The Experts below are selected from a list of 3 Experts worldwide ranked by ideXlab platform
Claude Wakselman - One of the best experts on this subject based on the ideXlab platform.
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The Bamberger Reaction in hydrogen fluoride: the use of mild reductive metals for the preparation of fluoroaromatic amines
Journal of Fluorine Chemistry, 1995Co-Authors: Marc Tordeux, Claude WakselmanAbstract:The reduction of nitroaromatic compounds by various metals (tin, lead, bismuth) in liquid hydrogen fluoride under an inert atmosphere leads to fluoroaromatic amines, in accord with the Bamberger Reaction. Generally, a co-solvent such as pentane or methylene chloride is used. Some non-fluorinated arylamines are also formed by a competitive direct reduction of the N-arylhydroxylamine intermediate. Of the mild reductive metals studied, bismuth was the most selective.
Marc Tordeux - One of the best experts on this subject based on the ideXlab platform.
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The Bamberger Reaction in hydrogen fluoride: the use of mild reductive metals for the preparation of fluoroaromatic amines
Journal of Fluorine Chemistry, 1995Co-Authors: Marc Tordeux, Claude WakselmanAbstract:The reduction of nitroaromatic compounds by various metals (tin, lead, bismuth) in liquid hydrogen fluoride under an inert atmosphere leads to fluoroaromatic amines, in accord with the Bamberger Reaction. Generally, a co-solvent such as pentane or methylene chloride is used. Some non-fluorinated arylamines are also formed by a competitive direct reduction of the N-arylhydroxylamine intermediate. Of the mild reductive metals studied, bismuth was the most selective.
