The Experts below are selected from a list of 291 Experts worldwide ranked by ideXlab platform
M Bochmann - One of the best experts on this subject based on the ideXlab platform.
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Zinc(II) η1- and η2-Toluene Complexes: Structure and Bonding in Zn(C6F5)2·(Toluene) and Zn(C6F4-2-C6F5)2·(Toluene)
Organometallics, 2006Co-Authors: Antonio Guerrero, Eddy Martin, David L. Hughes, Nikolas Kaltsoyannis, M BochmannAbstract:The first structural characterization of Toluene complexes of zinc is reported. The (perfluoroaryl)zinc compounds Zn(C6F5)2·(Toluene) and Zn(C6F4-2-C6F5)2·(Toluene) show Toluene in η2 and η1 coordination modes, respectively. On the other hand, charge distribution calculations, Mulliken overlap population analysis, and bonding energy data suggest that the interactions between the Zn and the Toluene ring are rather similar in both cases.
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Zinc(II) eta(1)- and eta(2)-Toluene complexes: Structure and bonding in Zn(C6F5)(2)center dot(Toluene) and Zn(C6F4-2-C6F5)(2)center dot(Toluene)
ORGANOMETALLICS, 2006Co-Authors: M BochmannAbstract:The first structural characterization of Toluene complexes of zinc is reported. The ( perfluoroaryl) zinc compounds Zn(C6F5)(2)center dot(Toluene) and Zn(C6F4-2-C6F5)(2)center dot(Toluene) show Toluene in eta(2) and eta(1) coordination modes, respectively. On the other hand, charge distribution calculations, Mulliken overlap population analysis, and bonding energy data suggest that the interactions between the Zn and the Toluene ring are rather similar in both cases.
Jerry L Atwood - One of the best experts on this subject based on the ideXlab platform.
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liquid liquid equilibria for Toluene heptane 1 ethyl 3 methylimidazolium triiodide and Toluene heptane 1 butyl 3 methylimidazolium triiodide
Journal of Chemical & Engineering Data, 2000Co-Authors: Murugan S Selvan, Marvin D Mckinley, And Raymond H Dubois, Jerry L AtwoodAbstract:This study focuses on the use of an ionic liquid for extracting an aromatic hydrocarbon from a mixture of an aromatic and an aliphatic hydrocarbon. Liquid−liquid equilibrium data were collected for the Toluene + heptane + 1-ethyl-3-methylimidazolium triiodide system at 45 °C and for the Toluene + heptane + 1-butyl-3-methylimidazolium triiodide system at 35 °C. The nonrandom two-liquid (NRTL) physical thermodynamic model was used to correlate the experimental data. The NRTL model was found to represent the data very well. The selectivity and capacity of the ionic liquids for extracting Toluene from Toluene + heptane solutions were evaluated. The separation factors were found to be above 50 for low Toluene compositions and nearly unity for high Toluene compositions.
Murugan S Selvan - One of the best experts on this subject based on the ideXlab platform.
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liquid liquid equilibria for Toluene heptane 1 ethyl 3 methylimidazolium triiodide and Toluene heptane 1 butyl 3 methylimidazolium triiodide
Journal of Chemical & Engineering Data, 2000Co-Authors: Murugan S Selvan, Marvin D Mckinley, And Raymond H Dubois, Jerry L AtwoodAbstract:This study focuses on the use of an ionic liquid for extracting an aromatic hydrocarbon from a mixture of an aromatic and an aliphatic hydrocarbon. Liquid−liquid equilibrium data were collected for the Toluene + heptane + 1-ethyl-3-methylimidazolium triiodide system at 45 °C and for the Toluene + heptane + 1-butyl-3-methylimidazolium triiodide system at 35 °C. The nonrandom two-liquid (NRTL) physical thermodynamic model was used to correlate the experimental data. The NRTL model was found to represent the data very well. The selectivity and capacity of the ionic liquids for extracting Toluene from Toluene + heptane solutions were evaluated. The separation factors were found to be above 50 for low Toluene compositions and nearly unity for high Toluene compositions.
Eun Ji Park - One of the best experts on this subject based on the ideXlab platform.
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Adsorption and desorption of Toluene on nanoporous TiO_2/SiO_2 prepared by atomic layer deposition (ALD): influence of TiO_2 thin film thickness and humidity
Adsorption, 2013Co-Authors: Eun Ji ParkAbstract:Adsorption and desorption of Toluene on bare and TiO_2-coated silica with a mean pore size of 15 nm under dry and humid conditions were studied using Toluene breakthrough curves and temperature programmed desorption (TPD) of Toluene and CO_2. Two TiO_2/silica samples (either partially or fully covered with TiO_2) were prepared with 50 and 200 cycles of TiO_2 atomic layer deposition (ALD), respectively. The capacity of silica to adsorb Toluene improved significantly with TiO_2-thin film coating under dry conditions. However, Toluene desorption from the surface due to displacement by water was more pronounced for TiO_2-coated samples than bare samples under humid conditions. In TPD experiments, silica with a thinner TiO_2 film (50-ALD cycled) had the highest reactivity for Toluene oxidation to CO_2 both in the absence and presence of water. Toluene adsorption and oxidation reactivity of silica can be controlled by modifying the silica surface with small amount of TiO_2 using ALD.
And Raymond H Dubois - One of the best experts on this subject based on the ideXlab platform.
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liquid liquid equilibria for Toluene heptane 1 ethyl 3 methylimidazolium triiodide and Toluene heptane 1 butyl 3 methylimidazolium triiodide
Journal of Chemical & Engineering Data, 2000Co-Authors: Murugan S Selvan, Marvin D Mckinley, And Raymond H Dubois, Jerry L AtwoodAbstract:This study focuses on the use of an ionic liquid for extracting an aromatic hydrocarbon from a mixture of an aromatic and an aliphatic hydrocarbon. Liquid−liquid equilibrium data were collected for the Toluene + heptane + 1-ethyl-3-methylimidazolium triiodide system at 45 °C and for the Toluene + heptane + 1-butyl-3-methylimidazolium triiodide system at 35 °C. The nonrandom two-liquid (NRTL) physical thermodynamic model was used to correlate the experimental data. The NRTL model was found to represent the data very well. The selectivity and capacity of the ionic liquids for extracting Toluene from Toluene + heptane solutions were evaluated. The separation factors were found to be above 50 for low Toluene compositions and nearly unity for high Toluene compositions.