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A V Pulya - One of the best experts on this subject based on the ideXlab platform.
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synthesis characteristics and epr study of mn ii and cu ii chelates with a product of condensation of 2 7 bromo 2 oxo 5 phenyl 3 н 1 4 benzodiazepin 1 yl Acetohydrazide and 2 3 dioxoindole
Russian Journal of Inorganic Chemistry, 2019Co-Authors: I I Seifullina, A V Pulya, L S Skorokhod, N N Efimov, E A Ugolkova, V V MininAbstract:The [Mn(HydrHIz)2] ∙ 2H2O (I) and [Cu(HydrHIz)2] (II) complexes (HydrHIz is a hydrozone—the product of condensation of hydrazide and isatin) have been synthesized through self-assembly in the М(СН3СОО)2–2-(7-bromo-2-oxo-5-phenyl-3Н-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–2,3-dioxoindole (HIz)–propan-2-ol systems (М = Mn, Cu). The complexes have been characterized by elemental analysis, electrical conductivity, and IR spectroscopy data. The composition and structure of the coordination cores in I and II have been determined by magnetic susceptibility and EPR spectroscopy methods.
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synthesis and characterization of zn ii complexes of 2 7 bromo 2 oxo 5 phenyl 2 3 dihydro 1 h 1 4 benzodiazepin 1 yl Acetohydrazide and its condensation products with pyruvic acid and isatin
Russian Journal of General Chemistry, 2018Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, V G Vlasenko, A L Trigub, I M RakipovAbstract:The systems ZnCl2–2-(7-bromo-2-oxo-5-phenyl-2,3-dihydro-1H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–propan-2-ol, ZnCl2–Hydr–pyruvic acid (HPv), and Zn(CH3COO)2–Hydr–isatin(HIz)–propan-2-ol were studied. Optimal synthesis conditions were determined, and the complexes [Zn(Hydr)2Cl2], [Zn(HydrHPv)2Cl2], and [Zn(HydrIz)2] were isolated. The complexes were characterized by elemental analysis, thermogravimetry, IR spectroscopy, and mass spectrometry. The electrical conductivities of the complexes were measured. The local environment of the central atom in the coordination entity was determined by X-ray absorption spectroscopy.
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self assembling in the systems мх 2 2 7 bromo 2 oxo 5 phenyl 2 3 dihydro 1 н 1 4 benzdiazepin 1 yl Acetohydrazide salicyl aldehyde м сo ni zn x cl ch 3 coo
Russian Journal of General Chemistry, 2017Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, V G Vlasenko, Ya V Zubavichus, A L Trigub, S I LevchenkovAbstract:By self-assembling in the systems MX2–2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1Н-1,4-benzdiazepin-1-yl)Acetohydrazide (Hydr)–salicyl aldehyde (HSal) (М = Co, Ni, Zn; X = Cl, CH3COO) the complexes of composition [Co(HydrSal)2], [Ni(HydrSal)2], [Zn(HydrHSal)Cl2], [Zn(HydrSal)(CH3COO)(H2O)] have been synthesized. The local atomic structure of the coordination unit was determined by the method of X-ray absorption spectroscopy. Thermal stability, electroconductivity, and magnetic susceptibility of the complexes have been studied.
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products of complexation in the cu ch 3 cоо 2 2 7 bromo 2 oxo 5 phenyl 3h 1 4 benzodiazepin 1 yl Acetohydrazide salicylaldehyde isopropanol system
Russian Journal of Inorganic Chemistry, 2017Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, N N Efimov, E A Ugolkova, V G Vlasenko, S I Levchenkov, Ya V Zubavichus, A L Trigub, V V MininAbstract:Copper(II) complexes isolated from the Cu(CH3COO)2–2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–salicylaldehyde (HSal)–isopropanol system [Cu2(HydrSal)2(μ-CH3COO)] (I), [Cu(HydrSal)2] (II) (HydrSal (hydrazone)is the condensation product of hydrazide and salicylaldehide) are synthesized and investigated. The complexes are characterized by elemental analysis, electrical conductivity measurements, and IR spectroscopy. The composition and structure of the Cu2+ coordination core are determined by ESR spectroscopy (I), magnetic susceptibility measurements and extended X-ray absorption fine structure (EXAFS) spectroscopy (II).
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copper ii coordination compounds with 2 7 bromo 2 oxo 5 phenyl 3h 1 4 benzdiazepin 1 yl Acetohydrazide and products of its condensation with pyruvic acid
Russian Journal of Inorganic Chemistry, 2016Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, N N Efimov, E A Ugolkova, V V MininAbstract:Some methods for the synthesis of copper(II) complexes with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr) ([Cu(Hydr)(H2O)Cl2]) and products of its condensation with pyruvic acid ([Cu(HydrHPv)(H2O)Cl2] and, with alkalization to pH 8, [Cu(HydrPv)2]) were developed, and the complexes themselves were synthesized. The complexes were characterized by electrical conductivity, magnetic susceptibility, and IR and EPR spectroscopy measurements.
I I Seifullina - One of the best experts on this subject based on the ideXlab platform.
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synthesis characteristics and epr study of mn ii and cu ii chelates with a product of condensation of 2 7 bromo 2 oxo 5 phenyl 3 н 1 4 benzodiazepin 1 yl Acetohydrazide and 2 3 dioxoindole
Russian Journal of Inorganic Chemistry, 2019Co-Authors: I I Seifullina, A V Pulya, L S Skorokhod, N N Efimov, E A Ugolkova, V V MininAbstract:The [Mn(HydrHIz)2] ∙ 2H2O (I) and [Cu(HydrHIz)2] (II) complexes (HydrHIz is a hydrozone—the product of condensation of hydrazide and isatin) have been synthesized through self-assembly in the М(СН3СОО)2–2-(7-bromo-2-oxo-5-phenyl-3Н-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–2,3-dioxoindole (HIz)–propan-2-ol systems (М = Mn, Cu). The complexes have been characterized by elemental analysis, electrical conductivity, and IR spectroscopy data. The composition and structure of the coordination cores in I and II have been determined by magnetic susceptibility and EPR spectroscopy methods.
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synthesis and characterization of zn ii complexes of 2 7 bromo 2 oxo 5 phenyl 2 3 dihydro 1 h 1 4 benzodiazepin 1 yl Acetohydrazide and its condensation products with pyruvic acid and isatin
Russian Journal of General Chemistry, 2018Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, V G Vlasenko, A L Trigub, I M RakipovAbstract:The systems ZnCl2–2-(7-bromo-2-oxo-5-phenyl-2,3-dihydro-1H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–propan-2-ol, ZnCl2–Hydr–pyruvic acid (HPv), and Zn(CH3COO)2–Hydr–isatin(HIz)–propan-2-ol were studied. Optimal synthesis conditions were determined, and the complexes [Zn(Hydr)2Cl2], [Zn(HydrHPv)2Cl2], and [Zn(HydrIz)2] were isolated. The complexes were characterized by elemental analysis, thermogravimetry, IR spectroscopy, and mass spectrometry. The electrical conductivities of the complexes were measured. The local environment of the central atom in the coordination entity was determined by X-ray absorption spectroscopy.
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self assembling in the systems мх 2 2 7 bromo 2 oxo 5 phenyl 2 3 dihydro 1 н 1 4 benzdiazepin 1 yl Acetohydrazide salicyl aldehyde м сo ni zn x cl ch 3 coo
Russian Journal of General Chemistry, 2017Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, V G Vlasenko, Ya V Zubavichus, A L Trigub, S I LevchenkovAbstract:By self-assembling in the systems MX2–2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1Н-1,4-benzdiazepin-1-yl)Acetohydrazide (Hydr)–salicyl aldehyde (HSal) (М = Co, Ni, Zn; X = Cl, CH3COO) the complexes of composition [Co(HydrSal)2], [Ni(HydrSal)2], [Zn(HydrHSal)Cl2], [Zn(HydrSal)(CH3COO)(H2O)] have been synthesized. The local atomic structure of the coordination unit was determined by the method of X-ray absorption spectroscopy. Thermal stability, electroconductivity, and magnetic susceptibility of the complexes have been studied.
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products of complexation in the cu ch 3 cоо 2 2 7 bromo 2 oxo 5 phenyl 3h 1 4 benzodiazepin 1 yl Acetohydrazide salicylaldehyde isopropanol system
Russian Journal of Inorganic Chemistry, 2017Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, N N Efimov, E A Ugolkova, V G Vlasenko, S I Levchenkov, Ya V Zubavichus, A L Trigub, V V MininAbstract:Copper(II) complexes isolated from the Cu(CH3COO)2–2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–salicylaldehyde (HSal)–isopropanol system [Cu2(HydrSal)2(μ-CH3COO)] (I), [Cu(HydrSal)2] (II) (HydrSal (hydrazone)is the condensation product of hydrazide and salicylaldehide) are synthesized and investigated. The complexes are characterized by elemental analysis, electrical conductivity measurements, and IR spectroscopy. The composition and structure of the Cu2+ coordination core are determined by ESR spectroscopy (I), magnetic susceptibility measurements and extended X-ray absorption fine structure (EXAFS) spectroscopy (II).
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copper ii coordination compounds with 2 7 bromo 2 oxo 5 phenyl 3h 1 4 benzdiazepin 1 yl Acetohydrazide and products of its condensation with pyruvic acid
Russian Journal of Inorganic Chemistry, 2016Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, N N Efimov, E A Ugolkova, V V MininAbstract:Some methods for the synthesis of copper(II) complexes with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr) ([Cu(Hydr)(H2O)Cl2]) and products of its condensation with pyruvic acid ([Cu(HydrHPv)(H2O)Cl2] and, with alkalization to pH 8, [Cu(HydrPv)2]) were developed, and the complexes themselves were synthesized. The complexes were characterized by electrical conductivity, magnetic susceptibility, and IR and EPR spectroscopy measurements.
L S Skorokhod - One of the best experts on this subject based on the ideXlab platform.
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synthesis characteristics and epr study of mn ii and cu ii chelates with a product of condensation of 2 7 bromo 2 oxo 5 phenyl 3 н 1 4 benzodiazepin 1 yl Acetohydrazide and 2 3 dioxoindole
Russian Journal of Inorganic Chemistry, 2019Co-Authors: I I Seifullina, A V Pulya, L S Skorokhod, N N Efimov, E A Ugolkova, V V MininAbstract:The [Mn(HydrHIz)2] ∙ 2H2O (I) and [Cu(HydrHIz)2] (II) complexes (HydrHIz is a hydrozone—the product of condensation of hydrazide and isatin) have been synthesized through self-assembly in the М(СН3СОО)2–2-(7-bromo-2-oxo-5-phenyl-3Н-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–2,3-dioxoindole (HIz)–propan-2-ol systems (М = Mn, Cu). The complexes have been characterized by elemental analysis, electrical conductivity, and IR spectroscopy data. The composition and structure of the coordination cores in I and II have been determined by magnetic susceptibility and EPR spectroscopy methods.
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synthesis and characterization of zn ii complexes of 2 7 bromo 2 oxo 5 phenyl 2 3 dihydro 1 h 1 4 benzodiazepin 1 yl Acetohydrazide and its condensation products with pyruvic acid and isatin
Russian Journal of General Chemistry, 2018Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, V G Vlasenko, A L Trigub, I M RakipovAbstract:The systems ZnCl2–2-(7-bromo-2-oxo-5-phenyl-2,3-dihydro-1H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–propan-2-ol, ZnCl2–Hydr–pyruvic acid (HPv), and Zn(CH3COO)2–Hydr–isatin(HIz)–propan-2-ol were studied. Optimal synthesis conditions were determined, and the complexes [Zn(Hydr)2Cl2], [Zn(HydrHPv)2Cl2], and [Zn(HydrIz)2] were isolated. The complexes were characterized by elemental analysis, thermogravimetry, IR spectroscopy, and mass spectrometry. The electrical conductivities of the complexes were measured. The local environment of the central atom in the coordination entity was determined by X-ray absorption spectroscopy.
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self assembling in the systems мх 2 2 7 bromo 2 oxo 5 phenyl 2 3 dihydro 1 н 1 4 benzdiazepin 1 yl Acetohydrazide salicyl aldehyde м сo ni zn x cl ch 3 coo
Russian Journal of General Chemistry, 2017Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, V G Vlasenko, Ya V Zubavichus, A L Trigub, S I LevchenkovAbstract:By self-assembling in the systems MX2–2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1Н-1,4-benzdiazepin-1-yl)Acetohydrazide (Hydr)–salicyl aldehyde (HSal) (М = Co, Ni, Zn; X = Cl, CH3COO) the complexes of composition [Co(HydrSal)2], [Ni(HydrSal)2], [Zn(HydrHSal)Cl2], [Zn(HydrSal)(CH3COO)(H2O)] have been synthesized. The local atomic structure of the coordination unit was determined by the method of X-ray absorption spectroscopy. Thermal stability, electroconductivity, and magnetic susceptibility of the complexes have been studied.
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products of complexation in the cu ch 3 cоо 2 2 7 bromo 2 oxo 5 phenyl 3h 1 4 benzodiazepin 1 yl Acetohydrazide salicylaldehyde isopropanol system
Russian Journal of Inorganic Chemistry, 2017Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, N N Efimov, E A Ugolkova, V G Vlasenko, S I Levchenkov, Ya V Zubavichus, A L Trigub, V V MininAbstract:Copper(II) complexes isolated from the Cu(CH3COO)2–2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–salicylaldehyde (HSal)–isopropanol system [Cu2(HydrSal)2(μ-CH3COO)] (I), [Cu(HydrSal)2] (II) (HydrSal (hydrazone)is the condensation product of hydrazide and salicylaldehide) are synthesized and investigated. The complexes are characterized by elemental analysis, electrical conductivity measurements, and IR spectroscopy. The composition and structure of the Cu2+ coordination core are determined by ESR spectroscopy (I), magnetic susceptibility measurements and extended X-ray absorption fine structure (EXAFS) spectroscopy (II).
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copper ii coordination compounds with 2 7 bromo 2 oxo 5 phenyl 3h 1 4 benzdiazepin 1 yl Acetohydrazide and products of its condensation with pyruvic acid
Russian Journal of Inorganic Chemistry, 2016Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, N N Efimov, E A Ugolkova, V V MininAbstract:Some methods for the synthesis of copper(II) complexes with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr) ([Cu(Hydr)(H2O)Cl2]) and products of its condensation with pyruvic acid ([Cu(HydrHPv)(H2O)Cl2] and, with alkalization to pH 8, [Cu(HydrPv)2]) were developed, and the complexes themselves were synthesized. The complexes were characterized by electrical conductivity, magnetic susceptibility, and IR and EPR spectroscopy measurements.
V V Minin - One of the best experts on this subject based on the ideXlab platform.
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synthesis characteristics and epr study of mn ii and cu ii chelates with a product of condensation of 2 7 bromo 2 oxo 5 phenyl 3 н 1 4 benzodiazepin 1 yl Acetohydrazide and 2 3 dioxoindole
Russian Journal of Inorganic Chemistry, 2019Co-Authors: I I Seifullina, A V Pulya, L S Skorokhod, N N Efimov, E A Ugolkova, V V MininAbstract:The [Mn(HydrHIz)2] ∙ 2H2O (I) and [Cu(HydrHIz)2] (II) complexes (HydrHIz is a hydrozone—the product of condensation of hydrazide and isatin) have been synthesized through self-assembly in the М(СН3СОО)2–2-(7-bromo-2-oxo-5-phenyl-3Н-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–2,3-dioxoindole (HIz)–propan-2-ol systems (М = Mn, Cu). The complexes have been characterized by elemental analysis, electrical conductivity, and IR spectroscopy data. The composition and structure of the coordination cores in I and II have been determined by magnetic susceptibility and EPR spectroscopy methods.
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products of complexation in the cu ch 3 cоо 2 2 7 bromo 2 oxo 5 phenyl 3h 1 4 benzodiazepin 1 yl Acetohydrazide salicylaldehyde isopropanol system
Russian Journal of Inorganic Chemistry, 2017Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, N N Efimov, E A Ugolkova, V G Vlasenko, S I Levchenkov, Ya V Zubavichus, A L Trigub, V V MininAbstract:Copper(II) complexes isolated from the Cu(CH3COO)2–2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr)–salicylaldehyde (HSal)–isopropanol system [Cu2(HydrSal)2(μ-CH3COO)] (I), [Cu(HydrSal)2] (II) (HydrSal (hydrazone)is the condensation product of hydrazide and salicylaldehide) are synthesized and investigated. The complexes are characterized by elemental analysis, electrical conductivity measurements, and IR spectroscopy. The composition and structure of the Cu2+ coordination core are determined by ESR spectroscopy (I), magnetic susceptibility measurements and extended X-ray absorption fine structure (EXAFS) spectroscopy (II).
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copper ii coordination compounds with 2 7 bromo 2 oxo 5 phenyl 3h 1 4 benzdiazepin 1 yl Acetohydrazide and products of its condensation with pyruvic acid
Russian Journal of Inorganic Chemistry, 2016Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, N N Efimov, E A Ugolkova, V V MininAbstract:Some methods for the synthesis of copper(II) complexes with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)Acetohydrazide (Hydr) ([Cu(Hydr)(H2O)Cl2]) and products of its condensation with pyruvic acid ([Cu(HydrHPv)(H2O)Cl2] and, with alkalization to pH 8, [Cu(HydrPv)2]) were developed, and the complexes themselves were synthesized. The complexes were characterized by electrical conductivity, magnetic susceptibility, and IR and EPR spectroscopy measurements.
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synthesis and characterization of mn ii coordination compounds with 2 7 bromo 2 oxo 5 phenyl 3h 1 4 benzdiazepin 1 yl Acetohydrazide and its condensation product with pyruvic acid
Russian Journal of Inorganic Chemistry, 2015Co-Authors: A V Pulya, I I Seifullina, L S Skorokhod, N N Efimov, E A Ugolkova, V V MininAbstract:Complexes of MnCl2 with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzdiazepin-1-yl)Acetohydrazide (Hydr) and its condensation product with pyruvic acid (HPv) of composition [Mn(Hydr)2Cl2] (I) and [Mn(HydrHPv)2Cl2] (II) were prepared. The complexes were characterized by conductivity and magnetic susceptibility measurements, IR and ESR spectroscopy.
Suchetha N Shetty - One of the best experts on this subject based on the ideXlab platform.
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synthesis and antimicrobial activities of some novel 1 2 4 triazolo 3 4 b 1 3 4 thiadiazoles and 1 2 4 triazolo 3 4 b 1 3 4 thiadiazines carrying thioalkyl and sulphonyl phenoxy moieties
European Journal of Medicinal Chemistry, 2007Co-Authors: T Karabasanagouda, Airody Vasudeva Adhikari, Suchetha N ShettyAbstract:Abstract Thirty one new 6-aryl-3-{(4-substituted phenoxy) methyl}-1,2,4-triazolo[3,4- b ]-1,3,4-thiadiazoles ( 6a – s ) and 6-aryl-3-{(4-substituted phenoxy methyl}-7 H -1,2,4-triazolo[3,4- b ]-1,3,4-thiadiazines ( 7a – l ) have been synthesized from 4-thioalkyl phenols ( 1a – b ) through a multi-step reaction sequence. Compounds 1a – b reacted with ethyl chloroacetate in presence of acetone and potassium carbonate to give ethyl [4-(thioalkyl) phenoxy] acetates ( 2a – b ). Further, 2a was oxidized to [4-(methyl sulphonyl) phenoxy] acetate ( 2c ) using hydrogen peroxide in acetic acid. Reactions of ( 2a – c ) with hydrazine hydrate in alcoholic medium furnished 2-[4-thiosubstituted phenoxy] Acetohydrazides ( 3a – b ) and 2-[4-methyl sulphonyl phenoxy] Acetohydrazide ( 3c ) which on treatment with carbon disulphide and methanolic potassium hydroxide yielded corresponding potassium dithiocarbazates ( 4a – c ). They were then converted to 4-amino-5-{(4-thioalkyl phenoxy) methyl}-4 H -1,2,4-triazole-3-thiols ( 5a – b ) and 4-amino-5-{(4-methyl sulphonyl phenoxy) methyl}-4 H -1,2,4-triazole-3-thiol ( 5c ) by refluxing them with aqueous hydrazine hydrate. The title compounds 6a – s were prepared by condensing 5a – c with various aromatic carboxylic acids in presence of phosphorus oxychloride. The intermediates 5a – c , on condensation with various substituted phenacyl bromides afforded a series of title compounds ( 7a – l ). The structures of new compounds 2a – 7l were established on the basis of their elemental analysis, IR, 1 H NMR, 13 C NMR and mass spectral data. All the title compounds were subjected to in vitro antibacterial testing against four pathogenic strains and antifungal screening against three fungi. Preliminary results indicate that some of them exhibited promising activities and they deserve more consideration as potential antimicrobials.
