Tannin Derivative

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Romagnoli Roberto - One of the best experts on this subject based on the ideXlab platform.

  • Quaternary Ammonium “Tannate” for Antifouling Coatings
    'American Chemical Society (ACS)', 2020
    Co-Authors: Bellotti Natalia, Del Amo, Delia Beatriz, Romagnoli Roberto
    Abstract:

    The undesirable accumulation of a wide variety of marine organisms (biofouling) on ship hulls can lead to significantly increased costs, principally by increased fuel consumption to maintain cruising speed. Generally, these coatings have bioactive compounds, called biocides. In this sense, this paper deals with the assessment of the antifouling properties of a natural product Derivative obtained from "quebracho" Tannin and a quaternary ammonium salt (hexadecyltrimethylammonium bromide ([CH3(CH2)15N(CH3)3]Br). Two Derivatives were obtained depending on the precipitation pH (4 and 8). The bioactivity of these Derivatives was assessed by means of the Artemia test. Furthermore, soluble matrix paints were prepared with two different binders: rosin/oleic acid and rosin/styrene-acrylate copolymer. The leaching of "quebracho" Tannin Derivatives from coatings in artificial seawater was monitored until constant values were obtained, previous to the immersion in natural environments. Finally, the antifouling activity of coatings pigmented with the "quebracho" Tannin Derivative was evaluated in Mar del Plata harbor (38°08′17″S-57 31′18″W). The coating obtained with the Derivative obtained at pH 4 and rosin/oleic acid as binder proved to have an acceptable efficiency for 10 months.Centro de Investigación y Desarrollo en Tecnología de Pintura

  • "Quebracho" Tannin Derivative and boosters biocides for new antifouling formulations
    'Springer Science and Business Media LLC', 2012
    Co-Authors: Bellotti Natalia, Deya, Marta Cecilia, Del Amo, Delia Beatriz, Romagnoli Roberto
    Abstract:

    The growth of fouling communities on ships' hulls causes economic losses due to increased fuel consumption and to the deterioration of the metallic substrate by corrosion. Antifouling paints are formulated to avoid the settlement of these organisms and may contain biocides as active compounds. The objective of this research was to evaluate the antifouling performance of paints formulated with a "quebracho" Tannin Derivative (zinc "tannate") and "boosters" (secondary biocides). The "boosters" used in this study were bismuth lactate, a zeolite exchanged with silver cations, and the same zeolite modified with silver chloride. Bioassays with "boosters" solutions were carried out employing Artemia persimilis. Soluble matrix antifouling paints were formulated and their action was assessed in a natural sea water environment. Results showed that the bismuth lactate resulted in a coating with almost triple service life of the antifouling paints with zinc "tannate." Paints formulated with the silver composites behaved slightly better than the control paint.Fil: Bellotti, Natalia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: M.C. Deyá. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: del Amo, Delia Beatriz. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Romagnoli, Roberto. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentin

R. Romagnoli - One of the best experts on this subject based on the ideXlab platform.

  • “Quebracho” Tannin Derivative and boosters biocides for new antifouling formulations
    Journal of Coatings Technology and Research, 2012
    Co-Authors: N. Bellotti, C. Deyá, B. Amo, R. Romagnoli
    Abstract:

    The growth of fouling communities on ships’ hulls causes economic losses due to increased fuel consumption and to the deterioration of the metallic substrate by corrosion. Antifouling paints are formulated to avoid the settlement of these organisms and may contain biocides as active compounds. The objective of this research was to evaluate the antifouling performance of paints formulated with a “quebracho” Tannin Derivative (zinc “tannate”) and “boosters” (secondary biocides). The “boosters” used in this study were bismuth lactate, a zeolite exchanged with silver cations, and the same zeolite modified with silver chloride. Bioassays with “boosters” solutions were carried out employing Artemia persimilis . Soluble matrix antifouling paints were formulated and their action was assessed in a natural sea water environment. Results showed that the bismuth lactate resulted in a coating with almost triple service life of the antifouling paints with zinc “tannate.” Paints formulated with the silver composites behaved slightly better than the control paint.

Bellotti Natalia - One of the best experts on this subject based on the ideXlab platform.

  • Quaternary Ammonium “Tannate” for Antifouling Coatings
    'American Chemical Society (ACS)', 2020
    Co-Authors: Bellotti Natalia, Del Amo, Delia Beatriz, Romagnoli Roberto
    Abstract:

    The undesirable accumulation of a wide variety of marine organisms (biofouling) on ship hulls can lead to significantly increased costs, principally by increased fuel consumption to maintain cruising speed. Generally, these coatings have bioactive compounds, called biocides. In this sense, this paper deals with the assessment of the antifouling properties of a natural product Derivative obtained from "quebracho" Tannin and a quaternary ammonium salt (hexadecyltrimethylammonium bromide ([CH3(CH2)15N(CH3)3]Br). Two Derivatives were obtained depending on the precipitation pH (4 and 8). The bioactivity of these Derivatives was assessed by means of the Artemia test. Furthermore, soluble matrix paints were prepared with two different binders: rosin/oleic acid and rosin/styrene-acrylate copolymer. The leaching of "quebracho" Tannin Derivatives from coatings in artificial seawater was monitored until constant values were obtained, previous to the immersion in natural environments. Finally, the antifouling activity of coatings pigmented with the "quebracho" Tannin Derivative was evaluated in Mar del Plata harbor (38°08′17″S-57 31′18″W). The coating obtained with the Derivative obtained at pH 4 and rosin/oleic acid as binder proved to have an acceptable efficiency for 10 months.Centro de Investigación y Desarrollo en Tecnología de Pintura

  • "Quebracho" Tannin Derivative and boosters biocides for new antifouling formulations
    'Springer Science and Business Media LLC', 2012
    Co-Authors: Bellotti Natalia, Deya, Marta Cecilia, Del Amo, Delia Beatriz, Romagnoli Roberto
    Abstract:

    The growth of fouling communities on ships' hulls causes economic losses due to increased fuel consumption and to the deterioration of the metallic substrate by corrosion. Antifouling paints are formulated to avoid the settlement of these organisms and may contain biocides as active compounds. The objective of this research was to evaluate the antifouling performance of paints formulated with a "quebracho" Tannin Derivative (zinc "tannate") and "boosters" (secondary biocides). The "boosters" used in this study were bismuth lactate, a zeolite exchanged with silver cations, and the same zeolite modified with silver chloride. Bioassays with "boosters" solutions were carried out employing Artemia persimilis. Soluble matrix antifouling paints were formulated and their action was assessed in a natural sea water environment. Results showed that the bismuth lactate resulted in a coating with almost triple service life of the antifouling paints with zinc "tannate." Paints formulated with the silver composites behaved slightly better than the control paint.Fil: Bellotti, Natalia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: M.C. Deyá. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: del Amo, Delia Beatriz. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Romagnoli, Roberto. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentin

N. Bellotti - One of the best experts on this subject based on the ideXlab platform.

  • “Quebracho” Tannin Derivative and boosters biocides for new antifouling formulations
    Journal of Coatings Technology and Research, 2012
    Co-Authors: N. Bellotti, C. Deyá, B. Amo, R. Romagnoli
    Abstract:

    The growth of fouling communities on ships’ hulls causes economic losses due to increased fuel consumption and to the deterioration of the metallic substrate by corrosion. Antifouling paints are formulated to avoid the settlement of these organisms and may contain biocides as active compounds. The objective of this research was to evaluate the antifouling performance of paints formulated with a “quebracho” Tannin Derivative (zinc “tannate”) and “boosters” (secondary biocides). The “boosters” used in this study were bismuth lactate, a zeolite exchanged with silver cations, and the same zeolite modified with silver chloride. Bioassays with “boosters” solutions were carried out employing Artemia persimilis . Soluble matrix antifouling paints were formulated and their action was assessed in a natural sea water environment. Results showed that the bismuth lactate resulted in a coating with almost triple service life of the antifouling paints with zinc “tannate.” Paints formulated with the silver composites behaved slightly better than the control paint.

Del Amo, Delia Beatriz - One of the best experts on this subject based on the ideXlab platform.

  • Quaternary Ammonium “Tannate” for Antifouling Coatings
    'American Chemical Society (ACS)', 2020
    Co-Authors: Bellotti Natalia, Del Amo, Delia Beatriz, Romagnoli Roberto
    Abstract:

    The undesirable accumulation of a wide variety of marine organisms (biofouling) on ship hulls can lead to significantly increased costs, principally by increased fuel consumption to maintain cruising speed. Generally, these coatings have bioactive compounds, called biocides. In this sense, this paper deals with the assessment of the antifouling properties of a natural product Derivative obtained from "quebracho" Tannin and a quaternary ammonium salt (hexadecyltrimethylammonium bromide ([CH3(CH2)15N(CH3)3]Br). Two Derivatives were obtained depending on the precipitation pH (4 and 8). The bioactivity of these Derivatives was assessed by means of the Artemia test. Furthermore, soluble matrix paints were prepared with two different binders: rosin/oleic acid and rosin/styrene-acrylate copolymer. The leaching of "quebracho" Tannin Derivatives from coatings in artificial seawater was monitored until constant values were obtained, previous to the immersion in natural environments. Finally, the antifouling activity of coatings pigmented with the "quebracho" Tannin Derivative was evaluated in Mar del Plata harbor (38°08′17″S-57 31′18″W). The coating obtained with the Derivative obtained at pH 4 and rosin/oleic acid as binder proved to have an acceptable efficiency for 10 months.Centro de Investigación y Desarrollo en Tecnología de Pintura

  • "Quebracho" Tannin Derivative and boosters biocides for new antifouling formulations
    'Springer Science and Business Media LLC', 2012
    Co-Authors: Bellotti Natalia, Deya, Marta Cecilia, Del Amo, Delia Beatriz, Romagnoli Roberto
    Abstract:

    The growth of fouling communities on ships' hulls causes economic losses due to increased fuel consumption and to the deterioration of the metallic substrate by corrosion. Antifouling paints are formulated to avoid the settlement of these organisms and may contain biocides as active compounds. The objective of this research was to evaluate the antifouling performance of paints formulated with a "quebracho" Tannin Derivative (zinc "tannate") and "boosters" (secondary biocides). The "boosters" used in this study were bismuth lactate, a zeolite exchanged with silver cations, and the same zeolite modified with silver chloride. Bioassays with "boosters" solutions were carried out employing Artemia persimilis. Soluble matrix antifouling paints were formulated and their action was assessed in a natural sea water environment. Results showed that the bismuth lactate resulted in a coating with almost triple service life of the antifouling paints with zinc "tannate." Paints formulated with the silver composites behaved slightly better than the control paint.Fil: Bellotti, Natalia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: M.C. Deyá. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: del Amo, Delia Beatriz. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Romagnoli, Roberto. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentin