Bandgap Material

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The Experts below are selected from a list of 19170 Experts worldwide ranked by ideXlab platform

Zexing Cao - One of the best experts on this subject based on the ideXlab platform.

Guillaume Cassabois - One of the best experts on this subject based on the ideXlab platform.

  • Hexagonal boron nitride: an indirect Bandgap semiconductor with unique opto-electronic properties
    2017
    Co-Authors: Guillaume Cassabois
    Abstract:

    I will discuss our recent studies showing that the optical response in hBN displays prominent evidence for phonon-assisted optical transitions, with a very unusual phenomenology. By two-photon spectroscopy, we demonstrated that the intrinsic optical properties at the band edge are characteristic of an indirect Bandgap Material. Polarization-resolved experiments with a detection from the sample edge allowed us to show that the phonon symmetries can be traced back in the optical response. I will further highlight the unique properties of this Material where the optical response is tailored by the phonon group velocities in the middle of the Brillouin zone. I will finally present optical characterization results of the promising high-temperature MBE growth of hBN.

  • Hexagonal boron nitride: an indirect Bandgap semiconductor with unique opto-electronic properties
    2017
    Co-Authors: Guillaume Cassabois
    Abstract:

    I will discuss our recent studies showing that the optical response in hBN displays prominent evidence for phonon-assisted optical transitions, with a very unusual phenomenology. By two-photon spectroscopy, we demonstrated that the intrinsic optical properties at the band edge are characteristic of an indirect Bandgap Material. Polarization-resolved experiments with a detection from the sample edge allowed us to show that the phonon symmetries can be traced back in the optical response. I will further highlight the unique properties of this Material where the optical response is tailored by the phonon group velocities in the middle of the Brillouin zone. I will finally present optical characterization results of the promising high-temperature MBE growth of hBN, in collaboration with Nottingham University.

  • Phonon-assisted optical response in hexagonal boron nitride
    2017
    Co-Authors: Guillaume Cassabois
    Abstract:

    I will discuss our recent studies showing that the optical response in hBN displays prominent evidence for phonon-assisted optical transitions. First of all, by two-photon spectroscopy, we have demonstrated that the intrinsic optical properties at the band edge are characteristic of an indirect Bandgap Material. I will further discuss our experimental evidence that transverse optical phonons at the K point of the Brillouin zone assist inter-K valley scattering in hexagonal boron nitride, thanks to the presence of a density of final electronic states coming from extended stacking faults. Finally, I will present our measurements of the vibronic spectrum in a point defect in hBN, displaying a remarkable mapping with the phonon density of states, and in particular a suppression of the phonon-assisted recombination signal at the phonon gap energy. I will discuss our recent studies showing that the optical response in hBN displays prominent evidence for phonon-assisted optical transitions. First of all, by two-photon spectroscopy, we have demonstrated that the intrinsic optical properties at the band edge are characteristic of an indirect Bandgap Material. I will further discuss our experimental evidence that transverse optical phonons at the K point of the Brillouin zone assist inter-K valley scattering in hexagonal boron nitride, thanks to the presence of a density of final electronic states coming from extended stacking faults. Finally, I will present our measurements of the vibronic spectrum in a point defect in hBN, displaying a remarkable mapping with the phonon density of states, and in particular a suppression of the phonon-assisted recombination signal at the phonon gap energy.

  • Indirect excitons and electron-phonon interaction in hexagonal boron nitride
    2016
    Co-Authors: Guillaume Cassabois
    Abstract:

    In this paper, we discuss our recent experiments by two-photon spectroscopy demonstrating that hBN is an indirect Bandgap Material. We will show that the optical properties of hBN are profoundly determined by phonon-assisted transitions involving either virtual or real excitonic states. We will present our measurements of the exciton binding energy by two-photon excitation, leading to the estimation of 6.08 eV for the single-particle Bandgap in hBN. We will also discuss our experimental evidence that transverse optical phonons at the K point of the Brillouin zone assist inter-K valley scattering in hexagonal boron nitride.

  • Indirect excitons and electron-phonon interaction in hexagonal boron nitride
    2016
    Co-Authors: Guillaume Cassabois
    Abstract:

    I will discuss our recent experiments by two-photon spectroscopy demonstrating that hBN is an indirect Bandgap Material. I will show that the optical properties of hBN are profoundly determined by phonon-assisted transitions involving either virtual or real excitonic states. I will present our measurements of the exciton binding energy by two-photon excitation, leading to the estimation of 6.08 eV for the single-particle Bandgap in hBN. I will also discuss our experimental evidence that transverse optical phonons at the K point of the Brillouin zone assist inter-K valley scattering in hexagonal boron nitride.

J S Williams - One of the best experts on this subject based on the ideXlab platform.

R Asomoza - One of the best experts on this subject based on the ideXlab platform.

  • plasma cvd deposited p type silicon oxide wide Bandgap Material for solar cells
    Solar Energy Materials and Solar Cells, 1998
    Co-Authors: Yasuhiro Matsumoto, F Melendez, R Asomoza
    Abstract:

    Abstract The short-circuit current density is an important parameter to improve the conversion efficiency of solar cells. Solar cells with heterojunction structures employing a wide-Bandgap window-layers are nowadays common to achieve greater photogenerated current. Plasma CVD deposited a-SiO x  : H (Hydrogenated amorphous silicon oxide) has been widely used as an insulator and for surface passivation in electronic device manufacturing, however, there is little knowledge about doped Materials. We have prepared a-SiO x  : H films using silane (SiH 4 ) and oxygen (O 2 ) as reactive gases in a capacitively-coupled single-chamber plasma CVD system. Diborane (B 2 H 6 ) was introduced as a doping gas to obtain p-type conduction silicon oxide. In this work we report properties of the prepared Materials at different substrate temperatures, plasma power and doping concentrations. The optical Bandgap increases with oxygen-to-silane-gas-flow ratio, while the electrical conductivity decreases. The optical Bandgap changes easily as a function of gas-source ratio from 1.3 to 2.0 eV. The deposition rate varies from 10 to 22 nm/min, depending mostly on the plasma excitation power. As a first approach, hydrogenated amorphous silicon solar cells have been fabricated using p-type a-SiO x  : H with around 1.85 eV optical Bandgap and conductivity greater than 10 −7  Scm. The measured current–voltage characteristics of the solar cells under the artificial light of 100 mW/cm 2 are V oc =0.84 V, J sc =14.66 mA/cm 2 with a conversion efficiency of 6.95%.

Xinrui Cao - One of the best experts on this subject based on the ideXlab platform.