Variational Procedure

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Vesselin I Dimitrov - One of the best experts on this subject based on the ideXlab platform.

Manoj K Mishra - One of the best experts on this subject based on the ideXlab platform.

  • initial state laser control of curve crossing reactions using the rayleigh ritz Variational Procedure
    Journal of Chemical Physics, 1996
    Co-Authors: Peter Gross, Ashish K Gupta, Deepa B Bairagi, Manoj K Mishra
    Abstract:

    A new two‐step Procedure for laser control of photodissociation is presented. In the first step of the Procedure, we show that control of photodissociation product yields can be exerted through preparation of the initial wave function prior to application of the photodissociation field in contrast to previous laser control studies where attention has focused on the design of the field which induces dissociation. Specifically, for a chosen channel from which maximum product yield is desired and a given photodissociation field, the optimal linear combination of vibrational eigenstates which comprise the initial wave function is found using a straightforward Variational calculation. Any photodissociation pulse shape and amplitude can be assumed since the Schrodinger equation is solved directly. Application of this method to control of product yields in the photodissociation of hydrogen iodide is demonstrated. The second step of the control Procedure involves the preparation of the coherent superposition of d...

  • Initial state laser control of curve‐crossing reactions using the Rayleigh–Ritz Variational Procedure
    Journal of Chemical Physics, 1996
    Co-Authors: Peter Gross, Ashish K Gupta, Deepa B Bairagi, Manoj K Mishra
    Abstract:

    A new two‐step Procedure for laser control of photodissociation is presented. In the first step of the Procedure, we show that control of photodissociation product yields can be exerted through preparation of the initial wave function prior to application of the photodissociation field in contrast to previous laser control studies where attention has focused on the design of the field which induces dissociation. Specifically, for a chosen channel from which maximum product yield is desired and a given photodissociation field, the optimal linear combination of vibrational eigenstates which comprise the initial wave function is found using a straightforward Variational calculation. Any photodissociation pulse shape and amplitude can be assumed since the Schrodinger equation is solved directly. Application of this method to control of product yields in the photodissociation of hydrogen iodide is demonstrated. The second step of the control Procedure involves the preparation of the coherent superposition of d...

P. A. Terziev - One of the best experts on this subject based on the ideXlab platform.

  • Variational Procedure leading from Davidson potentials to the E(5)and X(5) critical point symmetries
    HNPS Proceedings, 2020
    Co-Authors: Dennis Bonatsos, D. Lenis, Nikolay Minkov, D. Petrellis, P. P. Raychev, P. A. Terziev
    Abstract:

    Davidson potentials of the form β^2 + β0^4/β^2, when used in the original Bohr Hamiltonian for γ-independent potentials bridge the U(5) and 0(6) symmetries. Using a Variational Procedure, we determine for each value of angular momentum L the value of β0 at which the derivative of the energy ratio RL = E(L)/E(2) with respect to β0 has a sharp maximum, the collection of RL values at these points forming a band which practically coincides with the ground state band of the E(5) model, corresponding to the critical point in the shape phase transition from U(5) to Ο(6). The same potentials, when used in the Bohr Hamiltonian after separating variables as in the X(5) model, bridge the U(5) and SU(3) symmetries, the same Variational Procedure leading to a band which practically coincides with the ground state band of the X(5) model, corresponding to the critical point of the U(5) to SU(3) shape phase transition. A new derivation of the Holmberg-Lipas formula for nuclear energy spectra is obtained as a by-product.

  • e 5 and x 5 critical point symmetries obtained from davidson potentials through a Variational Procedure
    Physical Review C, 2004
    Co-Authors: Dennis Bonatsos, D. Lenis, Nikolay Minkov, D. Petrellis, P. P. Raychev, P. A. Terziev
    Abstract:

    Davidson potentials of the form $\beta^2 +\beta_0^4/\beta^2$, when used in the E(5) framework, bridge the U(5) and O(6) symmetries, while they bridge the U(5) and SU(3) symmetries when used in the X(5) framework. Using a Variational Procedure, we determine for each value of angular momentum $L$ thevalue of $\beta_0$ at which the rate of change of various physical quantities (energy ratios, intraband B(E2) ratios, quadrupole moment ratios) has a maximum, the collection of the values of the physical quantity formed in this way being a candidate for describing its behavior at the relevant critical point. Energy ratios lead to the E(5) and X(5) results (whice correspond to an infinite well potential in $\beta$), while intraband B(E2) ratios and quadrupole moments lead to the E(5)-$\beta^4$ and X(5)-$\beta^4$ results, which correspond to the use of a $\beta^4$ potential in the relevant framework. A new derivation of the Holmberg-Lipas formula for nuclear energy spectra is obtained as a by-product.

  • ground state bands of the e 5 and x 5 critical symmetries obtained from davidson potentials through a Variational Procedure
    Physics Letters B, 2004
    Co-Authors: Dennis Bonatsos, D. Lenis, Nikolay Minkov, D. Petrellis, P. P. Raychev, P. A. Terziev
    Abstract:

    Abstract Davidson potentials of the form β 2 + β 0 4 / β 2 , when used in the original Bohr Hamiltonian for γ -independent potentials bridge the U(5) and O(6) symmetries. Using a Variational Procedure, we determine for each value of angular momentum L the value of β 0 at which the derivative of the energy ratio R L = E ( L )/ E (2) with respect to β 0 has a sharp maximum, the collection of R L values at these points forming a band which practically coincides with the ground state band of the E(5) model, corresponding to the critical point in the shape phase transition from U(5) to O(6). The same potentials, when used in the Bohr Hamiltonian after separating variables as in the X(5) model, bridge the U(5) and SU(3) symmetries, the same Variational Procedure leading to a band which practically coincides with the ground state band of the X(5) model, corresponding to the critical point of the U(5) to SU(3) shape phase transition. A new derivation of the Holmberg–Lipas formula for nuclear energy spectra is obtained as a by-product.

Peter Gross - One of the best experts on this subject based on the ideXlab platform.

  • initial state laser control of curve crossing reactions using the rayleigh ritz Variational Procedure
    Journal of Chemical Physics, 1996
    Co-Authors: Peter Gross, Ashish K Gupta, Deepa B Bairagi, Manoj K Mishra
    Abstract:

    A new two‐step Procedure for laser control of photodissociation is presented. In the first step of the Procedure, we show that control of photodissociation product yields can be exerted through preparation of the initial wave function prior to application of the photodissociation field in contrast to previous laser control studies where attention has focused on the design of the field which induces dissociation. Specifically, for a chosen channel from which maximum product yield is desired and a given photodissociation field, the optimal linear combination of vibrational eigenstates which comprise the initial wave function is found using a straightforward Variational calculation. Any photodissociation pulse shape and amplitude can be assumed since the Schrodinger equation is solved directly. Application of this method to control of product yields in the photodissociation of hydrogen iodide is demonstrated. The second step of the control Procedure involves the preparation of the coherent superposition of d...

  • Initial state laser control of curve‐crossing reactions using the Rayleigh–Ritz Variational Procedure
    Journal of Chemical Physics, 1996
    Co-Authors: Peter Gross, Ashish K Gupta, Deepa B Bairagi, Manoj K Mishra
    Abstract:

    A new two‐step Procedure for laser control of photodissociation is presented. In the first step of the Procedure, we show that control of photodissociation product yields can be exerted through preparation of the initial wave function prior to application of the photodissociation field in contrast to previous laser control studies where attention has focused on the design of the field which induces dissociation. Specifically, for a chosen channel from which maximum product yield is desired and a given photodissociation field, the optimal linear combination of vibrational eigenstates which comprise the initial wave function is found using a straightforward Variational calculation. Any photodissociation pulse shape and amplitude can be assumed since the Schrodinger equation is solved directly. Application of this method to control of product yields in the photodissociation of hydrogen iodide is demonstrated. The second step of the control Procedure involves the preparation of the coherent superposition of d...

R Khordad - One of the best experts on this subject based on the ideXlab platform.