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Liu Chenguang - One of the best experts on this subject based on the ideXlab platform.
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Preparation of unsupported and mesoporous Ni-Mo-W sulfide catalysts by low temperature solid-state reaction
Journal of China University of Petroleum, 2007Co-Authors: Liu ChenguangAbstract:A novel preparation method of diesel oil deeply-hydrotreating catalysts was introduced.By using Ammonium Tetrathiomolybdate,Ammonium tetrathiotungstate and basic nickel carbonate as the catalyst precursors and compound MS-1 as the template unsupported Ni-Mo-W sulfide catalysts with higher specific surface area,proper pore volume and mesoporous structure were synthesized through the technology of low temperature solid-state surface reaction.The X-ray diffraction(XRD),low temperature N2 adsorption(BET method),scanning electron microscopy(SEM) and high resolution transmission electron microscope(HRTEM) were employed to characterize the as-synthesized sulfide catalysts.The as-synthesized catalysts were evaluated in the high-pressure vessel by utilizing FCC diesel oil as the material.The evaluation results show that the assynthesized sulfide catalysts have excellent performance of hydrodesulfurization and hydrodenitrogenation.