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Axel Herzog – One of the best experts on this subject based on the ideXlab platform.

  • Synthesen und Strukturen sechsgliedriger Cyclometallaphosphazene von Tellur(IV) und Rhenium(VII) / Syntheses and Structures of Six-Membered Cyclometallaphosphazenes Containing Tellurium(IV) and Rhenium(VII)
    Zeitschrift für Naturforschung B, 1993
    Co-Authors: Iring Leichtweis, Reinhard Hasselbring, W. Herbert, Mathias Noltemeyer, Axel Herzog

    Abstract:

    The reactions of the tridentate ligands (Me₃Si)₂NC(4-RC₆H₄)NPPh,NSiMe₃ [(1): R=H, (2): R=CF₃] with Re₂O₇ yield the six-membered rings , (4): R=CF₃]. The Acyclic Compound Me₃SiNC(4-CF₃C₆H₄)NPPh₂NReO₂OSiMe₃ (5) has been obtained by reaction of 2 with Me₃SiOReO₃₋ 2 reacts quantitatively with TeCl₄ to form the metallacycle . The molecular structures of 4·CH₂Cl₂ and 6 · pyridine · 0.5 toluene have been determined by X-ray diffraction.

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Iring Leichtweis – One of the best experts on this subject based on the ideXlab platform.

  • Synthesen und Strukturen sechsgliedriger Cyclometallaphosphazene von Tellur(IV) und Rhenium(VII) / Syntheses and Structures of Six-Membered Cyclometallaphosphazenes Containing Tellurium(IV) and Rhenium(VII)
    Zeitschrift für Naturforschung B, 1993
    Co-Authors: Iring Leichtweis, Reinhard Hasselbring, W. Herbert, Mathias Noltemeyer, Axel Herzog

    Abstract:

    The reactions of the tridentate ligands (Me₃Si)₂NC(4-RC₆H₄)NPPh,NSiMe₃ [(1): R=H, (2): R=CF₃] with Re₂O₇ yield the six-membered rings , (4): R=CF₃]. The Acyclic Compound Me₃SiNC(4-CF₃C₆H₄)NPPh₂NReO₂OSiMe₃ (5) has been obtained by reaction of 2 with Me₃SiOReO₃₋ 2 reacts quantitatively with TeCl₄ to form the metallacycle . The molecular structures of 4·CH₂Cl₂ and 6 · pyridine · 0.5 toluene have been determined by X-ray diffraction.

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W. Herbert – One of the best experts on this subject based on the ideXlab platform.

  • Synthesen und Strukturen sechsgliedriger Cyclometallaphosphazene von Tellur(IV) und Rhenium(VII) / Syntheses and Structures of Six-Membered Cyclometallaphosphazenes Containing Tellurium(IV) and Rhenium(VII)
    Zeitschrift für Naturforschung B, 1993
    Co-Authors: Iring Leichtweis, Reinhard Hasselbring, W. Herbert, Mathias Noltemeyer, Axel Herzog

    Abstract:

    The reactions of the tridentate ligands (Me₃Si)₂NC(4-RC₆H₄)NPPh,NSiMe₃ [(1): R=H, (2): R=CF₃] with Re₂O₇ yield the six-membered rings , (4): R=CF₃]. The Acyclic Compound Me₃SiNC(4-CF₃C₆H₄)NPPh₂NReO₂OSiMe₃ (5) has been obtained by reaction of 2 with Me₃SiOReO₃₋ 2 reacts quantitatively with TeCl₄ to form the metallacycle . The molecular structures of 4·CH₂Cl₂ and 6 · pyridine · 0.5 toluene have been determined by X-ray diffraction.

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