The Experts below are selected from a list of 408 Experts worldwide ranked by ideXlab platform
Andrey E. Shchekotikhin - One of the best experts on this subject based on the ideXlab platform.
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β-Hydroxylation of anthraquinone derivatives with benzaldehyde oxime as a source of hydroxyl group
Tetrahedron, 2019Co-Authors: Alexander S. Tikhomirov, Ivan V. Ivanov, Alexander M. Korolev, Andrey E. ShchekotikhinAbstract:Abstract Hydroxyanthraquinones are of significant interest due to their broad spectrum of biological activity, coloring properties and synthetic applications. Here, we describe a mild and convenient method for β-hydroxylation of anthraquinone derivatives that can be used during late stages of modifications. The scheme is based on the Miller-Loudon-Snyder Reaction, which uses benzaldoxime as a source of a hydroxyl group. The influence of different leaving groups and neighboring substituents at the anthraquinone core on Reaction rate and yield has been evaluated. A series of β-hydroxyanthraquinone derivatives was synthesized using the developed approach.
Alexander S. Tikhomirov - One of the best experts on this subject based on the ideXlab platform.
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β-Hydroxylation of anthraquinone derivatives with benzaldehyde oxime as a source of hydroxyl group
Tetrahedron, 2019Co-Authors: Alexander S. Tikhomirov, Ivan V. Ivanov, Alexander M. Korolev, Andrey E. ShchekotikhinAbstract:Abstract Hydroxyanthraquinones are of significant interest due to their broad spectrum of biological activity, coloring properties and synthetic applications. Here, we describe a mild and convenient method for β-hydroxylation of anthraquinone derivatives that can be used during late stages of modifications. The scheme is based on the Miller-Loudon-Snyder Reaction, which uses benzaldoxime as a source of a hydroxyl group. The influence of different leaving groups and neighboring substituents at the anthraquinone core on Reaction rate and yield has been evaluated. A series of β-hydroxyanthraquinone derivatives was synthesized using the developed approach.
Ivan V. Ivanov - One of the best experts on this subject based on the ideXlab platform.
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β-Hydroxylation of anthraquinone derivatives with benzaldehyde oxime as a source of hydroxyl group
Tetrahedron, 2019Co-Authors: Alexander S. Tikhomirov, Ivan V. Ivanov, Alexander M. Korolev, Andrey E. ShchekotikhinAbstract:Abstract Hydroxyanthraquinones are of significant interest due to their broad spectrum of biological activity, coloring properties and synthetic applications. Here, we describe a mild and convenient method for β-hydroxylation of anthraquinone derivatives that can be used during late stages of modifications. The scheme is based on the Miller-Loudon-Snyder Reaction, which uses benzaldoxime as a source of a hydroxyl group. The influence of different leaving groups and neighboring substituents at the anthraquinone core on Reaction rate and yield has been evaluated. A series of β-hydroxyanthraquinone derivatives was synthesized using the developed approach.
Alexander M. Korolev - One of the best experts on this subject based on the ideXlab platform.
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β-Hydroxylation of anthraquinone derivatives with benzaldehyde oxime as a source of hydroxyl group
Tetrahedron, 2019Co-Authors: Alexander S. Tikhomirov, Ivan V. Ivanov, Alexander M. Korolev, Andrey E. ShchekotikhinAbstract:Abstract Hydroxyanthraquinones are of significant interest due to their broad spectrum of biological activity, coloring properties and synthetic applications. Here, we describe a mild and convenient method for β-hydroxylation of anthraquinone derivatives that can be used during late stages of modifications. The scheme is based on the Miller-Loudon-Snyder Reaction, which uses benzaldoxime as a source of a hydroxyl group. The influence of different leaving groups and neighboring substituents at the anthraquinone core on Reaction rate and yield has been evaluated. A series of β-hydroxyanthraquinone derivatives was synthesized using the developed approach.