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  • sodium activity in the heterogeneous phase system na beta al2 o 3 Borate Glass meo me
    Journal of The Electrochemical Society, 2004
    Co-Authors: H. Näfe, S Gollhofer
    Abstract:

    The heterogeneous phase system Na-beta-Al 2 O 3 (NBA)/Borate Glass, NiO, FeO/FeNi that represents a potential sodium reference electrode has been thermodynamically characterized in the temperature interval 400-600°C by potentiometric measurements on the following solid electrolyte galvanic cell: Au, O 2 , CO 2 |Na 2 CO 3 (Au)|NBA(Au)|YSZ|NBA(Au)Borate Glass, NiO, FeO|FeNi|Au. The sodium activity of the system amounts to Iga Na = 2.160 ± 0.59 - 14667.793 ± 448.90 K /T The experimental findings indicate that the Borate Glass not only plays the role of an inert solvent for the remaining phases but reacts itself with Na-beta-Al 2 O 3 , thus adopting a certain sodium oxide content which in equilibrium with the metal and the metal oxide establishes the sodium potential of the system.

  • Sodium Activity in the Heterogeneous Phase System Na ­ beta ­ Al2 O 3 / Borate Glass, MeO/Me
    Journal of The Electrochemical Society, 2004
    Co-Authors: H. Näfe, S Gollhofer
    Abstract:

    The heterogeneous phase system Na-beta-Al 2 O 3 (NBA)/Borate Glass, NiO, FeO/FeNi that represents a potential sodium reference electrode has been thermodynamically characterized in the temperature interval 400-600°C by potentiometric measurements on the following solid electrolyte galvanic cell: Au, O 2 , CO 2 |Na 2 CO 3 (Au)|NBA(Au)|YSZ|NBA(Au)Borate Glass, NiO, FeO|FeNi|Au. The sodium activity of the system amounts to Iga Na = 2.160 ± 0.59 - 14667.793 ± 448.90 K /T The experimental findings indicate that the Borate Glass not only plays the role of an inert solvent for the remaining phases but reacts itself with Na-beta-Al 2 O 3 , thus adopting a certain sodium oxide content which in equilibrium with the metal and the metal oxide establishes the sodium potential of the system.