive dolomites) and the vug-lining dolomite cements suggest that most porosity in these dolomite reservoirs was inherited from the precursor limestones, which probably experienced meteoric leaching during late Permian uplift. This study highlights that there are geodynamic controls on fluid flow and consequent diagenetic evolution of carbonates in tectonically active sedimentary basins. It illustrates that burial alone in this setting is not a sufficient driver for diagenetic alteration and porosity reduction. The combination of U Pb Radiometric Dating, clumped isotope thermometry and routine geochemical analyses is a useful approach in refining the diagenetic and porosity evolution history of ancient carbonate successions.