Solubility Limit

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C. D. Kim - One of the best experts on this subject based on the ideXlab platform.

Shlomit Zamir - One of the best experts on this subject based on the ideXlab platform.

  • Solubility Limit of Si in YAG at 1700°C in vacuum
    Journal of the European Ceramic Society, 2017
    Co-Authors: Shlomit Zamir
    Abstract:

    Abstract Measurement of the Solubility Limit of Si in yttrium aluminum garnet (YAG-Y3Al5O12) is crucial for understanding the mechanisms by which Si influences grain boundary mobility, and the mechanisms by which grain boundaries migrate. In the present work, the Solubility Limit of Si in YAG at 1700 °C in vacuum (5 × 10−6 Torr), which are the most common sintering temperature and environment for YAG, was measured for the first time. Measurements were conducted by wavelength dispersive spectroscopy (WDS), using polished YAG specimens with 3700 ppm Si (0.8 wt% SiO2). Si content to ensure saturation with Si. The accuracy of the WDS result was confirmed by using a series of doped specimens and by comparing to inductively coupled plasma mass spectrometry ICP-MS results. The results indicate that the Solubility Limit of Si in YAG at 1700 °C (5 × 10−6 Torr), is 980 ± 60 ppm. The measured Si Solubility was found to significantly depend on the cooling rate, where for furnace cooled specimens the measured Si Solubility was 650 ± 60 ppm. A second phase in triple junction was repeatedly observed when higher content of Si was used, confirming this work results.

  • Solubility Limit of si in yag at 1700 c in vacuum
    Journal of The European Ceramic Society, 2017
    Co-Authors: Shlomit Zamir
    Abstract:

    Abstract Measurement of the Solubility Limit of Si in yttrium aluminum garnet (YAG-Y3Al5O12) is crucial for understanding the mechanisms by which Si influences grain boundary mobility, and the mechanisms by which grain boundaries migrate. In the present work, the Solubility Limit of Si in YAG at 1700 °C in vacuum (5 × 10−6 Torr), which are the most common sintering temperature and environment for YAG, was measured for the first time. Measurements were conducted by wavelength dispersive spectroscopy (WDS), using polished YAG specimens with 3700 ppm Si (0.8 wt% SiO2). Si content to ensure saturation with Si. The accuracy of the WDS result was confirmed by using a series of doped specimens and by comparing to inductively coupled plasma mass spectrometry ICP-MS results. The results indicate that the Solubility Limit of Si in YAG at 1700 °C (5 × 10−6 Torr), is 980 ± 60 ppm. The measured Si Solubility was found to significantly depend on the cooling rate, where for furnace cooled specimens the measured Si Solubility was 650 ± 60 ppm. A second phase in triple junction was repeatedly observed when higher content of Si was used, confirming this work results.

J.c. Choi - One of the best experts on this subject based on the ideXlab platform.

Ellen Wachtel - One of the best experts on this subject based on the ideXlab platform.

Xusheng Wang - One of the best experts on this subject based on the ideXlab platform.

  • dielectric nonlinear properties of batio3 catio3 srtio3 ceramics near the Solubility Limit
    Materials Chemistry and Physics, 2008
    Co-Authors: Xusheng Wang, Lingling Zhang, Hong Liu, Jiwei Zhai, Xi Yao
    Abstract:

    Abstract Ba 1− x − y Sr y Ca x TiO 3 ( x  = 0.2–0.5, and y  = 0, 0.05 and 0.1) ceramics were prepared by conventional ceramic method at 1400 °C, and their structural and dielectric properties were characterized near the Solubility Limit. It was found that the Solubility Limit lay around x  = 0.24 for Ba 1− x Ca x TiO 3 series, x  = 0.30 for Ba 0.95− x Sr 0.05 Ca x TiO 3 series, and x  = 0.34 for Ba 0.9− x Sr 0.1 Ca x TiO 3 series, respectively. The dielectric constant increased obviously near the Solubility Limit. Appropriate tunability values ( n r  = 0.22–0.38) were obtained in the Ba 0.95− x Sr 0.05 Ca x TiO 3 and Ba 0.9− x Sr 0.1 Ca x TiO 3 samples near the Solubility Limit and in the insoluble area, though the samples contained large fraction of non-ferroelectric phase.

  • Dielectric nonlinear properties of BaTiO3–CaTiO3–SrTiO3 ceramics near the Solubility Limit
    Materials Chemistry and Physics, 2008
    Co-Authors: Xusheng Wang, Lingling Zhang, Hong Liu, Jiwei Zhai, Xi Yao
    Abstract:

    Abstract Ba 1− x − y Sr y Ca x TiO 3 ( x  = 0.2–0.5, and y  = 0, 0.05 and 0.1) ceramics were prepared by conventional ceramic method at 1400 °C, and their structural and dielectric properties were characterized near the Solubility Limit. It was found that the Solubility Limit lay around x  = 0.24 for Ba 1− x Ca x TiO 3 series, x  = 0.30 for Ba 0.95− x Sr 0.05 Ca x TiO 3 series, and x  = 0.34 for Ba 0.9− x Sr 0.1 Ca x TiO 3 series, respectively. The dielectric constant increased obviously near the Solubility Limit. Appropriate tunability values ( n r  = 0.22–0.38) were obtained in the Ba 0.95− x Sr 0.05 Ca x TiO 3 and Ba 0.9− x Sr 0.1 Ca x TiO 3 samples near the Solubility Limit and in the insoluble area, though the samples contained large fraction of non-ferroelectric phase.

  • Large electrostriction near the Solubility Limit in BaTiO3–CaTiO3 ceramics
    Applied Physics Letters, 2005
    Co-Authors: Xusheng Wang, Hiroshi Yamada
    Abstract:

    This study prepared (1−x)BaTiO3–xCaTiO3 (x=0.20–1.0) ceramics. Their structural and electric properties were analyzed. High electrostrictive strain of 0.22%, higher by 157% as compared to BaTiO3 ceramic, was obtained near the Solubility Limit in the side of composite (x=0.23), which is a diphasic ceramic composed of a ferroelectric tetragonal Ba0.8Ca0.2TiO3 solid solution and a normal dielectric orthorhombic Ba0.07Ca0.93TiO3 solid solution. This enhanced electrostriction resulted from the coupling of the large ionic polarization in Ba0.07Ca0.93TiO3 with the non-180° domains in Ba0.8Ca0.2TiO3 during the external electric field exertion.

  • large electrostriction near the Solubility Limit in batio3 catio3 ceramics
    Applied Physics Letters, 2005
    Co-Authors: Xusheng Wang, Hiroshi Yamada
    Abstract:

    This study prepared (1−x)BaTiO3–xCaTiO3 (x=0.20–1.0) ceramics. Their structural and electric properties were analyzed. High electrostrictive strain of 0.22%, higher by 157% as compared to BaTiO3 ceramic, was obtained near the Solubility Limit in the side of composite (x=0.23), which is a diphasic ceramic composed of a ferroelectric tetragonal Ba0.8Ca0.2TiO3 solid solution and a normal dielectric orthorhombic Ba0.07Ca0.93TiO3 solid solution. This enhanced electrostriction resulted from the coupling of the large ionic polarization in Ba0.07Ca0.93TiO3 with the non-180° domains in Ba0.8Ca0.2TiO3 during the external electric field exertion.