Counter Electrode

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Gentian Yue - One of the best experts on this subject based on the ideXlab platform.

  • functionalized graphene poly 3 4 ethylenedioxythiophene polystyrenesulfonate as Counter Electrode catalyst for dye sensitized solar cells
    Energy, 2013
    Co-Authors: Miaoliang Huang, Zhang Lan, Jianming Lin, Gentian Yue, Yaoming Xiao
    Abstract:

    A (grapheme/poly(3,4-ethylenedioxythiophene):polystyrenesulfonate) graphene/PEDOT:PSS composite film was Electrodeposited on fluorine-doped tin oxide conductive substrate by one-step electrochemical polymerization method. The low-cost and platinum-free film was used as Counter Electrode in (dye-sensitized solar cell) DSSC. The cyclic voltammetry, electrochemical impedance spectroscopy and Tafel measurements indicate that the graphene/PEDOT:PSS composite film has low charge-transfer resistance on the electrolyte/Electrode interface and high catalytic activity for the reduction of triiodide to iodide and. As a result, the DSSC based on the graphene/PEDOT:PSS Counter Electrode showed high power conversion efficiency of 7.86% under a simulated sunlight illumination of 100 mW cm−2 (AM 1.5), which is comparable with the performance of the DSSC based on Pt Counter Electrode (7.31%).

  • a Counter Electrode of multi wall carbon nanotubes decorated with tungsten sulfide used in dye sensitized solar cells
    Carbon, 2013
    Co-Authors: Miaoliang Huang, Jianming Lin, Gentian Yue, Yaoming Xiao, Jengyu Lin, Shengyen Tai, Zhang Lan
    Abstract:

    Abstract Multi-wall carbon nanotubes decorated with tungsten sulfide (MWCNTs-WS2) were synthesized by using a hydrothermal method, and used as a low-cost platinum-free Counter Electrode for dye-sensitized solar cell (DSSC). Cyclic voltammetry and electrochemical impedance spectroscopy characterizations indicate that the Counter Electrode has a high catalytic activity for the reduction of triiodide to iodide and a low charge transfer resistance at the electrolyte–Electrode interface. A DSSC based on this Counter Electrode achieves a high power conversion efficiency of 6.41% under a simulated solar illumination of 100 mW cm−2 (AM 1.5). This efficiency is comparable to 6.56% for a DSSC with Pt Counter Electrode.

  • A dye-sensitized solar cell based on PEDOT:PSS Counter Electrode
    Chinese Science Bulletin, 2013
    Co-Authors: Gentian Yue, Miaoliang Huang, Jianming Lin, Leqing Fan, Yaoming Xiao, Ying Yao
    Abstract:

    A Counter Electrode for dye-sensitized solar cell (DSSC) was prepared by coating poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) with high transparency and adhesion on a conducting FTO glass at low temperature. The surface morphology, conductivity, sheet resistance, redox properties and photoelectric properties of the PEDOT:PSS/carbon Electrodes were observed using scanning electron microscopy, a four-probe tester and a CHI660D electrochemical measurement system. The experimental results showed that DSSCs had the best photoelectric properties for PEDOT:PSS/carbon Counter Electrodes annealed at 80°C under vacuum conditions. The overall energy conversion efficiency of the DSSC with PEDOT:PSS/carbon Counter Electrode and barrier layer reached 7.61% under irradiation from a simulated solar light with intensity of 100 mW/cm2 (AM 1.5). The excellent photoelectric properties, simple preparation procedure and low cost allow the PEDOT:PSS/carbon Electrode to be a credible alternative Electrode for use in DSSCs.

  • high performance platinum free Counter Electrode of molybdenum sulfide carbon used in dye sensitized solar cells
    Journal of Materials Chemistry, 2013
    Co-Authors: Miaoliang Huang, Jianming Lin, Gentian Yue, Yaoming Xiao, Jengyu Lin
    Abstract:

    A high porous molybdenum sulfide–carbon (MoS2–C) hybrid film was prepared by using an in situ hydrothermal route. The MoS2–C hybrid film served as a low-cost and high efficient platinum-free Counter Electrode for a dye-sensitized solar cell (DSSC). The cyclic voltammetry, electrochemical impedance spectroscopy and Tafel curve analysis indicate that the MoS2–C Electrode possesses low charge transfer resistance on the electrolyte–Electrode interface, high electrocatalytic activity and fast reaction kinetics for the reduction of triiodide to iodide at the Counter Electrode, which is due to large specific surface area and special structure and compositions of MoS2–C film. A DSSC with the novel MoS2–C Counter Electrode achieve a high power conversion efficiency of 7.69% under standard light illumination, which exceeds that of the DSSC with a Pt Counter Electrode (6.74%).

Zhang Lan - One of the best experts on this subject based on the ideXlab platform.

  • a microporous platinum Counter Electrode used in dye sensitized solar cells
    Nano Energy, 2013
    Co-Authors: Ziying Tang, Min Zheng, Jinhao Huo, Zhang Lan
    Abstract:

    Abstract A microporous platinum film is prepared by a facile rapid thermal decomposition method. Scanning electronic microscope observes a large amount of interconnected and uniform micropores with a pore diameter of 100–150 nm on the microporous platinum Electrode. The cyclic voltammetry measurements indicate that the microporous platinum Electrode has higher catalytic activity and smaller resistance than the conventional platinum Electrode does. By using the microporous platinum film as Counter Electrode, a dye-sensitized solar cell (DSSC) is fabricated, the DSSC achieves a high light-to-electric energy conversion efficiency of 8.15% under a simulated solar light irradiation with a intensity of 100 mW cm−2. The efficiency is increased by 21.28% compared to that of the DSSC with conventional platinum Counter Electrode.

  • functionalized graphene poly 3 4 ethylenedioxythiophene polystyrenesulfonate as Counter Electrode catalyst for dye sensitized solar cells
    Energy, 2013
    Co-Authors: Miaoliang Huang, Zhang Lan, Jianming Lin, Gentian Yue, Yaoming Xiao
    Abstract:

    A (grapheme/poly(3,4-ethylenedioxythiophene):polystyrenesulfonate) graphene/PEDOT:PSS composite film was Electrodeposited on fluorine-doped tin oxide conductive substrate by one-step electrochemical polymerization method. The low-cost and platinum-free film was used as Counter Electrode in (dye-sensitized solar cell) DSSC. The cyclic voltammetry, electrochemical impedance spectroscopy and Tafel measurements indicate that the graphene/PEDOT:PSS composite film has low charge-transfer resistance on the electrolyte/Electrode interface and high catalytic activity for the reduction of triiodide to iodide and. As a result, the DSSC based on the graphene/PEDOT:PSS Counter Electrode showed high power conversion efficiency of 7.86% under a simulated sunlight illumination of 100 mW cm−2 (AM 1.5), which is comparable with the performance of the DSSC based on Pt Counter Electrode (7.31%).

  • a Counter Electrode of multi wall carbon nanotubes decorated with tungsten sulfide used in dye sensitized solar cells
    Carbon, 2013
    Co-Authors: Miaoliang Huang, Jianming Lin, Gentian Yue, Yaoming Xiao, Jengyu Lin, Shengyen Tai, Zhang Lan
    Abstract:

    Abstract Multi-wall carbon nanotubes decorated with tungsten sulfide (MWCNTs-WS2) were synthesized by using a hydrothermal method, and used as a low-cost platinum-free Counter Electrode for dye-sensitized solar cell (DSSC). Cyclic voltammetry and electrochemical impedance spectroscopy characterizations indicate that the Counter Electrode has a high catalytic activity for the reduction of triiodide to iodide and a low charge transfer resistance at the electrolyte–Electrode interface. A DSSC based on this Counter Electrode achieves a high power conversion efficiency of 6.41% under a simulated solar illumination of 100 mW cm−2 (AM 1.5). This efficiency is comparable to 6.56% for a DSSC with Pt Counter Electrode.

  • Application of microporous polyaniline Counter Electrode for dye-sensitized solar cells
    Electrochemistry Communications, 2008
    Co-Authors: Qunwei Tang, Zhang Lan, Jianming Lin, Leqing Fan
    Abstract:

    Abstract An inexpensive microporous polyaniline (PANI) is used as a substitute for platinum to construct the Counter Electrode in dye-sensitized solar cells (DSSCs). The PANI Counter Electrode with microporosity and a size diameter of about 100 nm possesses lower charge-transfer resistance and higher electrocatalytic activity for the I 3 - / I - redox reaction than Pt Electrode does. The overall energy conversion efficiency of the DSSC with PANI Counter Electrode reaches 7.15%, which is higher than that of the DSSC with Pt Counter Electrode. The excellent photoelectric properties, simple preparation procedure and inexpensive cost allow PANI Electrode to be a credible alternative for DSSCs.

  • high performance polypyrrole nanoparticles Counter Electrode for dye sensitized solar cells
    Journal of Power Sources, 2008
    Co-Authors: Leqing Fan, Zhang Lan, Jianming Lin, Sanchun Hao
    Abstract:

    Abstract Polypyrrole (PPy) nanoparticle was synthesized and coated on a conducting FTO glass to construct PPy Counter Electrode used in dye-sensitized solar cell (DSSC). Scanning electron microscope images show that PPy with porous and particle diameter in 40–60 nm is covered on the FTO glass uniformly and tightly. Cyclic voltammograms of I 2 /I − system measurement reveals that the PPy Electrode has smaller charge-transfer resistance and higher electrocatalytic activity for the I 2 /I − redox reaction than that Pt Electrode does. Overall energy conversion efficiency of the DSSC with the PPy Counter Electrode reaches 7.66%, which is higher (11%) than that of the DSSC with Pt Counter Electrode. The excellent photoelectric properties, simple preparation procedure and inexpensive cost allow the PPy Electrode to be a credible alternative used in DSSCs.

Qiquan Qiao - One of the best experts on this subject based on the ideXlab platform.

  • Activated graphene nanoplatelets as a Counter Electrode for dye-sensitized solar cells
    Journal of Applied Physics, 2016
    Co-Authors: Jiawei Gong, Zhengping Zhou, K. Sumathy, Huojun Yang, Qiquan Qiao
    Abstract:

    Activated graphene nanoplatelets (aGNPs) prepared by a hydrothermal method using KOH as activating agent were used as Counter Electrode for high efficiency dye-sensitized solar cells (DSSCs). After the KOH activation, the scanning electron microscopy image shows that aGNPs demonstrate a more curled, rough, and porous morphology which could contain both micro- and mesopores. The KOH activation changed the stacked layers of GNPs to a more crumpled and curved morphology. The microstructure of large pores significantly increased the Electrode surface area and roughness, leading to the high electrocatalytic activity for triiodide reduction at the Counter Electrode. The DSSCs fabricated using aGNP as Counter Electrodes were tested under standard AM 1.5 illumination with an intensity of 91.5 mW/cm2. The device achieved an overall power conversion efficiency of 7.7%, which is comparable to the conventional platinum Counter Electrode (8%). Therefore, the low cost and high performance aGNP based Counter Electrode i...

  • electrospun carbon nanofibers with surface attached platinum nanoparticles as cost effective and efficient Counter Electrode for dye sensitized solar cells
    Nano Energy, 2015
    Co-Authors: Alex Aboagye, Qiquan Qiao, Hytham Elbohy, Ajit D Kelkar, Xuefeng Qian, Lifeng Zhang
    Abstract:

    Abstract Dye-sensitized solar cells (DSCs) have attracted incredible attention in recent years as relatively inexpensive alternative to silicon solar cells. Conventionally, a transparent fluoride-doped tin oxide (FTO) conductive glass with a thin layer coating of platinum (Pt) is used as Counter Electrode in DSCs. The widespread use of Pt as Counter Electrode in DSCs is due to its catalytic capability for I 3 - reduction in electrolyte. However, Pt is costly and can be affected by the corrosive nature of I - /I 3 - redox couple, which makes it a less desirable candidate for use in industrial scale manufacturing. In this study, carbon nanofibers with surface-attached Pt nanoparticles were prepared by stabilization and carbonization of electrospun polyacrylonitrile (PAN) nanofibers and subsequent controllable Pt nanoparticle growth on the obtained carbon nanofiber surface through redox reaction. The hierarchical carbon nanofibers with surface-attached Pt nanoparticles (ECNFs-PtNPs) were then employed as cost-effective Counter Electrode in DSCs. The effects of size, morphology, and loading of Pt nanoparticles on performance of DSCs were investigated. Compared to conventional Counter Electrode, the Counter Electrode that was made of ECNFs-PtNPs exhibited larger open circuit voltage (V oc ). The DSCs that were made with ECNFs-PtNPs Counter Electrode demonstrated excellent solar energy conversion efficiencies in the range of 7% to 8%.

  • Transparent platinum Counter Electrode for efficient semi-transparent dye-sensitized solar cells
    Thin Solid Films, 2014
    Co-Authors: Anastasiia Iefanova, Qiquan Qiao, Umesh Gautam, Prashant Poudel, Daren Davoux, Jeevan Nepal, Venkataiah Mallam, Brian A. Logue, Farrokh Baroughi
    Abstract:

    Abstract A method for fabrication of highly transparent platinum Counter Electrodes (CEs) has been developed based on spray coating of Pt nanoparticles (NPs) on hot substrates. This method leads to 86% reduction in Pt consumption reducing the Pt cost per peak watt of Counter Electrode from $0.79/Wp down to $0.11/Wp compared to the conventional Pt Counter Electrodes made by sputter deposition. The simplicity and low cost of this method provide a basis for an up-scalable fabrication process. The Pt NP layer is over 88% transparent, leading to overall transparency of 80% when incorporated with indium tin oxide/glass substrates for functional Counter Electrodes. This Counter Electrode exhibits a large surface area and high catalytic activity, comparable to that of the conventional opaque CEs. Semi-transparent dye-sensitized solar cells fabricated based on this Counter Electrode showed 6.17% power conversion efficiency.

  • Improved performance of dye solar cells using nanocarbon as support for platinum nanoparticles in Counter Electrode
    Nano Energy, 2014
    Co-Authors: Prashant Poudel, Amit Thapa, Hytham Elbohy, Qiquan Qiao
    Abstract:

    Abstract Carbon nanoparticles (CNPs) were used to support platinum nanoparticles as Counter Electrodes in dye-sensitized solar cells (DSCs). Carbon nanoparticles provided larger effective surface area and better exposure of Pt nanoparticles resulting in very efficient electrocatalytic performance as Counter Electrode. DSCs fabricated using such Counter Electrode showed enhanced efficiency owing to lower series resistance and higher fill factor as a result of reduced charge transfer resistance. The overall power conversion efficiency of the DSC devices using these CNP/Pt Counter Electrodes reached 8.12% as compared to 7.49% for reference platinum Counter Electrode DSCs under 1 sun illumination.

  • Low cost platinum Counter Electrode for dye-sensitized solar cells
    2013 IEEE 39th Photovoltaic Specialists Conference (PVSC), 2013
    Co-Authors: Anastasiia Iefanova, Qiquan Qiao, Umesh Gautam, Prashant Poudel, Daren Davoux, Jeevan Nepal, Venkataiah Mallam, Brian A. Logue, Farrokh Baroughi
    Abstract:

    A platinum Counter-Electrode (CE) was fabricated using spray-deposition method to provide efficient dye-sensitized solar cells (DSSCs). This method uses over 86% less Pt compared to conventional Pt Counter-Electrode prepared by highly efficient sputter deposition method. The cost of this new Counter-Electrode is estimated to be only 0.11$/Wp. Moreover, this Counter-Electrode exhibits a high transparency, over 80% in visible and near infrared, along with high catalytic activity, comparable with that of the conventional Pt Counter-Electrode. Scanning electron microscope (SEM) images show Pt nanoparticles varying in size from 5 nm to 70 nm distributed on transparent conducting oxide (TCO)/glass substrate. DSSCs based on this Counter-Electrode showed 6.17% power conversion efficiency, comparable to 6.46% efficiency of the corresponding reference DSSC with sputtered Pt Counter-Electrode.

Jianming Lin - One of the best experts on this subject based on the ideXlab platform.

  • functionalized graphene poly 3 4 ethylenedioxythiophene polystyrenesulfonate as Counter Electrode catalyst for dye sensitized solar cells
    Energy, 2013
    Co-Authors: Miaoliang Huang, Zhang Lan, Jianming Lin, Gentian Yue, Yaoming Xiao
    Abstract:

    A (grapheme/poly(3,4-ethylenedioxythiophene):polystyrenesulfonate) graphene/PEDOT:PSS composite film was Electrodeposited on fluorine-doped tin oxide conductive substrate by one-step electrochemical polymerization method. The low-cost and platinum-free film was used as Counter Electrode in (dye-sensitized solar cell) DSSC. The cyclic voltammetry, electrochemical impedance spectroscopy and Tafel measurements indicate that the graphene/PEDOT:PSS composite film has low charge-transfer resistance on the electrolyte/Electrode interface and high catalytic activity for the reduction of triiodide to iodide and. As a result, the DSSC based on the graphene/PEDOT:PSS Counter Electrode showed high power conversion efficiency of 7.86% under a simulated sunlight illumination of 100 mW cm−2 (AM 1.5), which is comparable with the performance of the DSSC based on Pt Counter Electrode (7.31%).

  • a Counter Electrode of multi wall carbon nanotubes decorated with tungsten sulfide used in dye sensitized solar cells
    Carbon, 2013
    Co-Authors: Miaoliang Huang, Jianming Lin, Gentian Yue, Yaoming Xiao, Jengyu Lin, Shengyen Tai, Zhang Lan
    Abstract:

    Abstract Multi-wall carbon nanotubes decorated with tungsten sulfide (MWCNTs-WS2) were synthesized by using a hydrothermal method, and used as a low-cost platinum-free Counter Electrode for dye-sensitized solar cell (DSSC). Cyclic voltammetry and electrochemical impedance spectroscopy characterizations indicate that the Counter Electrode has a high catalytic activity for the reduction of triiodide to iodide and a low charge transfer resistance at the electrolyte–Electrode interface. A DSSC based on this Counter Electrode achieves a high power conversion efficiency of 6.41% under a simulated solar illumination of 100 mW cm−2 (AM 1.5). This efficiency is comparable to 6.56% for a DSSC with Pt Counter Electrode.

  • A dye-sensitized solar cell based on PEDOT:PSS Counter Electrode
    Chinese Science Bulletin, 2013
    Co-Authors: Gentian Yue, Miaoliang Huang, Jianming Lin, Leqing Fan, Yaoming Xiao, Ying Yao
    Abstract:

    A Counter Electrode for dye-sensitized solar cell (DSSC) was prepared by coating poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) with high transparency and adhesion on a conducting FTO glass at low temperature. The surface morphology, conductivity, sheet resistance, redox properties and photoelectric properties of the PEDOT:PSS/carbon Electrodes were observed using scanning electron microscopy, a four-probe tester and a CHI660D electrochemical measurement system. The experimental results showed that DSSCs had the best photoelectric properties for PEDOT:PSS/carbon Counter Electrodes annealed at 80°C under vacuum conditions. The overall energy conversion efficiency of the DSSC with PEDOT:PSS/carbon Counter Electrode and barrier layer reached 7.61% under irradiation from a simulated solar light with intensity of 100 mW/cm2 (AM 1.5). The excellent photoelectric properties, simple preparation procedure and low cost allow the PEDOT:PSS/carbon Electrode to be a credible alternative Electrode for use in DSSCs.

  • high performance platinum free Counter Electrode of molybdenum sulfide carbon used in dye sensitized solar cells
    Journal of Materials Chemistry, 2013
    Co-Authors: Miaoliang Huang, Jianming Lin, Gentian Yue, Yaoming Xiao, Jengyu Lin
    Abstract:

    A high porous molybdenum sulfide–carbon (MoS2–C) hybrid film was prepared by using an in situ hydrothermal route. The MoS2–C hybrid film served as a low-cost and high efficient platinum-free Counter Electrode for a dye-sensitized solar cell (DSSC). The cyclic voltammetry, electrochemical impedance spectroscopy and Tafel curve analysis indicate that the MoS2–C Electrode possesses low charge transfer resistance on the electrolyte–Electrode interface, high electrocatalytic activity and fast reaction kinetics for the reduction of triiodide to iodide at the Counter Electrode, which is due to large specific surface area and special structure and compositions of MoS2–C film. A DSSC with the novel MoS2–C Counter Electrode achieve a high power conversion efficiency of 7.69% under standard light illumination, which exceeds that of the DSSC with a Pt Counter Electrode (6.74%).

  • Application of microporous polyaniline Counter Electrode for dye-sensitized solar cells
    Electrochemistry Communications, 2008
    Co-Authors: Qunwei Tang, Zhang Lan, Jianming Lin, Leqing Fan
    Abstract:

    Abstract An inexpensive microporous polyaniline (PANI) is used as a substitute for platinum to construct the Counter Electrode in dye-sensitized solar cells (DSSCs). The PANI Counter Electrode with microporosity and a size diameter of about 100 nm possesses lower charge-transfer resistance and higher electrocatalytic activity for the I 3 - / I - redox reaction than Pt Electrode does. The overall energy conversion efficiency of the DSSC with PANI Counter Electrode reaches 7.15%, which is higher than that of the DSSC with Pt Counter Electrode. The excellent photoelectric properties, simple preparation procedure and inexpensive cost allow PANI Electrode to be a credible alternative for DSSCs.

Yaoming Xiao - One of the best experts on this subject based on the ideXlab platform.

  • functionalized graphene poly 3 4 ethylenedioxythiophene polystyrenesulfonate as Counter Electrode catalyst for dye sensitized solar cells
    Energy, 2013
    Co-Authors: Miaoliang Huang, Zhang Lan, Jianming Lin, Gentian Yue, Yaoming Xiao
    Abstract:

    A (grapheme/poly(3,4-ethylenedioxythiophene):polystyrenesulfonate) graphene/PEDOT:PSS composite film was Electrodeposited on fluorine-doped tin oxide conductive substrate by one-step electrochemical polymerization method. The low-cost and platinum-free film was used as Counter Electrode in (dye-sensitized solar cell) DSSC. The cyclic voltammetry, electrochemical impedance spectroscopy and Tafel measurements indicate that the graphene/PEDOT:PSS composite film has low charge-transfer resistance on the electrolyte/Electrode interface and high catalytic activity for the reduction of triiodide to iodide and. As a result, the DSSC based on the graphene/PEDOT:PSS Counter Electrode showed high power conversion efficiency of 7.86% under a simulated sunlight illumination of 100 mW cm−2 (AM 1.5), which is comparable with the performance of the DSSC based on Pt Counter Electrode (7.31%).

  • a Counter Electrode of multi wall carbon nanotubes decorated with tungsten sulfide used in dye sensitized solar cells
    Carbon, 2013
    Co-Authors: Miaoliang Huang, Jianming Lin, Gentian Yue, Yaoming Xiao, Jengyu Lin, Shengyen Tai, Zhang Lan
    Abstract:

    Abstract Multi-wall carbon nanotubes decorated with tungsten sulfide (MWCNTs-WS2) were synthesized by using a hydrothermal method, and used as a low-cost platinum-free Counter Electrode for dye-sensitized solar cell (DSSC). Cyclic voltammetry and electrochemical impedance spectroscopy characterizations indicate that the Counter Electrode has a high catalytic activity for the reduction of triiodide to iodide and a low charge transfer resistance at the electrolyte–Electrode interface. A DSSC based on this Counter Electrode achieves a high power conversion efficiency of 6.41% under a simulated solar illumination of 100 mW cm−2 (AM 1.5). This efficiency is comparable to 6.56% for a DSSC with Pt Counter Electrode.

  • A dye-sensitized solar cell based on PEDOT:PSS Counter Electrode
    Chinese Science Bulletin, 2013
    Co-Authors: Gentian Yue, Miaoliang Huang, Jianming Lin, Leqing Fan, Yaoming Xiao, Ying Yao
    Abstract:

    A Counter Electrode for dye-sensitized solar cell (DSSC) was prepared by coating poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) with high transparency and adhesion on a conducting FTO glass at low temperature. The surface morphology, conductivity, sheet resistance, redox properties and photoelectric properties of the PEDOT:PSS/carbon Electrodes were observed using scanning electron microscopy, a four-probe tester and a CHI660D electrochemical measurement system. The experimental results showed that DSSCs had the best photoelectric properties for PEDOT:PSS/carbon Counter Electrodes annealed at 80°C under vacuum conditions. The overall energy conversion efficiency of the DSSC with PEDOT:PSS/carbon Counter Electrode and barrier layer reached 7.61% under irradiation from a simulated solar light with intensity of 100 mW/cm2 (AM 1.5). The excellent photoelectric properties, simple preparation procedure and low cost allow the PEDOT:PSS/carbon Electrode to be a credible alternative Electrode for use in DSSCs.

  • high performance platinum free Counter Electrode of molybdenum sulfide carbon used in dye sensitized solar cells
    Journal of Materials Chemistry, 2013
    Co-Authors: Miaoliang Huang, Jianming Lin, Gentian Yue, Yaoming Xiao, Jengyu Lin
    Abstract:

    A high porous molybdenum sulfide–carbon (MoS2–C) hybrid film was prepared by using an in situ hydrothermal route. The MoS2–C hybrid film served as a low-cost and high efficient platinum-free Counter Electrode for a dye-sensitized solar cell (DSSC). The cyclic voltammetry, electrochemical impedance spectroscopy and Tafel curve analysis indicate that the MoS2–C Electrode possesses low charge transfer resistance on the electrolyte–Electrode interface, high electrocatalytic activity and fast reaction kinetics for the reduction of triiodide to iodide at the Counter Electrode, which is due to large specific surface area and special structure and compositions of MoS2–C film. A DSSC with the novel MoS2–C Counter Electrode achieve a high power conversion efficiency of 7.69% under standard light illumination, which exceeds that of the DSSC with a Pt Counter Electrode (6.74%).