3 Indolemethanol

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Patrick Rollin - One of the best experts on this subject based on the ideXlab platform.

  • identification of enzymatic degradation products from synthesized glucobrassicin by gas chromatography mass spectrometry
    Journal of Chromatography A, 1991
    Co-Authors: Laurent Latxague, C Gardrat, J L Coustille, Marieclaude Viaud, Patrick Rollin
    Abstract:

    Abstract Synthesized glucobrassicin, an indole glucosinolate present in rape, was submitted to exogenous enzymatic degradation with commercial myrosinase at two different pH values. Organic products were analysed after silylation by gas chromatography using a thermoionic detector. Three products (3-Indolemethanol, 3-indoleacetonitrile and 3,3′-diindolylmethane) were identified by comparison with the retention times of silylated authentic materials and by gas chromatography-mass spectrometry. Two different degradation schemes were proposed according to the pH conditions: 3-indoleacetonitrile was obtained at acidic pH and 3,3′-diindolylmethane at neutral pH. The synthetic glucobrassicin thus behaved in the same manner as the natural product.

Laurent Latxague - One of the best experts on this subject based on the ideXlab platform.

  • identification of enzymatic degradation products from synthesized glucobrassicin by gas chromatography mass spectrometry
    Journal of Chromatography A, 1991
    Co-Authors: Laurent Latxague, C Gardrat, J L Coustille, Marieclaude Viaud, Patrick Rollin
    Abstract:

    Abstract Synthesized glucobrassicin, an indole glucosinolate present in rape, was submitted to exogenous enzymatic degradation with commercial myrosinase at two different pH values. Organic products were analysed after silylation by gas chromatography using a thermoionic detector. Three products (3-Indolemethanol, 3-indoleacetonitrile and 3,3′-diindolylmethane) were identified by comparison with the retention times of silylated authentic materials and by gas chromatography-mass spectrometry. Two different degradation schemes were proposed according to the pH conditions: 3-indoleacetonitrile was obtained at acidic pH and 3,3′-diindolylmethane at neutral pH. The synthetic glucobrassicin thus behaved in the same manner as the natural product.

C Gardrat - One of the best experts on this subject based on the ideXlab platform.

  • identification of enzymatic degradation products from synthesized glucobrassicin by gas chromatography mass spectrometry
    Journal of Chromatography A, 1991
    Co-Authors: Laurent Latxague, C Gardrat, J L Coustille, Marieclaude Viaud, Patrick Rollin
    Abstract:

    Abstract Synthesized glucobrassicin, an indole glucosinolate present in rape, was submitted to exogenous enzymatic degradation with commercial myrosinase at two different pH values. Organic products were analysed after silylation by gas chromatography using a thermoionic detector. Three products (3-Indolemethanol, 3-indoleacetonitrile and 3,3′-diindolylmethane) were identified by comparison with the retention times of silylated authentic materials and by gas chromatography-mass spectrometry. Two different degradation schemes were proposed according to the pH conditions: 3-indoleacetonitrile was obtained at acidic pH and 3,3′-diindolylmethane at neutral pH. The synthetic glucobrassicin thus behaved in the same manner as the natural product.

J L Coustille - One of the best experts on this subject based on the ideXlab platform.

  • identification of enzymatic degradation products from synthesized glucobrassicin by gas chromatography mass spectrometry
    Journal of Chromatography A, 1991
    Co-Authors: Laurent Latxague, C Gardrat, J L Coustille, Marieclaude Viaud, Patrick Rollin
    Abstract:

    Abstract Synthesized glucobrassicin, an indole glucosinolate present in rape, was submitted to exogenous enzymatic degradation with commercial myrosinase at two different pH values. Organic products were analysed after silylation by gas chromatography using a thermoionic detector. Three products (3-Indolemethanol, 3-indoleacetonitrile and 3,3′-diindolylmethane) were identified by comparison with the retention times of silylated authentic materials and by gas chromatography-mass spectrometry. Two different degradation schemes were proposed according to the pH conditions: 3-indoleacetonitrile was obtained at acidic pH and 3,3′-diindolylmethane at neutral pH. The synthetic glucobrassicin thus behaved in the same manner as the natural product.

Marieclaude Viaud - One of the best experts on this subject based on the ideXlab platform.

  • identification of enzymatic degradation products from synthesized glucobrassicin by gas chromatography mass spectrometry
    Journal of Chromatography A, 1991
    Co-Authors: Laurent Latxague, C Gardrat, J L Coustille, Marieclaude Viaud, Patrick Rollin
    Abstract:

    Abstract Synthesized glucobrassicin, an indole glucosinolate present in rape, was submitted to exogenous enzymatic degradation with commercial myrosinase at two different pH values. Organic products were analysed after silylation by gas chromatography using a thermoionic detector. Three products (3-Indolemethanol, 3-indoleacetonitrile and 3,3′-diindolylmethane) were identified by comparison with the retention times of silylated authentic materials and by gas chromatography-mass spectrometry. Two different degradation schemes were proposed according to the pH conditions: 3-indoleacetonitrile was obtained at acidic pH and 3,3′-diindolylmethane at neutral pH. The synthetic glucobrassicin thus behaved in the same manner as the natural product.