Zinc Dichloride

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I P Beletskaya - One of the best experts on this subject based on the ideXlab platform.

Grigoriy N Bondarenko - One of the best experts on this subject based on the ideXlab platform.

Tobias Ranff - One of the best experts on this subject based on the ideXlab platform.

  • synthesis of optically active bis 2 oxazolines crystal structure of a 1 2 bis 2 oxazolinyl benzene zncl2 complex
    1991
    Co-Authors: Carsten Bolm, Konrad Weickhardt, Margareta Zehnder, Tobias Ranff
    Abstract:

    Dinitriles (5–7, 12, 13) react with enantiomerically pure β-amino alcohols (8 – 11,17) under Zinc chloride catalysis to give optically active C2-symmetric bis(oxazolines). 1,2-Bis(2-oxazolin-2-yl)benzenes 1a – e are obtained under mild reaction conditions. 1H-NMR spectroscopy indicates the formation of 1:1 complexes 23 of these compounds with ZnCl2. The energy required for a conformational interconversion of Zinc Dichloride complex 23e was determined by variable-temperature 1H-NMR studies. An X-ray structure analysis was performed with the substituted [1,2-bis(2-oxazolinyl)benzene]Zinc Dichloride complex 23a.

Ekaterina G Dvurechenskaya - One of the best experts on this subject based on the ideXlab platform.

Olga G Ganina - One of the best experts on this subject based on the ideXlab platform.