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Bilal Gürbüz - One of the best experts on this subject based on the ideXlab platform.

Belgin Coşge - One of the best experts on this subject based on the ideXlab platform.

Mustafa Kiralan - One of the best experts on this subject based on the ideXlab platform.

Hartwig Schulz - One of the best experts on this subject based on the ideXlab platform.

  • Discrimination of Fennel chemotypes applying IR and Raman spectroscopy – discovery of a new γ -asarone chemotype
    Julius-Kühn-Archiv, 2016
    Co-Authors: Andrea Krähmer, Gennadi Gudi, Lothar Henning, Hans Kruger, Hartwig Schulz
    Abstract:

    Various vibrational spectroscopy methods have been applied to classify different Fennel chemotypes according to their individual profile of volatile substances. Intact Fennel fruits of different chemotypes could be successfully discriminated by Attenuated Total Reflectance Fourier transform Infrared (ATR-FTIR) and Near Infrared (NIR) spectroscopy. Solvent extracts (CCl4) of the considered Fennel fruits showed characteristic fingerprints with marker bands related to the individual volatile components ( trans -anethole, fenchone, estragole, piperitenone oxide, γ -asarone, limonene) for ATR-FTIR and FT-Raman spectroscopy. Especially νC=C and νC=O absorption bands contribute to the different spectral profiles. Based on hierarchical cluster analysis, the considered Fennel accessions were classified according to gas chromatographic (GC) and vibrational spectroscopic data. Furthermore, even a discrimination of “sweet” and “bitter” Fennel fruits, both belonging to the trans -anethole chemotype, could be successfully performed. All vibrational spectroscopical techniques used in this study are rapid and easy to apply. Hence, they allow different Fennel chemotypes to be reliably distinguished and can also be used for on-site measurement in free nature.

  • discrimination of Fennel chemotypes applying ir and raman spectroscopy discovery of a new γ asarone chemotype
    Journal of Agricultural and Food Chemistry, 2014
    Co-Authors: Gennadi Gudi, Andrea Krähmer, Lothar Hennig, Hans Kruger, Hartwig Schulz
    Abstract:

    Various vibrational spectroscopy methods have been applied to classify different Fennel chemotypes according to their individual profile of volatile substances. Intact Fennel fruits of different chemotypes could be successfully discriminated by attenuated total reflectance Fourier transform infrared (ATR-FTIR) and near infrared (NIR) spectroscopy. Solvent extracts (CCl4) of the considered Fennel fruits showed characteristic fingerprints with marker bands related to the individual volatile components (trans-anethole, fenchone, estragole, piperitenone oxide, γ-asarone, limonene) for ATR-FTIR and FT-Raman spectroscopy. Especially νC═C and νC═O absorption bands contribute to the different spectral profiles. On the basis of hierarchical cluster analysis, the considered Fennel accessions were classified according to gas chromatographic (GC) and vibrational spectroscopic data. Furthermore, even a discrimination of “sweet” and “bitter” Fennel fruits, both belonging to the trans-anethole chemotype, could be succes...

Denis Grancher - One of the best experts on this subject based on the ideXlab platform.

  • Variability of ferulenol and ferprenin concentration in French giant Fennel (Ferula sp.) leaves
    Toxicon, 2019
    Co-Authors: Gilbert Gault, Sébastien Lefebvre, Etienne Benoit, Virginie Lattard, Denis Grancher
    Abstract:

    Few studies have reported quantitative data about the levels of prenylated coumarins in Ferula sp. Yet, the toxicity of Ferula sp. is only due to the presence of prenylated coumarins and to their concentrations and all studies suggest the existence of several chemotypes within the same species or even within the same variety. The aim of this study was to investigate the hypothesis of different chemotypes in french Ferula sp. in relationship with the botanical species. In this objective, the species of giant Fennels and their concentrations in prenylated coumarins were explored. Three different species or subspecies of giant Fennel were detected in continental France: F. communis communis communis L., F. communis catalaunica microcarpa Cauwet-Marc and F. glauca L. Surprisingly, the three species/subspecies of giant Fennels were found to be located in exclusive and well separated geographical areas. In French giant Fennels, ferulenol and ferprenin were detected. Distribution of ferulenol and ferprenin were found to be different between botanical varieties, but also according to the season, the soil and the altitude. Our study seems to suggest that among F. communis species, the same plant can be regarded as poisonous at one point and another as non-poisonous.