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Mizuguchi Jin - One of the best experts on this subject based on the ideXlab platform.
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Crystal Structure of a Hexa-Nuclear Al-Complex with Ligands of 3,5-Di-t-butylsalicylate Ions
日本分析化学会, 2009Co-Authors: Kamei Yuya, Mizuguchi JinAbstract:An Al-complex with 3,5-di-t-butylsalicylate ions as ligands (commercial name, E-88 from Orient Chemical Industries, LTD) is a charge-control agent (CCA) used for toners in Electrophotography. The title compound is found to crystallize in a monoclinic system, as characterized by the following crystallographic parameters: Cc, a = 19.3525(4), b = 35.4460(4), c = 27.9608(7)Å, β = 110.1240(10)˚, Z = 4, V = 18009.3(6)Å~{3}. The structure was solved by direct methods and refined by full-matrix least squares on F^{2} to final values of R1 = 0.1589 and wR2 = 0.4128
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Benzyltributylammonium 7-hydroxynaphthalene-1-sulfonate
International Union of Crystallography, 2009Co-Authors: Sato Yohei, Uta Kazuya, Mizuguchi JinAbstract:The title compound, C19H34N+･C10H7O4S-, is a charge-control agent used for toners in Electrophotography. The anions form one-dimensional chains by O—H･･･O hydrogen bonds in a zigzag fashion along the c axis between the OH group of one anion and the sulfonate O atom of a neighboring anion. One of the n-butyl chains of the cation is disordered over two sites in a 0.77:0.23 ratio
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Benzyltributylammonium 4,6-dihydroxynaphthalene-2-sulfonate
International Union of Crystallography, 2009Co-Authors: Uta Kazuya, Mizuguchi JinAbstract:The title molecular salt, C19H34N+･C10H7O5S-, is a chargecontrol agent used for toners in Electrophotography with a high melting point of 508 K. In the crystal structure, the anions form inversion dimers, linked by pairs of O—H･･･O hydrogen bonds. Further O—H･･･O links between dimers generate anionic sheets propagating in (010). One of the n-butyl chains of the cation is disordered over two sets of sites in a 0.53:0.47 ratio
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Benzyltributylammonium 6,7-dihydroxynaphthalene-2-sulfonate
International Union of Crystallography, 2009Co-Authors: Uta Kazuya, Mizuguchi JinAbstract:The title molecular salt, C19H34N+･C10H7O5S-, is a chargecontrol agent used for toners in Electrophotography. There are two formula units in the asymmetric unit. Both anions form inversion dimers connected by pairs of O—H･･･O hydrogen bonds between the –OH group of one anion and a sulfonic O atom of the neighboring one. The two dimers A and B are characterized by a step between the least-squares planes of the naphthalene atoms of 0.85 and 2.30 A ˚ . Further O—H･･･O bonds link the dimers into a two-dimensional network propagating in (110) such that dimer A is hydrogen-bonded to four B units and vice versa. One of the tert-butyl chains in one of the cations is disordered over two sets of sites in a 0.56:0.44 ratio
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Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O':O'}-sodium(I)chromium(III)]
International Union of Crystallography, 2008Co-Authors: Ito Shinpei, Sato Yohei, Mizuguchi JinAbstract:The title compound, [CrNa(C16H9ClN2O2)2(C3H6O)2]n, is an azo-CrIII complex polymer that is used as a charge-control agent in Electrophotography. The monomeric unit is composed of octahedral CrIII and NaI units, and is characterized by twofold rotation symmetry. The CrIII atom is chelated by two N and four O atoms from two [(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The ligand anion exists in the cis form. The NaI atom is coordinated by two phenoxy O atoms from a neighboring CrIII unit, two naphthoxy O atoms from another neighboring CrIII unit and two O atoms from acetone molecules. The dinuclear complex forms a one-dimensional polymer running along the c axis
Sato Yohei - One of the best experts on this subject based on the ideXlab platform.
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Benzyltributylammonium 7-hydroxynaphthalene-1-sulfonate
International Union of Crystallography, 2009Co-Authors: Sato Yohei, Uta Kazuya, Mizuguchi JinAbstract:The title compound, C19H34N+･C10H7O4S-, is a charge-control agent used for toners in Electrophotography. The anions form one-dimensional chains by O—H･･･O hydrogen bonds in a zigzag fashion along the c axis between the OH group of one anion and the sulfonate O atom of a neighboring anion. One of the n-butyl chains of the cation is disordered over two sites in a 0.77:0.23 ratio
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Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O':O'}-sodium(I)chromium(III)]
International Union of Crystallography, 2008Co-Authors: Ito Shinpei, Sato Yohei, Mizuguchi JinAbstract:The title compound, [CrNa(C16H9ClN2O2)2(C3H6O)2]n, is an azo-CrIII complex polymer that is used as a charge-control agent in Electrophotography. The monomeric unit is composed of octahedral CrIII and NaI units, and is characterized by twofold rotation symmetry. The CrIII atom is chelated by two N and four O atoms from two [(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The ligand anion exists in the cis form. The NaI atom is coordinated by two phenoxy O atoms from a neighboring CrIII unit, two naphthoxy O atoms from another neighboring CrIII unit and two O atoms from acetone molecules. The dinuclear complex forms a one-dimensional polymer running along the c axis
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Diacetonitriletetrakis{μ2-3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}tetraaquadiiron(III)disodium(I) dihydrate
International Union of Crystallography, 2008Co-Authors: Sato Yohei, Uta Kazuya, Jin MizuguchiAbstract:The title compound, [Fe2Na2(C23H14ClN3O3)4(C2H3N)2(H2O)4]·2H2O, is a hydrated Fe–azo complex dimer that is used as a charge-control agent in Electrophotography. The molecule is a centrosymmetric dimer with two octahedral FeIII units linked by two bridging five-coordinate NaI cations. Each FeIII atom is chelated by the N and two O atoms from two 3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The Na+ cation is coordinated by a carbonyl O atom from the two ligands of each octahedral FeIII unit, two water molecules and the N atom of an acetonitrile molecule. Two solvent water molecules complete the structure. In the crystal structure, the dimeric molecules are bridged by a pair of discrete intermolecular O—H...O hydrogen bonds, one of which involves a sodium-bound water molecule and a hydrate water, and the other a 5-chlorophenolate O atom and a water molecule to form an extended chain along b
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Diacetonitriletetrakis{μ2-3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}tetraaquadiiron(III)disodium(I) dihydrate
International Union of Crystallography, 2008Co-Authors: Sato Yohei, Uta Kazuya, Mizuguchi JinAbstract:The title compound, [Fe2Na2(C23H14ClN3O3)4(C2H3N)2(H2O)4]·2H2O, is a hydrated Fe-azo complex dimer that is used as a charge-control agent in Electrophotography. The molecule is a centrosymmetric dimer with two octahedral FeIII units linked by two bridging five-coordinate NaI cations. Each FeIII atom is chelated by the N and two O atoms from two 3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The Na+ cation is coordinated by a carbonyl O atom from the two ligands of each octahedral FeIII unit, two water molecules and the N atom of an acetonitrile molecule. Two solvent water molecules complete the structure. In the crystal structure, the dimeric molecules are bridged by a pair of discrete intermolecular O-HO hydrogen bonds, one of which involves a sodium-bound water molecule and a hydrate water, and the other a 5-chlorophenolate O atom and a water molecule to form an extended chain along b
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Benzyltributylammonium 4-hydroxynaphthalene-1-sulfonate
International Union of Crystallography, 2007Co-Authors: Mizuguchi Jin, Sato Yohei, Uta Kazuya, Sato KazuyukiAbstract:The title compound, C19H34N+·C10H7O4S-, is a charge-control agent used in Electrophotography. The anions form chains along the b axis through O-H･･･O hydrogen bonding
Uta Kazuya - One of the best experts on this subject based on the ideXlab platform.
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Benzyltributylammonium 7-hydroxynaphthalene-1-sulfonate
International Union of Crystallography, 2009Co-Authors: Sato Yohei, Uta Kazuya, Mizuguchi JinAbstract:The title compound, C19H34N+･C10H7O4S-, is a charge-control agent used for toners in Electrophotography. The anions form one-dimensional chains by O—H･･･O hydrogen bonds in a zigzag fashion along the c axis between the OH group of one anion and the sulfonate O atom of a neighboring anion. One of the n-butyl chains of the cation is disordered over two sites in a 0.77:0.23 ratio
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Benzyltributylammonium 4,6-dihydroxynaphthalene-2-sulfonate
International Union of Crystallography, 2009Co-Authors: Uta Kazuya, Mizuguchi JinAbstract:The title molecular salt, C19H34N+･C10H7O5S-, is a chargecontrol agent used for toners in Electrophotography with a high melting point of 508 K. In the crystal structure, the anions form inversion dimers, linked by pairs of O—H･･･O hydrogen bonds. Further O—H･･･O links between dimers generate anionic sheets propagating in (010). One of the n-butyl chains of the cation is disordered over two sets of sites in a 0.53:0.47 ratio
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Benzyltributylammonium 6,7-dihydroxynaphthalene-2-sulfonate
International Union of Crystallography, 2009Co-Authors: Uta Kazuya, Mizuguchi JinAbstract:The title molecular salt, C19H34N+･C10H7O5S-, is a chargecontrol agent used for toners in Electrophotography. There are two formula units in the asymmetric unit. Both anions form inversion dimers connected by pairs of O—H･･･O hydrogen bonds between the –OH group of one anion and a sulfonic O atom of the neighboring one. The two dimers A and B are characterized by a step between the least-squares planes of the naphthalene atoms of 0.85 and 2.30 A ˚ . Further O—H･･･O bonds link the dimers into a two-dimensional network propagating in (110) such that dimer A is hydrogen-bonded to four B units and vice versa. One of the tert-butyl chains in one of the cations is disordered over two sets of sites in a 0.56:0.44 ratio
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Diacetonitriletetrakis{μ2-3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}tetraaquadiiron(III)disodium(I) dihydrate
International Union of Crystallography, 2008Co-Authors: Sato Yohei, Uta Kazuya, Jin MizuguchiAbstract:The title compound, [Fe2Na2(C23H14ClN3O3)4(C2H3N)2(H2O)4]·2H2O, is a hydrated Fe–azo complex dimer that is used as a charge-control agent in Electrophotography. The molecule is a centrosymmetric dimer with two octahedral FeIII units linked by two bridging five-coordinate NaI cations. Each FeIII atom is chelated by the N and two O atoms from two 3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The Na+ cation is coordinated by a carbonyl O atom from the two ligands of each octahedral FeIII unit, two water molecules and the N atom of an acetonitrile molecule. Two solvent water molecules complete the structure. In the crystal structure, the dimeric molecules are bridged by a pair of discrete intermolecular O—H...O hydrogen bonds, one of which involves a sodium-bound water molecule and a hydrate water, and the other a 5-chlorophenolate O atom and a water molecule to form an extended chain along b
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Diacetonitriletetrakis{μ2-3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}tetraaquadiiron(III)disodium(I) dihydrate
International Union of Crystallography, 2008Co-Authors: Sato Yohei, Uta Kazuya, Mizuguchi JinAbstract:The title compound, [Fe2Na2(C23H14ClN3O3)4(C2H3N)2(H2O)4]·2H2O, is a hydrated Fe-azo complex dimer that is used as a charge-control agent in Electrophotography. The molecule is a centrosymmetric dimer with two octahedral FeIII units linked by two bridging five-coordinate NaI cations. Each FeIII atom is chelated by the N and two O atoms from two 3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The Na+ cation is coordinated by a carbonyl O atom from the two ligands of each octahedral FeIII unit, two water molecules and the N atom of an acetonitrile molecule. Two solvent water molecules complete the structure. In the crystal structure, the dimeric molecules are bridged by a pair of discrete intermolecular O-HO hydrogen bonds, one of which involves a sodium-bound water molecule and a hydrate water, and the other a 5-chlorophenolate O atom and a water molecule to form an extended chain along b
Jin Mizuguchi - One of the best experts on this subject based on the ideXlab platform.
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Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)]
International Union of Crystallography, 2008Co-Authors: Jin Mizuguchi, Yohei Sato, Shinpei ItoAbstract:The title compound, [CrNa(C16H9ClN2O2)2(C3H6O)2]n, is an azo-CrIII complex polymer that is used as a charge-control agent in Electrophotography. The monomeric unit is composed of octahedral CrIII and NaI units, and is characterized by twofold rotation symmetry. The CrIII atom is chelated by two N and four O atoms from two [(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The ligand anion exists in the cis form. The NaI atom is coordinated by two phenoxy O atoms from a neighboring CrIII unit, two naphthoxy O atoms from another neighboring CrIII unit and two O atoms from acetone molecules. The dinuclear complex forms a one-dimensional polymer running along the c axis
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Diacetonitriletetrakis{μ2-3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}tetraaquadiiron(III)disodium(I) dihydrate
International Union of Crystallography, 2008Co-Authors: Sato Yohei, Uta Kazuya, Jin MizuguchiAbstract:The title compound, [Fe2Na2(C23H14ClN3O3)4(C2H3N)2(H2O)4]·2H2O, is a hydrated Fe–azo complex dimer that is used as a charge-control agent in Electrophotography. The molecule is a centrosymmetric dimer with two octahedral FeIII units linked by two bridging five-coordinate NaI cations. Each FeIII atom is chelated by the N and two O atoms from two 3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The Na+ cation is coordinated by a carbonyl O atom from the two ligands of each octahedral FeIII unit, two water molecules and the N atom of an acetonitrile molecule. Two solvent water molecules complete the structure. In the crystal structure, the dimeric molecules are bridged by a pair of discrete intermolecular O—H...O hydrogen bonds, one of which involves a sodium-bound water molecule and a hydrate water, and the other a 5-chlorophenolate O atom and a water molecule to form an extended chain along b
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Ammonium bis{3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}ferrate(III) methanol solvate
Acta Crystallographica Section E Structure Reports Online, 2007Co-Authors: Jin Mizuguchi, Yohei Sato, Kazuya UtaAbstract:The title compound, (NH4)[Fe(C23H24ClN3O3)2]·CH4O, is a charge-control agent used in Electrophotography. The central FeIII atom is coordinated by four O atoms and two N atoms of two symmetry-independent ligands. The metallic complex has no crystallographic symmetry. The structure features hydrogen-bonded double chains, which run along the a axis
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n propyl gallate dichloromethane 3 0 5
Acta Crystallographica Section E-structure Reports Online, 2005Co-Authors: Akio Hitachi, Shohei Iwata, Takashi Makino, Jin MizuguchiAbstract:n-Propyl gallate (PG) is a charge-control agent used for toners in Electrophotography, and shows pseudo-polymorphism. The title compound, 3C10H12O5·0.5CH2Cl2, is isostructural with the corresponding chloroform solvate. The asymmetric unit is composed of three PG molecules and a half-molecule of dichloromethane, the solvent being disordered over an inversion centre. There are intra- and intermolecular O—H⋯O hydrogen bonds, forming a two-dimensional hydrogen-bond network in the (421) plane.
Yohei Sato - One of the best experts on this subject based on the ideXlab platform.
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Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)]
International Union of Crystallography, 2008Co-Authors: Jin Mizuguchi, Yohei Sato, Shinpei ItoAbstract:The title compound, [CrNa(C16H9ClN2O2)2(C3H6O)2]n, is an azo-CrIII complex polymer that is used as a charge-control agent in Electrophotography. The monomeric unit is composed of octahedral CrIII and NaI units, and is characterized by twofold rotation symmetry. The CrIII atom is chelated by two N and four O atoms from two [(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The ligand anion exists in the cis form. The NaI atom is coordinated by two phenoxy O atoms from a neighboring CrIII unit, two naphthoxy O atoms from another neighboring CrIII unit and two O atoms from acetone molecules. The dinuclear complex forms a one-dimensional polymer running along the c axis
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Ammonium bis{3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}ferrate(III) methanol solvate
Acta Crystallographica Section E Structure Reports Online, 2007Co-Authors: Jin Mizuguchi, Yohei Sato, Kazuya UtaAbstract:The title compound, (NH4)[Fe(C23H24ClN3O3)2]·CH4O, is a charge-control agent used in Electrophotography. The central FeIII atom is coordinated by four O atoms and two N atoms of two symmetry-independent ligands. The metallic complex has no crystallographic symmetry. The structure features hydrogen-bonded double chains, which run along the a axis
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Diacetonitriletetrakis{μ2-3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}tetraaquadiiron(III)disodium(I) dihydrate
International Union of Crystallography, 2026Co-Authors: Yohei Sato, Kazuya Uta, Mizuguchi JinAbstract:The title compound, [Fe2Na2(C23H14ClN3O3)4(C2H3N)2(H2O)4]·2H2O, is a hydrated Fe–azo complex dimer that is used as a charge-control agent in Electrophotography. The molecule is a centrosymmetric dimer with two octahedral FeIII units linked by two bridging five-coordinate NaI cations. Each FeIII atom is chelated by the N and two O atoms from two 3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The Na+ cation is coordinated by a carbonyl O atom from the two ligands of each octahedral FeIII unit, two water molecules and the N atom of an acetonitrile molecule. Two solvent water molecules complete the structure. In the crystal structure, the dimeric molecules are bridged by a pair of discrete intermolecular O—H⋯O hydrogen bonds, one of which involves a sodium-bound water molecule and a hydrate water, and the other a 5-chlorophenolate O atom and a water molecule to form an extended chain along b