Spectral Overlap

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Jamie D. Phillips - One of the best experts on this subject based on the ideXlab platform.

  • resolving Spectral Overlap issue of intermediate band solar cells using non uniform sub bandgap state filling
    Progress in Photovoltaics, 2014
    Co-Authors: Albert Lin, Jamie D. Phillips
    Abstract:

    Intermediate band solar cell provides novel alternative to multi-junction solar cell, but its efficiency is significantly degraded when Spectral Overlap exists between different absorption bands. Here, a scheme using non-uniform sub-bandgap state filling together with intermediate band transport is proposed to resolve the Spectral Overlap issue. On the basis of detailed balance calculation, Spectrally decoupled devices using low–high state filling is shown to achieve 52.8% conversion efficiency when 4eV Spectral Overlap is present between absorption coefficients of different bands, compared with baseline efficiency equal to 35.1% for conventional half-filled intermediate band devices. If a base material without intermediate band is added to the two section low–high state filling devices, the efficiency is further increased to 61.5%, which approaches efficiency of 63.2% for intermediate band devices with no Spectral Overlap and 63.8% for unconstrained triple-junction tandem cells. The junction thermalization loss associated with proposed new structures is shown to be equal to conventional half-filled intermediate band devices. Copyright © 2013 John Wiley & Sons, Ltd.

  • Resolving Spectral Overlap issue of intermediate band solar cells using non‐uniform sub‐bandgap state filling
    Progress in Photovoltaics: Research and Applications, 2013
    Co-Authors: Albert Lin, Jamie D. Phillips
    Abstract:

    Intermediate band solar cell provides novel alternative to multi-junction solar cell, but its efficiency is significantly degraded when Spectral Overlap exists between different absorption bands. Here, a scheme using non-uniform sub-bandgap state filling together with intermediate band transport is proposed to resolve the Spectral Overlap issue. On the basis of detailed balance calculation, Spectrally decoupled devices using low–high state filling is shown to achieve 52.8% conversion efficiency when 4eV Spectral Overlap is present between absorption coefficients of different bands, compared with baseline efficiency equal to 35.1% for conventional half-filled intermediate band devices. If a base material without intermediate band is added to the two section low–high state filling devices, the efficiency is further increased to 61.5%, which approaches efficiency of 63.2% for intermediate band devices with no Spectral Overlap and 63.8% for unconstrained triple-junction tandem cells. The junction thermalization loss associated with proposed new structures is shown to be equal to conventional half-filled intermediate band devices. Copyright © 2013 John Wiley & Sons, Ltd.

  • Decoupling Spectral Overlap of intermediate band solar cells using low-high state filling
    2012 38th IEEE Photovoltaic Specialists Conference, 2012
    Co-Authors: Albert Lin, Jamie D. Phillips
    Abstract:

    The high efficiency predicted for solar cells based on multi-photon processes relies on the assumption of optical transitions with non-Overlapping Spectral bands. Spectral Overlap reduces the conversion efficiency due to energy loss associated with improper usage of higher energy photons for lower energy optical transitions. In this study, device structures with non-uniform occupation of intermediate electronic states are proposed to reduce the dependence of conversion efficiency on Spectral Overlap. Solar cell conversion efficiencies are calculated for structures where absorption bands are spatially decoupled due to defined occupation of intermediate states. Conversion efficiencies for a two section and three section device with Spectral Overlap of 4 eV are determined to be 52.8 % and 61.5 %, respectively, and are significantly larger than the calculated efficiency of 35.1% for the case of a standard multi-photon cell with uniform half-filled intermediate states The Spectrally-decoupled device provides a means to achieve high theoretical efficiency independent of Spectral Overlap that approaches the detailed balance efficiency limit of 63.2 % for intermediate state devices without Spectral Overlap and 63.8 % for unconstrained triple—junction tandem cells.

Albert Lin - One of the best experts on this subject based on the ideXlab platform.

  • resolving Spectral Overlap issue of intermediate band solar cells using non uniform sub bandgap state filling
    Progress in Photovoltaics, 2014
    Co-Authors: Albert Lin, Jamie D. Phillips
    Abstract:

    Intermediate band solar cell provides novel alternative to multi-junction solar cell, but its efficiency is significantly degraded when Spectral Overlap exists between different absorption bands. Here, a scheme using non-uniform sub-bandgap state filling together with intermediate band transport is proposed to resolve the Spectral Overlap issue. On the basis of detailed balance calculation, Spectrally decoupled devices using low–high state filling is shown to achieve 52.8% conversion efficiency when 4eV Spectral Overlap is present between absorption coefficients of different bands, compared with baseline efficiency equal to 35.1% for conventional half-filled intermediate band devices. If a base material without intermediate band is added to the two section low–high state filling devices, the efficiency is further increased to 61.5%, which approaches efficiency of 63.2% for intermediate band devices with no Spectral Overlap and 63.8% for unconstrained triple-junction tandem cells. The junction thermalization loss associated with proposed new structures is shown to be equal to conventional half-filled intermediate band devices. Copyright © 2013 John Wiley & Sons, Ltd.

  • Resolving Spectral Overlap issue of intermediate band solar cells using non‐uniform sub‐bandgap state filling
    Progress in Photovoltaics: Research and Applications, 2013
    Co-Authors: Albert Lin, Jamie D. Phillips
    Abstract:

    Intermediate band solar cell provides novel alternative to multi-junction solar cell, but its efficiency is significantly degraded when Spectral Overlap exists between different absorption bands. Here, a scheme using non-uniform sub-bandgap state filling together with intermediate band transport is proposed to resolve the Spectral Overlap issue. On the basis of detailed balance calculation, Spectrally decoupled devices using low–high state filling is shown to achieve 52.8% conversion efficiency when 4eV Spectral Overlap is present between absorption coefficients of different bands, compared with baseline efficiency equal to 35.1% for conventional half-filled intermediate band devices. If a base material without intermediate band is added to the two section low–high state filling devices, the efficiency is further increased to 61.5%, which approaches efficiency of 63.2% for intermediate band devices with no Spectral Overlap and 63.8% for unconstrained triple-junction tandem cells. The junction thermalization loss associated with proposed new structures is shown to be equal to conventional half-filled intermediate band devices. Copyright © 2013 John Wiley & Sons, Ltd.

  • Decoupling Spectral Overlap of intermediate band solar cells using low-high state filling
    2012 38th IEEE Photovoltaic Specialists Conference, 2012
    Co-Authors: Albert Lin, Jamie D. Phillips
    Abstract:

    The high efficiency predicted for solar cells based on multi-photon processes relies on the assumption of optical transitions with non-Overlapping Spectral bands. Spectral Overlap reduces the conversion efficiency due to energy loss associated with improper usage of higher energy photons for lower energy optical transitions. In this study, device structures with non-uniform occupation of intermediate electronic states are proposed to reduce the dependence of conversion efficiency on Spectral Overlap. Solar cell conversion efficiencies are calculated for structures where absorption bands are spatially decoupled due to defined occupation of intermediate states. Conversion efficiencies for a two section and three section device with Spectral Overlap of 4 eV are determined to be 52.8 % and 61.5 %, respectively, and are significantly larger than the calculated efficiency of 35.1% for the case of a standard multi-photon cell with uniform half-filled intermediate states The Spectrally-decoupled device provides a means to achieve high theoretical efficiency independent of Spectral Overlap that approaches the detailed balance efficiency limit of 63.2 % for intermediate state devices without Spectral Overlap and 63.8 % for unconstrained triple—junction tandem cells.

Chun-kit Chan - One of the best experts on this subject based on the ideXlab platform.

Andrzej Ke¸dziorski - One of the best experts on this subject based on the ideXlab platform.

  • Efficiency of the energy transfer in lanthanide-organic chelates; Spectral Overlap integral
    Journal of Luminescence, 2010
    Co-Authors: Lidia Smentek, Andrzej Ke¸dziorski
    Abstract:

    Abstract The present work is devoted to the evaluation of the efficiency of the sensitized luminescence of the lanthanide complexes. In particular the dependence of the quantum yield of the luminescence on the physical factors that determine the Spectral Overlap integral is analyzed in detail. The calculations are based on the model of the evaluation of the Spectral Overlap integral proposed by Malta. It is shown that the theoretical trend in the change of the quantum yield reproduces the general properties of the experimental behavior observed in particular for Tb 3+ complexes.

Shuang Gao - One of the best experts on this subject based on the ideXlab platform.