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Zhongping Chen - One of the best experts on this subject based on the ideXlab platform.

Qiang Wang - One of the best experts on this subject based on the ideXlab platform.

Jun Zhang - One of the best experts on this subject based on the ideXlab platform.

Haruyuki Inui - One of the best experts on this subject based on the ideXlab platform.

  • Structural
    2015
    Co-Authors: Haruyuki Inui, Akihiro Fujii, Katsushi Tanaka, Hiroki Sakamoto, Acta Crystallographica Section B, Akihiro A Fujii, Katsushi Tanaka B Hiroki, Kazuo Ishizukac
    Abstract:

    New electron Diffraction Method to identify the chirality of enantiomorphic crystal

  • Enantiomorph identification of crystals belonging to the point groups of 622 and 6 by convergent-beam electron Diffraction Method
    Intermetallics, 2007
    Co-Authors: Akihiro Fujii, Katsushi Tanaka, Hiroki Sakamoto, Satoshi Fujio, Haruyuki Inui
    Abstract:

    Abstract A CBED Method proposed by the present authors for chiral identification of enantiomorphic crystals has been successfully applied to crystals with the point groups of 622 and 6. The intensity asymmetry of ZOLZ and/or FOLZ reflections of the Bijvoet pairs is utilized for enantiomorph identification and such intensity asymmetry is noted regardless of beam convergence angle but the extent to which the asymmetry is noted depends on crystal thickness and accelerating voltage. The crystal thickness should be smaller than the extinction distance of relevant reflections that constitute ‘umweganregung’ in multiple scattering, which is responsible for the intensity asymmetry. As a result, the maximum crystal thickness, below which the asymmetric intensity distribution of Bijvoet reflections is evident, increases as the accelerating voltage is increased. When the crystal thickness is small, however, the intensity asymmetry is more pronounced as the accelerating voltage is decreased due to the increased propensity of multiple scattering.

  • New electron Diffraction Method to identify the chirality of enantiomorphic crystals
    Acta Crystallographica Section B Structural Science, 2003
    Co-Authors: Haruyuki Inui, Akihiro Fujii, Katsushi Tanaka, Hiroki Sakamoto, Kazuo Ishizuka
    Abstract:

    A new CBED (convergent-beam electron Diffraction) Method is proposed for the identification of the chirality of enantiomorphic crystals, in which asymmetry in the intensity of the reflections of Bijvoet pairs in an experimental symmetrical zone-axis CBED pattern is compared with that of a computer-simulated CBED pattern. The intensity difference for reflections of these Bijvoet pairs results from multiple scattering (dynamical nature of electron Diffraction) among relevant Bijvoet pairs of reflections, each pair of which has identical amplitude and different phase angles. Therefore, the crystal thickness where chiral identification is made with the present Method is limited by the extinction distance of Bijvoet pairs of reflections relevant to multiple scattering to produce the intensity asymmetry, which is usually of the order of a few tens of nanometers. With the present Method, a single CBED pattern is sufficient and chiral identification can be made for all the possible enantiomorphic crystals that are allowed to exist in crystallography.

Lingfeng Yu - One of the best experts on this subject based on the ideXlab platform.