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Louis Fieser - One of the best experts on this subject based on the ideXlab platform.
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titanocene bis triethyl phosphite
Fieser and Fieser's Reagents for Organic Synthesis, 2017Co-Authors: Tselok Ho, Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: alkenes; desulfurative silylation; cyclopentenones; alkenation; n-arylpyrrolidines; cyclopropanes; coupling reactions; polyene synthesis; homopropargylic alcohols; conjugated dienes; Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
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Fieser and Fieser's Reagents for Organic Synthesis - Titanocene Bis(Triethyl Phosphite)
Fieser and Fieser's Reagents for Organic Synthesis, 2017Co-Authors: Tse‐lok Ho, Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: alkenes; desulfurative silylation; cyclopentenones; alkenation; n-arylpyrrolidines; cyclopropanes; coupling reactions; polyene synthesis; homopropargylic alcohols; conjugated dienes; Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
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Fieser and Fieser's Reagents for Organic Synthesis - Titanocene Dichloride - Zinc
Fieser and Fieser's Reagents for Organic Synthesis, 2013Co-Authors: Tse‐lok Ho, Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: titanocene dichloride -zinc; reductive coupling; reduction; allylic substitution; reductive cyclization; organometallic reagents; reduction of epoxides; Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
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Fieser and Fieser's Reagents for Organic Synthesis - 2‐(Trifluoromethyliodonio)‐α,α‐dimethylbenzyloxide
Fieser and Fieser's Reagents for Organic Synthesis, 2013Co-Authors: Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
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Fieser and Fieser's Reagents for Organic Synthesis - Trifluormethanesulfonic Anhydride (Triflic Anhydride)
Fieser and Fieser's Reagents for Organic Synthesis, 2013Co-Authors: Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: oxy group activation; dethioacetalization; triflation; cyclization; dioxyphosphonium triflates; conjugate addition; reduction; cycloaddition; fragmentative elimination; triflation; friedel–Crafts Reactions; pummerer Rearrangement; coupling; Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
Mary Fieser - One of the best experts on this subject based on the ideXlab platform.
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titanocene bis triethyl phosphite
Fieser and Fieser's Reagents for Organic Synthesis, 2017Co-Authors: Tselok Ho, Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: alkenes; desulfurative silylation; cyclopentenones; alkenation; n-arylpyrrolidines; cyclopropanes; coupling reactions; polyene synthesis; homopropargylic alcohols; conjugated dienes; Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
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Fieser and Fieser's Reagents for Organic Synthesis - Titanocene Bis(Triethyl Phosphite)
Fieser and Fieser's Reagents for Organic Synthesis, 2017Co-Authors: Tse‐lok Ho, Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: alkenes; desulfurative silylation; cyclopentenones; alkenation; n-arylpyrrolidines; cyclopropanes; coupling reactions; polyene synthesis; homopropargylic alcohols; conjugated dienes; Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
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Fieser and Fieser's Reagents for Organic Synthesis - Titanocene Dichloride - Zinc
Fieser and Fieser's Reagents for Organic Synthesis, 2013Co-Authors: Tse‐lok Ho, Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: titanocene dichloride -zinc; reductive coupling; reduction; allylic substitution; reductive cyclization; organometallic reagents; reduction of epoxides; Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
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Fieser and Fieser's Reagents for Organic Synthesis - 2‐(Trifluoromethyliodonio)‐α,α‐dimethylbenzyloxide
Fieser and Fieser's Reagents for Organic Synthesis, 2013Co-Authors: Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
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Fieser and Fieser's Reagents for Organic Synthesis - Trifluormethanesulfonic Anhydride (Triflic Anhydride)
Fieser and Fieser's Reagents for Organic Synthesis, 2013Co-Authors: Mary Fieser, Louis FieserAbstract:This article has no abstract. Keywords: oxy group activation; dethioacetalization; triflation; cyclization; dioxyphosphonium triflates; conjugate addition; reduction; cycloaddition; fragmentative elimination; triflation; friedel–Crafts Reactions; pummerer Rearrangement; coupling; Tetrabutylammonium fluoride, TBAF; Tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate
O. S. Pavlova - One of the best experts on this subject based on the ideXlab platform.
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Vapor Pressures for the Acetonitrile + Tetrabutylammonium Bromide, Water + Tetrabutylammonium Bromide, and Acetonitrile + Water + Tetrabutylammonium Bromide Systems
Journal of Chemical & Engineering Data, 2009Co-Authors: Alexander V. Kurzin, Andrey N. Evdokimov, Victorija B. Antipina, O. S. PavlovaAbstract:The vapor pressures of the acetonitrile + Tetrabutylammonium bromide, water + Tetrabutylammonium bromide, and acetonitrile + water + Tetrabutylammonium bromide systems have been measured at five constant salt molalities [(0.200, 0.400, 0.600, 0.800, and 1.000) mol·kg−1]. These systems have been studied at (298.15 and 323.15) K with a modified Othmer still.
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Vapor Pressures for 1,4-Dioxane + Tetrabutylammonium Nitrate, Water + Tetrabutylammonium Nitrate, and 1,4-Dioxane + Water + Tetrabutylammonium Nitrate
Journal of Chemical & Engineering Data, 2008Co-Authors: Alexander V. Kurzin, Andrey N. Evdokimov, Victorija B. Antipina, O. S. Pavlova, Vladimir E. GusevAbstract:The vapor pressures of the 1,4-dioxane + Tetrabutylammonium nitrate and water + Tetrabutylammonium nitrate systems have been measured at different salt molalities. The vapor pressures of the 1,4-dioxane + water + Tetrabutylammonium nitrate system have also been measured at 11 constant salt molalities (0.100, 0.250, 0.500, 0.750, 1.000, 1.500, 2.000, 2.500, 3.000, 3.500, and 4.000) mol·kg−1. These systems have been studied at (288.15, 298.15, and 308.15) K with a modified Othmer still. The electrolyte nonrandom two-liquid model was used for the calculation of the activity coefficients of solvents in the binary systems.
Alexander V. Kurzin - One of the best experts on this subject based on the ideXlab platform.
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Vapor Pressures for the Acetonitrile + Tetrabutylammonium Bromide, Water + Tetrabutylammonium Bromide, and Acetonitrile + Water + Tetrabutylammonium Bromide Systems
Journal of Chemical & Engineering Data, 2009Co-Authors: Alexander V. Kurzin, Andrey N. Evdokimov, Victorija B. Antipina, O. S. PavlovaAbstract:The vapor pressures of the acetonitrile + Tetrabutylammonium bromide, water + Tetrabutylammonium bromide, and acetonitrile + water + Tetrabutylammonium bromide systems have been measured at five constant salt molalities [(0.200, 0.400, 0.600, 0.800, and 1.000) mol·kg−1]. These systems have been studied at (298.15 and 323.15) K with a modified Othmer still.
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Vapor Pressures for 1,4-Dioxane + Tetrabutylammonium Nitrate, Water + Tetrabutylammonium Nitrate, and 1,4-Dioxane + Water + Tetrabutylammonium Nitrate
Journal of Chemical & Engineering Data, 2008Co-Authors: Alexander V. Kurzin, Andrey N. Evdokimov, Victorija B. Antipina, O. S. Pavlova, Vladimir E. GusevAbstract:The vapor pressures of the 1,4-dioxane + Tetrabutylammonium nitrate and water + Tetrabutylammonium nitrate systems have been measured at different salt molalities. The vapor pressures of the 1,4-dioxane + water + Tetrabutylammonium nitrate system have also been measured at 11 constant salt molalities (0.100, 0.250, 0.500, 0.750, 1.000, 1.500, 2.000, 2.500, 3.000, 3.500, and 4.000) mol·kg−1. These systems have been studied at (288.15, 298.15, and 308.15) K with a modified Othmer still. The electrolyte nonrandom two-liquid model was used for the calculation of the activity coefficients of solvents in the binary systems.
Kenji Sakamoto - One of the best experts on this subject based on the ideXlab platform.
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synthesis of triphenyl phosphate and benzyl benzoate with phase transfer catalyst in a heterogeneous liquid liquid reaction system
Industrial & Engineering Chemistry Research, 1994Co-Authors: Satoru Asai, Mitsunori Tanabe, Hidemi Nakamura, Kenji SakamotoAbstract:The synthetic reactions of triphenyl phosphate from diphenylphosphoryl chloride and sodium phenoxide and of benzyl benzoate from benzyl chloride and sodium benzoate with phase-transfer catalyst were studied in a heterogeneous liquid-liquid reaction system using an agitated vessel with a flat interface. Tetrabutylammonium bromide and 1,2-dichloroethane were used as a catalyst and a solvent, respectively. The behavior of the observed overall reaction rates was explained well by the proposed model. The overall reaction rates were proportional to the organic-phase interfacial concentrations of the actual reactants, Tetrabutylammonium phenoxide for the synthesis of triphenyl phosphate and Tetrabutylammonium benzoate for that of benzyl benzoate. Their interfacial concentrations were a unique function of the concentrations of Tetrabutylammonium bromide and the respective sodium salts. The intrinsic reaction rate constants, for the synthetic reactions of triphenyl phosphate and benzyl benzoate, which were evaluated by fitting the rate data to the model prediction, were 2.33X10 6 and 2.56 m 3 /kmol.s at 303K, respectively
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Distribution and dissociation equilibria of phase-transfer catalysts, Tetrabutylammonium salts
Industrial & Engineering Chemistry Research, 1993Co-Authors: Satoru Asai, Mitsunori Tanabe, Hidemi Nakamura, Kenji SakamotoAbstract:The distribution and dissociation equilibria of phase-transfer catalysts, Tetrabutylammonium salts (Q + Br, Q + Cl - , Q + OH - ), were measured at 303 K for the systems of 1,2-dichloroethane-water and aqueous electrolyte solutions. Furthermore, those of Q + C 6 H 5 O 2 - and Q + C 6 H 5 CO 2 - were evaluated at 303 K from the system of Q + Br - /1,2-dichloroethane/aqueous C 6 H 5 ONa and C 6 H 5 CO 2 Na solutions, respectively. The equilibrium relations varied greatly depending on the kinds of anionic group of the Tetrabutylammonium salts. The evaluated distribution coefficients of Tetrabutylammonium salts were correlated as a function of the ionic strength in the aqueous phase. The dissociation constants of Tetrabutylammonium salts were substantially independent of the ionic strength
