Thermodynamic Work

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Scott T Huxtable - One of the best experts on this subject based on the ideXlab platform.

  • the influence of interface bonding on thermal transport through solid liquid interfaces
    Applied Physics Letters, 2013
    Co-Authors: Hari Harikrishna, William A Ducker, Scott T Huxtable
    Abstract:

    We use time-domain thermoreflectance to show that interface thermal conductance, G, is proportional to the Thermodynamic Work of adhesion between gold and water, WSL, for a series of five alkane-thiol monolayers at the gold-water interface. WSL is a measure of the bond strength across the solid-liquid interface. Differences in bond strength, and thus differences in WSL, are achieved by varying the terminal group (ω-group) of the alkane-thiol monolayers on the gold. The interface thermal conductance values were in the range 60–190 MW m−2 K−1, and the solid-liquid contact angles span from 25° to 118°.

  • The influence of interface bonding on thermal transport through solid–liquid interfaces
    Applied Physics Letters, 2013
    Co-Authors: Hari Harikrishna, William A Ducker, Scott T Huxtable
    Abstract:

    We use time-domain thermoreflectance to show that interface thermal conductance, G, is proportional to the Thermodynamic Work of adhesion between gold and water, WSL, for a series of five alkane-thiol monolayers at the gold-water interface. WSL is a measure of the bond strength across the solid-liquid interface. Differences in bond strength, and thus differences in WSL, are achieved by varying the terminal group (ω-group) of the alkane-thiol monolayers on the gold. The interface thermal conductance values were in the range 60–190 MW m−2 K−1, and the solid-liquid contact angles span from 25° to 118°.

Bryce Alexander Roth - One of the best experts on this subject based on the ideXlab platform.

A. M. Jayannavar - One of the best experts on this subject based on the ideXlab platform.

  • Fluctuation theorems and atypical trajectories
    Journal of Physics A: Mathematical and Theoretical, 2011
    Co-Authors: Mamata Sahoo, Sourabh Lahiri, A. M. Jayannavar
    Abstract:

    In this Work, we have studied simple models that can be solved analytically to illustrate various fluctuation theorems. These fluctuation theorems provide symmetries individually to the distributions of physical quantities like the classical Work ($W_c$), Thermodynamic Work ($W$), total entropy ($\Delta s_{tot}$) and dissipated heat ($Q$), when the system is driven arbitrarily out of equilibrium. All these quantities can be defined for individual trajectories. We have studied the number of trajectories which exhibit behaviour unexpected at the macroscopic level. As the time of observation increases, the fraction of such atypical trajectories decreases, as expected at macroscale. Nature of distributions for the Thermodynamic Work and the entropy production in nonlinear models may exhibit peak (most probable value) in the atypical regime without violating the expected average behaviour. However, dissipated heat and classical Work exhibit peak in the regime of typical behaviour only.

  • Classical and Thermodynamic Work fluctuations
    Indian Journal of Physics, 2010
    Co-Authors: Mamata Sahoo, A. M. Jayannavar
    Abstract:

    We have studied the nature of classical Work (W c ) and Thermodynamic Work (W) fluctuations in systems driven out of equilibrium both in transient and time periodic steady state. As the observation time of a large number of trajectories increases, the fraction of trajectories which exhibit excursions away from the typical behaviour, namely, W c < 0, W < Δ F and dissipated heat Q < 0 decreases as anticipated for macroscopic time scales. An analytical expression for such trajectories is obtained. Trajectory for which W c < 0 may not correspond to W < Δ F or Q < 0. The applicability of steady state fluctuation theorems is discussed in our linear as well as nonlinear models.

  • classical and Thermodynamic Work fluctuations
    arXiv: Classical Physics, 2009
    Co-Authors: Mamata Sahoo, A. M. Jayannavar
    Abstract:

    We have studied the nature of classical Work ($W_{c}$) and Thermodynamic Work ($W$) fluctuations in systems driven out of equilibrium both in transient and time periodic steady state. As the observation time of trajectory increases, we show that the number of trajectories which exhibit excursions away from the typical behaviour i.e., $W_{c}<0$, $W<\Delta F$ and dissipated heat $Q<0$ decreases as anticipated for macroscopic time scales. Analytical expressions for such trajectories are obtained. Trajectory for which $W_{c}<0$ may not correspond to $W<\Delta F$ or $Q<0$. The applicability of steady state fluctuation theorems are discussed in our linear as well as nonlinear models.

  • nonequilibrium Work distributions for a trapped brownian particle in a time dependent magnetic field
    Physical Review E, 2008
    Co-Authors: Arnab Saha, A. M. Jayannavar
    Abstract:

    We study the dynamics of a trapped, charged Brownian particle in the presence of a time-dependent magnetic field. We calculate Work distributions for different time-dependent protocols numerically. In our problem, Thermodynamic Work is related to variation of the vector potential with time as opposed to the earlier studies where the Work is related to time variation of the potentials, a quantity that depends only on the coordinates of the particle. Using the Jarzynski and the Crooks equalities, we show that the free energy of the particle is independent of the magnetic field, thus complementing the Bohr-van Leeuwen theorem. We also show that our system exhibits a parametric resonance in a certain parameter space.

Dimitri N Mavris - One of the best experts on this subject based on the ideXlab platform.

Terry Rudolph - One of the best experts on this subject based on the ideXlab platform.

  • description of quantum coherence in Thermodynamic processes requires constraints beyond free energy
    Nature Communications, 2015
    Co-Authors: Matteo Lostaglio, David Jennings, Terry Rudolph
    Abstract:

    Recent studies have developed fundamental limitations on nanoscale Thermodynamics, in terms of a set of independent free energy relations. Here we show that free energy relations cannot properly describe quantum coherence in Thermodynamic processes. By casting time-asymmetry as a quantifiable, fundamental resource of a quantum state, we arrive at an additional, independent set of Thermodynamic constraints that naturally extend the existing ones. These asymmetry relations reveal that the traditional Szilard engine argument does not extend automatically to quantum coherences, but instead only relational coherences in a multipartite scenario can contribute to Thermodynamic Work. We find that coherence transformations are always irreversible. Our results also reveal additional structural parallels between Thermodynamics and the theory of entanglement.