Extraterrestrial Irradiance

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J P Burrows - One of the best experts on this subject based on the ideXlab platform.

  • A cloud identification algorithm over the Arctic for use with AATSR–SLSTR measurements
    'Copernicus GmbH', 2019
    Co-Authors: S. Jafariserajehlou, J P Burrows, L. Mei, M. Vountas, V. Rozanov, R. Hollmann
    Abstract:

    The accurate identification of the presence of cloud in the ground scenes observed by remote-sensing satellites is an end in itself. The lack of knowledge of cloud at high latitudes increases the error and uncertainty in the evaluation and assessment of the changing impact of aerosol and cloud in a warming climate. A prerequisite for the accurate retrieval of aerosol optical thickness (AOT) is the knowledge of the presence of cloud in a ground scene. In our study, observations of the upwelling radiance in the visible (VIS), near infrared (NIR), shortwave infrared (SWIR) and the thermal infrared (TIR), coupled with solar Extraterrestrial Irradiance, are used to determine the reflectance. We have developed a new cloud identification algorithm for application to the reflectance observations of the Advanced Along-Track Scanning Radiometer (AATSR) on European Space Agency (ESA)-Envisat and Sea and Land Surface Temperature Radiometer (SLSTR) on board the ESA Copernicus Sentinel-3A and -3B. The resultant AATSR–SLSTR cloud identification algorithm (ASCIA) addresses the requirements for the study AOT at high latitudes and utilizes time-series measurements. It is assumed that cloud-free surfaces have unchanged or little changed patterns for a given sampling period, whereas cloudy or partly cloudy scenes show much higher variability in space and time. In this method, the Pearson correlation coefficient (PCC) parameter is used to measure the “stability” of the atmosphere–surface system observed by satellites. The cloud-free surface is classified by analysing the PCC values on the block scale 25×25 km2. Subsequently, the reflection at 3.7 µm is used for accurate cloud identification at scene level: with areas of either 1×1 or 0.5×0.5 km2. The ASCIA data product has been validated by comparison with independent observations, e.g. surface synoptic observations (SYNOP), the data from AErosol RObotic NETwork (AERONET) and the following satellite products: (i) the ESA standard cloud product from AATSR L2 nadir cloud flag; (ii) the product from a method based on a clear-snow spectral shape developed at IUP Bremen (Istomina et al., 2010), which we call ISTO; and (iii) the Moderate Resolution Imaging Spectroradiometer (MODIS) products. In comparison to ground-based SYNOP measurements, we achieved a promising agreement better than 95 % and 83 % within ±2 and ±1 okta respectively. In general, ASCIA shows an improved performance in comparison to other algorithms applied to AATSR measurements for the identification of clouds in a ground scene observed at high latitudes.

  • Using a photochemical model for the validation of NO2 satellite measurements at different solar zenith angles
    Atmospheric Chemistry and Physics, 2005
    Co-Authors: A. Bracher, M. Sinnhuber, A. Rozanov, J P Burrows
    Abstract:

    SCIAMACHY (Scanning Imaging Spectrometer for Atmospheric Chartography) aboard the recently launched Environmental Satellite (ENVISAT) of ESA is measuring solar radiance upwelling from the atmosphere and the Extraterrestrial Irradiance. Appropriate inversion of the ultraviolet and visible radiance measurements, observed from the atmospheric limb, yields profiles of nitrogen dioxide, NO2, in the stratosphere (SCIAMACHY-IUP NO2 profiles V1). In order to assess their accuracy, the resulting NO2 profiles have been compared with those retrieved from the space borne occultation instruments Halogen Occultation Experiment (HALOE, data version v19) and Stratospheric Aerosol and Gas Experiment II (SAGE II, data version 6.2). As the HALOE and SAGE II measurements are performed during local sunrise or sunset and because NO2 has a significant diurnal variability, the NO2 profiles derived from HALOE and SAGE II have been transformed to those predicted for the solar zenith angles of the SCIAMACHY measurement by using a 1-dimensional photochemical model. The model used to facilitate the comparison of the NO2 profiles from the different satellite sensors is described and a sensitivity ananlysis provided. Comparisons between NO2 profiles from SCIAMACHY and those from HALOE NO2 but transformed to the SCIAMACHY solar zenith angle, for collocations from July to October 2002, show good agreement (within +/-12%) between the altitude range from 22 to 33km. The results from the comparison of all collocated NO2 profiles from SCIAMACHY and those from SAGE II transformed to the SCIAMACHY solar zenith angle show a systematic negative bias of 10 to 35% between 20km to 38km with a small standard deviation between 5 to 14%. These results agree with those of Newchurch and Ayoub (2004), implying that above 20km NO2 profiles from SAGE II sunset are probably somewhat high.

  • Tropospheric NO2 columns: a comparison between model and retrieved data from GOME measurements
    Atmospheric Chemistry and Physics, 2002
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

  • Atmospheric Chemistry and Physics
    2002
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Abstract. Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

  • tropospheric no 2 columns a comparison between model and retrieved data from gome measurements
    Atmospheric Chemistry and Physics, 2001
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Abstract. Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

Axel Lauer - One of the best experts on this subject based on the ideXlab platform.

  • Tropospheric NO2 columns: a comparison between model and retrieved data from GOME measurements
    Atmospheric Chemistry and Physics, 2002
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

  • Atmospheric Chemistry and Physics
    2002
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Abstract. Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

  • tropospheric no 2 columns a comparison between model and retrieved data from gome measurements
    Atmospheric Chemistry and Physics, 2001
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Abstract. Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

A Richter - One of the best experts on this subject based on the ideXlab platform.

  • Tropospheric NO2 columns: a comparison between model and retrieved data from GOME measurements
    Atmospheric Chemistry and Physics, 2002
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

  • Atmospheric Chemistry and Physics
    2002
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Abstract. Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

  • tropospheric no 2 columns a comparison between model and retrieved data from gome measurements
    Atmospheric Chemistry and Physics, 2001
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Abstract. Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

Martin Dameris - One of the best experts on this subject based on the ideXlab platform.

  • Tropospheric NO2 columns: a comparison between model and retrieved data from GOME measurements
    Atmospheric Chemistry and Physics, 2002
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

  • Atmospheric Chemistry and Physics
    2002
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Abstract. Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

  • tropospheric no 2 columns a comparison between model and retrieved data from gome measurements
    Atmospheric Chemistry and Physics, 2001
    Co-Authors: Axel Lauer, Martin Dameris, A Richter, J P Burrows
    Abstract:

    Abstract. Tropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated.

Burrows J. P. - One of the best experts on this subject based on the ideXlab platform.

  • Using a photochemical model for the validation of NO2 satellite measurements at different solar zenith angles
    European Geosciences Union, 2005
    Co-Authors: Bracher A., Sinnhuber M., Rozanov A., Burrows J. P.
    Abstract:

    International audienceSCIAMACHY (Scanning Imaging Spectrometer for Atmospheric Chartography) aboard the recently launched Environmental Satellite (ENVISAT) of ESA is measuring solar radiance upwelling from the atmosphere and the Extraterrestrial Irradiance. Appropriate inversion of the ultraviolet and visible radiance measurements, observed from the atmospheric limb, yields profiles of nitrogen dioxide, NO2, in the stratosphere (SCIAMACHY-IUP NO2 profiles V1). In order to assess their accuracy, the resulting NO2 profiles have been compared with those retrieved from the space borne occultation instruments Halogen Occultation Experiment (HALOE, data version v19) and Stratospheric Aerosol and Gas Experiment II (SAGE II, data version 6.2). As the HALOE and SAGE II measurements are performed during local sunrise or sunset and because NO2 has a significant diurnal variability, the NO2 profiles derived from HALOE and SAGE II have been transformed to those predicted for the solar zenith angles of the SCIAMACHY measurement by using a 1-dimensional photochemical model. The model used to facilitate the comparison of the NO2 profiles from the different satellite sensors is described and a sensitivity ananlysis provided. Comparisons between NO2 profiles from SCIAMACHY and those from HALOE NO2 but transformed to the SCIAMACHY solar zenith angle, for collocations from July to October 2002, show good agreement (within +/-12%) between the altitude range from 22 to 33km. The results from the comparison of all collocated NO2 profiles from SCIAMACHY and those from SAGE II transformed to the SCIAMACHY solar zenith angle show a systematic negative bias of 10 to 35% between 20km to 38km with a small standard deviation between 5 to 14%. These results agree with those of Newchurch and Ayoub (2004), implying that above 20km NO2 profiles from SAGE II sunset are probably somewhat high

  • Using photochemical models for the validation of NO2 satellite measurements at different solar zenith angles
    European Geosciences Union, 2004
    Co-Authors: Bracher A., Sinnhuber M., Rozanov A., Burrows J. P.
    Abstract:

    International audienceSCIAMACHY (Scanning Imaging Spectrometer for Atmospheric Chartography) aboard the recently launched Environmental Satellite (ENVISAT) of ESA is measuring solar radiance upwelling from the atmosphere and the Extraterrestrial Irradiance. Appropriate inversion of the ultraviolet and visible radiance measurements, observed from the atmospheric limb, yields profiles of nitrogen dioxide, NO2, in the stratosphere. In order to assess their accuracy, the resulting NO2 profiles have been compared with those retrieved from the space borne occultation instruments Halogen Occultation Experiment (HALOE, data version v19) and Stratospheric Aerosol and Gas Experiment II (SAGE II, data version 6.20). As the HALOE and SAGE II measurements are performed during local sunrise or sunset and because NO2 has a significant diurnal variability, the NO2 profiles derived from HALOE and SAGE II have been transformed to those predicted for the solar zenith angles of the SCIAMACHY measurement by using a 1-D photochemical model. The model used to facilitate the comparison of the NO2 profiles from the different satellite sensors is described and an error assessment provided. Comparisons between NO2 profiles from SCIAMACHY and those from HALOE NO2 but transformed to the SCIAMACHY solar zenith angle, for collocations from July to October 2002, show good agreement (within +/?15%) between the altitude range from 22 to 33 km. The results from the comparison of all collocated NO2 profiles from SCIAMACHY and those from SAGE II transformed to the SCIAMACHY solar zenith angle show a systematic negative bias of 10 to 35% between 20 km to 38 km with a small standard deviation between 5 to 14%. These results agree with those of Newchurch and Ayoub (2004), implying that above 20 km NO2 profiles from SAGE II sunset are probably somewhat high

  • Tropospheric NO2 columns: a comparison between model and retrieved data from GOME measurements
    European Geosciences Union, 2002
    Co-Authors: Lauer A., Dameris M., Richter A., Burrows J. P.
    Abstract:

    International audienceTropospheric NO2 plays a variety of significant roles in atmospheric chemistry. In the troposphere it is one of the most significant precursors of photochemical ozone (O3) production and nitric acid (HNO3). In this study tropospheric NO2 columns were calculated by the fully coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM. These have been compared with tropospheric NO2 columns, retrieved using the tropospheric excess method from measurements by the Global Ozone Monitoring Experiment (GOME) of up-welling earthshine radiance and the Extraterrestrial Irradiance. GOME is part of the core payload of the second European Research Satellite (ERS-2). For this study the first five years of GOME measurements have been used. The period of five years of observational data is sufficiently long to facilitate for the first time a comparison based on climatological averages with global coverage, focussing on the geographical distribution of the tropospheric NO2. A new approach of analysing regional differences (i.e. on continental scales) by calculating individual averages for different environments provides more detailed information about specific NOx sources and of their seasonal variations. The results obtained enable the validity of the model NO2 source distribution and the assumptions used to separate tropospheric and stratospheric parts of the NO2 column amount from the satellite measurements to be investigated