The Experts below are selected from a list of 443433 Experts worldwide ranked by ideXlab platform
Yukihiro Ozaki - One of the best experts on this subject based on the ideXlab platform.
-
Sample Sample Correlation asynchronous spectroscopic method coupled with multivariate curve resolution alternating least squares to analyze challenging bilinear data
Analytical Chemistry, 2020Co-Authors: Ran Guo, Xin Zhang, Xiao-feng Ling, Isao Noda, Yukihiro OzakiAbstract:An approach to construct a secondary asynchronous spectrum via Sample–Sample Correlation (SASS) is proposed to analyze bilinear data from hyphenated spectroscopic experiments. In SASS, bilinear dat...
-
Sample–Sample Correlation Asynchronous Spectroscopic Method Coupled with Multivariate Curve Resolution-Alternating Least Squares To Analyze Challenging Bilinear Data
Analytical chemistry, 2019Co-Authors: Ran Guo, Xin Zhang, Xiao-feng Ling, Isao Noda, Yukihiro OzakiAbstract:An approach to construct a secondary asynchronous spectrum via Sample–Sample Correlation (SASS) is proposed to analyze bilinear data from hyphenated spectroscopic experiments. In SASS, bilinear data is used to construct a series of two-dimensional (2D) Sample–Sample Correlation spectra. Then a vertical slice is extracted from each 2D Sample–Sample Correlation spectrum so that a secondary 2D asynchronous spectrum is constructed via these slices. The advantage of SASS is demonstrated by a model system with the following challenging situations: (1) Temporal profiles of different components severely overlap, making spectra of pure components difficult to directly obtain from either original bilinear data or multivariate curve resolution-alternating least squares (MCR-ALS) with non-negativity and unimodality constraints. (2) Every peak in the spectra of the eluted Samples contains contributions from at least two components. Hence, two-dimensional Correlation spectroscopy (2D-COS) and n-dimensional (nD) asynchr...
-
A New Possibility of the Generalized Two-Dimensional Correlation Spectroscopy. 1. Sample-Sample Correlation Spectroscopy
The Journal of Physical Chemistry A, 2000Co-Authors: Slobodan Šašić, And Andrzej Muszynski, Yukihiro OzakiAbstract:In this paper an extension of the generalized two-dimensional (2D) Correlation spectroscopy, Sample−Sample Correlation spectroscopy, is proposed to obtain the information about the species' perturbation-dependent dynamics. This is the first report of monitoring perturbation dynamics in the Samples by generalized 2D approach. After the rows and columns of the experimental matrix are exchanged in a way that the spectral data set is arranged in rows, unlike the common case, the Correlation between the concentrations of species is calculated. The method has been applied to a model system consisting of two bands with different degrees of overlapping. The concentration-dependent dynamics of the components that give rise to the two bands has been successfully analyzed. Similarities, differences, and correspondences between wavenumber−wavenumber Correlation spectroscopy (existing generalized 2D Correlation spectroscopy) and Sample−Sample Correlation spectroscopy have been discussed. The pretreatments of mean norm...
Ran Guo - One of the best experts on this subject based on the ideXlab platform.
-
Sample Sample Correlation asynchronous spectroscopic method coupled with multivariate curve resolution alternating least squares to analyze challenging bilinear data
Analytical Chemistry, 2020Co-Authors: Ran Guo, Xin Zhang, Xiao-feng Ling, Isao Noda, Yukihiro OzakiAbstract:An approach to construct a secondary asynchronous spectrum via Sample–Sample Correlation (SASS) is proposed to analyze bilinear data from hyphenated spectroscopic experiments. In SASS, bilinear dat...
-
Sample–Sample Correlation Asynchronous Spectroscopic Method Coupled with Multivariate Curve Resolution-Alternating Least Squares To Analyze Challenging Bilinear Data
Analytical chemistry, 2019Co-Authors: Ran Guo, Xin Zhang, Xiao-feng Ling, Isao Noda, Yukihiro OzakiAbstract:An approach to construct a secondary asynchronous spectrum via Sample–Sample Correlation (SASS) is proposed to analyze bilinear data from hyphenated spectroscopic experiments. In SASS, bilinear data is used to construct a series of two-dimensional (2D) Sample–Sample Correlation spectra. Then a vertical slice is extracted from each 2D Sample–Sample Correlation spectrum so that a secondary 2D asynchronous spectrum is constructed via these slices. The advantage of SASS is demonstrated by a model system with the following challenging situations: (1) Temporal profiles of different components severely overlap, making spectra of pure components difficult to directly obtain from either original bilinear data or multivariate curve resolution-alternating least squares (MCR-ALS) with non-negativity and unimodality constraints. (2) Every peak in the spectra of the eluted Samples contains contributions from at least two components. Hence, two-dimensional Correlation spectroscopy (2D-COS) and n-dimensional (nD) asynchr...
Wang Zhou - One of the best experts on this subject based on the ideXlab platform.
-
Tracy-Widom law for the extreme eigenvalues of Sample Correlation matrices
Electronic Journal of Probability, 2012Co-Authors: Zhigang Bao, Guangming Pan, Wang ZhouAbstract:Let the Sample Correlation matrix be $W=YY^T$ , where $Y=(y_{ij})_{p,n}$ with $y_{ij}=x_{ij}/\sqrt{\sum_{j=1}^nx_{ij}^2}$. We assume $\{x_{ij}: 1\leq i\leq p, 1\leq j\leq n\}$ to be a collection of independent symmetrically distributed random variables with sub-exponential tails. Moreover, for any $i$, we assume $x_{ij}, 1\leq j\leq n$ to be identically distributed. We assume $0
-
tracy widom law for the extreme eigenvalues of Sample Correlation matrices
arXiv: Statistics Theory, 2011Co-Authors: Zhigang Bao, Guangming Pan, Wang ZhouAbstract:Let the Sample Correlation matrix be $W=YY^T$, where $Y=(y_{ij})_{p,n}$ with $y_{ij}=x_{ij}/\sqrt{\sum_{j=1}^nx_{ij}^2}$. We assume $\{x_{ij}: 1\leq i\leq p, 1\leq j\leq n\}$ to be a collection of independent symmetric distributed random variables with sub-exponential tails. Moreover, for any $i$, we assume $x_{ij}, 1\leq j\leq n$ to be identically distributed. We assume $0
eigenvalues of $W$. If $x_{ij}$ are i.i.d. standard normal, we can derive the $TW_1$ for both the largest and smallest eigenvalues of the matrix $\mathcal{R}=RR^T$, where $R=(r_{ij})_{p,n}$ with $r_{ij}=(x_{ij}-\bar x_i)/\sqrt{\sum_{j=1}^n(x_{ij}-\bar x_i)^2}$, $\bar x_i=n^{-1}\sum_{j=1}^nx_{ij}$.
-
Almost Sure Limit of the Smallest Eigenvalue of Some Sample Correlation Matrices
Journal of Theoretical Probability, 2010Co-Authors: Han Xiao, Wang ZhouAbstract:Let X ^( n )=( X _ ij ) be a p × n data matrix, where the n columns form a random Sample of size n from a certain p -dimensional distribution. Let R ^( n )=( ρ _ ij ) be the p × p Sample Correlation coefficient matrix of X ^( n ), and $S^{(n)}=(1/n)X^{(n)}(X^{(n)})^{\ast}-\bar{X}\bar{X}^{\ast}$ be the Sample covariance matrix of X ^( n ), where $\bar{X}$ is the mean vector of the n observations. Assuming that X _ ij are independent and identically distributed with finite fourth moment, we show that the smallest eigenvalue of R ^( n ) converges almost surely to the limit $(1-\sqrt{c}\,)^{2}$ as n →∞ and p / n → c ∈(0,∞). We accomplish this by showing that the smallest eigenvalue of S ^( n ) converges almost surely to $(1-\sqrt{c}\,)^{2}$ .
-
Almost Sure Limit of the Smallest Eigenvalue of Some Sample Correlation Matrices
Journal of Theoretical Probability, 2010Co-Authors: Han Xiao, Wang ZhouAbstract:Let X(n)=(Xij) be a p×n data matrix, where the n columns form a random Sample of size n from a certain p-dimensional distribution. Let R(n)=(ρij) be the p×p Sample Correlation coefficient matrix of X(n), and \(S^{(n)}=(1/n)X^{(n)}(X^{(n)})^{\ast}-\bar{X}\bar{X}^{\ast}\) be the Sample covariance matrix of X(n), where \(\bar{X}\) is the mean vector of the n observations. Assuming that Xij are independent and identically distributed with finite fourth moment, we show that the smallest eigenvalue of R(n) converges almost surely to the limit \((1-\sqrt{c}\,)^{2}\) as n→∞ and p/n→c∈(0,∞). We accomplish this by showing that the smallest eigenvalue of S(n) converges almost surely to \((1-\sqrt{c}\,)^{2}\) .
-
Asymptotic distribution of the largest off-diagonal entry of Correlation matrices
Transactions of the American Mathematical Society, 2007Co-Authors: Wang ZhouAbstract:Suppose that we have observations from a -dimensional population. We are interested in testing that the variates of the population are independent under the situation where goes to infinity as . A test statistic is chosen to be , where is the Sample Correlation coefficient between the -th coordinate and the -th coordinate of the population. Under an independent hypothesis, we prove that the asymptotic distribution of is an extreme distribution of type , by using the Chen-Stein Poisson approximation method and the moderate deviations for Sample Correlation coefficients. As a statistically more relevant result, a limit distribution for , where is Spearman's rank Correlation coefficient between the -th coordinate and the -th coordinate of the population, is derived
Isao Noda - One of the best experts on this subject based on the ideXlab platform.
-
Sample Sample Correlation asynchronous spectroscopic method coupled with multivariate curve resolution alternating least squares to analyze challenging bilinear data
Analytical Chemistry, 2020Co-Authors: Ran Guo, Xin Zhang, Xiao-feng Ling, Isao Noda, Yukihiro OzakiAbstract:An approach to construct a secondary asynchronous spectrum via Sample–Sample Correlation (SASS) is proposed to analyze bilinear data from hyphenated spectroscopic experiments. In SASS, bilinear dat...
-
Sample–Sample Correlation Asynchronous Spectroscopic Method Coupled with Multivariate Curve Resolution-Alternating Least Squares To Analyze Challenging Bilinear Data
Analytical chemistry, 2019Co-Authors: Ran Guo, Xin Zhang, Xiao-feng Ling, Isao Noda, Yukihiro OzakiAbstract:An approach to construct a secondary asynchronous spectrum via Sample–Sample Correlation (SASS) is proposed to analyze bilinear data from hyphenated spectroscopic experiments. In SASS, bilinear data is used to construct a series of two-dimensional (2D) Sample–Sample Correlation spectra. Then a vertical slice is extracted from each 2D Sample–Sample Correlation spectrum so that a secondary 2D asynchronous spectrum is constructed via these slices. The advantage of SASS is demonstrated by a model system with the following challenging situations: (1) Temporal profiles of different components severely overlap, making spectra of pure components difficult to directly obtain from either original bilinear data or multivariate curve resolution-alternating least squares (MCR-ALS) with non-negativity and unimodality constraints. (2) Every peak in the spectra of the eluted Samples contains contributions from at least two components. Hence, two-dimensional Correlation spectroscopy (2D-COS) and n-dimensional (nD) asynchr...
Xin Zhang - One of the best experts on this subject based on the ideXlab platform.
-
Sample Sample Correlation asynchronous spectroscopic method coupled with multivariate curve resolution alternating least squares to analyze challenging bilinear data
Analytical Chemistry, 2020Co-Authors: Ran Guo, Xin Zhang, Xiao-feng Ling, Isao Noda, Yukihiro OzakiAbstract:An approach to construct a secondary asynchronous spectrum via Sample–Sample Correlation (SASS) is proposed to analyze bilinear data from hyphenated spectroscopic experiments. In SASS, bilinear dat...
-
Sample–Sample Correlation Asynchronous Spectroscopic Method Coupled with Multivariate Curve Resolution-Alternating Least Squares To Analyze Challenging Bilinear Data
Analytical chemistry, 2019Co-Authors: Ran Guo, Xin Zhang, Xiao-feng Ling, Isao Noda, Yukihiro OzakiAbstract:An approach to construct a secondary asynchronous spectrum via Sample–Sample Correlation (SASS) is proposed to analyze bilinear data from hyphenated spectroscopic experiments. In SASS, bilinear data is used to construct a series of two-dimensional (2D) Sample–Sample Correlation spectra. Then a vertical slice is extracted from each 2D Sample–Sample Correlation spectrum so that a secondary 2D asynchronous spectrum is constructed via these slices. The advantage of SASS is demonstrated by a model system with the following challenging situations: (1) Temporal profiles of different components severely overlap, making spectra of pure components difficult to directly obtain from either original bilinear data or multivariate curve resolution-alternating least squares (MCR-ALS) with non-negativity and unimodality constraints. (2) Every peak in the spectra of the eluted Samples contains contributions from at least two components. Hence, two-dimensional Correlation spectroscopy (2D-COS) and n-dimensional (nD) asynchr...