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Feng Gao - One of the best experts on this subject based on the ideXlab platform.

  • colorimetric and phosphorimetric dual signaling strategy mediated by inner Filter Effect for highly sensitive assay of organophosphorus pesticides
    Journal of Agricultural and Food Chemistry, 2015
    Co-Authors: Rong Zhang, Junyong Sun, Feng Gao
    Abstract:

    We describe here a colorimetric and phosphorimetric dual-signaling strategy for sensitive assay of organophosphorus pesticides (OPPs). The principle for assay depends on the phenomenon that the phosphorescence of Mn-ZnS quantum dots (QDs) can be dramatically quenched by Au nanoparticles (AuNPs) through the inner Filter Effect (IFE) and the activity of acetylcholinesterase (AChE), an enzyme that catalytically hydrolyzes acetylthiocholine to thiocholine that can be inhibited by OPPs. By virtue of the variations of absorbance and phosphorescence of the analytical system, a dual-readout assay for OPPs has been proposed. The limits of detection for different OPPs including paraoxon, parathion, omethoate, and dimethyl dichlorovinyl phosphate (DDVP) are found to be 0.29, 0.59, 0.67, and 0.44 ng/L, respectively. The proposed assay was allowed to detect pesticides in real spiked samples and authentic contaminated apples with satisfactory results, suggesting its potential applications to detect pesticides in complicated samples.

  • colorimetric and phosphorimetric dual signaling strategy mediated by inner Filter Effect for highly sensitive assay of organophosphorus pesticides
    Journal of Agricultural and Food Chemistry, 2015
    Co-Authors: Rong Zhang, Junyong Sun, Feng Gao
    Abstract:

    We describe here a colorimetric and phosphorimetric dual-signaling strategy for sensitive assay of organophosphorus pesticides (OPPs). The principle for assay depends on the phenomenon that the phosphorescence of Mn-ZnS quantum dots (QDs) can be dramatically quenched by Au nanoparticles (AuNPs) through the inner Filter Effect (IFE) and the activity of acetylcholinesterase (AChE), an enzyme that catalytically hydrolyzes acetylthiocholine to thiocholine that can be inhibited by OPPs. By virtue of the variations of absorbance and phosphorescence of the analytical system, a dual-readout assay for OPPs has been proposed. The limits of detection for different OPPs including paraoxon, parathion, omethoate, and dimethyl dichlorovinyl phosphate (DDVP) are found to be 0.29, 0.59, 0.67, and 0.44 ng/L, respectively. The proposed assay was allowed to detect pesticides in real spiked samples and authentic contaminated apples with satisfactory results, suggesting its potential applications to detect pesticides in compli...

  • Colorimetric and Phosphorimetric Dual-Signaling Strategy Mediated by Inner Filter Effect for Highly Sensitive Assay of Organophosphorus Pesticides
    2015
    Co-Authors: Rong Zhang, Junyong Sun, Feng Gao
    Abstract:

    We describe here a colorimetric and phosphorimetric dual-signaling strategy for sensitive assay of organophosphorus pesticides (OPPs). The principle for assay depends on the phenomenon that the phosphorescence of Mn-ZnS quantum dots (QDs) can be dramatically quenched by Au nanoparticles (AuNPs) through the inner Filter Effect (IFE) and the activity of acetylcholinesterase (AChE), an enzyme that catalytically hydrolyzes acetylthiocholine to thiocholine that can be inhibited by OPPs. By virtue of the variations of absorbance and phosphorescence of the analytical system, a dual-readout assay for OPPs has been proposed. The limits of detection for different OPPs including paraoxon, parathion, omethoate, and dimethyl dichlorovinyl phosphate (DDVP) are found to be 0.29, 0.59, 0.67, and 0.44 ng/L, respectively. The proposed assay was allowed to detect pesticides in real spiked samples and authentic contaminated apples with satisfactory results, suggesting its potential applications to detect pesticides in complicated samples

Rong Zhang - One of the best experts on this subject based on the ideXlab platform.

  • colorimetric and phosphorimetric dual signaling strategy mediated by inner Filter Effect for highly sensitive assay of organophosphorus pesticides
    Journal of Agricultural and Food Chemistry, 2015
    Co-Authors: Rong Zhang, Junyong Sun, Feng Gao
    Abstract:

    We describe here a colorimetric and phosphorimetric dual-signaling strategy for sensitive assay of organophosphorus pesticides (OPPs). The principle for assay depends on the phenomenon that the phosphorescence of Mn-ZnS quantum dots (QDs) can be dramatically quenched by Au nanoparticles (AuNPs) through the inner Filter Effect (IFE) and the activity of acetylcholinesterase (AChE), an enzyme that catalytically hydrolyzes acetylthiocholine to thiocholine that can be inhibited by OPPs. By virtue of the variations of absorbance and phosphorescence of the analytical system, a dual-readout assay for OPPs has been proposed. The limits of detection for different OPPs including paraoxon, parathion, omethoate, and dimethyl dichlorovinyl phosphate (DDVP) are found to be 0.29, 0.59, 0.67, and 0.44 ng/L, respectively. The proposed assay was allowed to detect pesticides in real spiked samples and authentic contaminated apples with satisfactory results, suggesting its potential applications to detect pesticides in complicated samples.

  • colorimetric and phosphorimetric dual signaling strategy mediated by inner Filter Effect for highly sensitive assay of organophosphorus pesticides
    Journal of Agricultural and Food Chemistry, 2015
    Co-Authors: Rong Zhang, Junyong Sun, Feng Gao
    Abstract:

    We describe here a colorimetric and phosphorimetric dual-signaling strategy for sensitive assay of organophosphorus pesticides (OPPs). The principle for assay depends on the phenomenon that the phosphorescence of Mn-ZnS quantum dots (QDs) can be dramatically quenched by Au nanoparticles (AuNPs) through the inner Filter Effect (IFE) and the activity of acetylcholinesterase (AChE), an enzyme that catalytically hydrolyzes acetylthiocholine to thiocholine that can be inhibited by OPPs. By virtue of the variations of absorbance and phosphorescence of the analytical system, a dual-readout assay for OPPs has been proposed. The limits of detection for different OPPs including paraoxon, parathion, omethoate, and dimethyl dichlorovinyl phosphate (DDVP) are found to be 0.29, 0.59, 0.67, and 0.44 ng/L, respectively. The proposed assay was allowed to detect pesticides in real spiked samples and authentic contaminated apples with satisfactory results, suggesting its potential applications to detect pesticides in compli...

  • Colorimetric and Phosphorimetric Dual-Signaling Strategy Mediated by Inner Filter Effect for Highly Sensitive Assay of Organophosphorus Pesticides
    2015
    Co-Authors: Rong Zhang, Junyong Sun, Feng Gao
    Abstract:

    We describe here a colorimetric and phosphorimetric dual-signaling strategy for sensitive assay of organophosphorus pesticides (OPPs). The principle for assay depends on the phenomenon that the phosphorescence of Mn-ZnS quantum dots (QDs) can be dramatically quenched by Au nanoparticles (AuNPs) through the inner Filter Effect (IFE) and the activity of acetylcholinesterase (AChE), an enzyme that catalytically hydrolyzes acetylthiocholine to thiocholine that can be inhibited by OPPs. By virtue of the variations of absorbance and phosphorescence of the analytical system, a dual-readout assay for OPPs has been proposed. The limits of detection for different OPPs including paraoxon, parathion, omethoate, and dimethyl dichlorovinyl phosphate (DDVP) are found to be 0.29, 0.59, 0.67, and 0.44 ng/L, respectively. The proposed assay was allowed to detect pesticides in real spiked samples and authentic contaminated apples with satisfactory results, suggesting its potential applications to detect pesticides in complicated samples

David P Divincenzo - One of the best experts on this subject based on the ideXlab platform.

  • quantum computing and single qubit measurements using the spin Filter Effect invited
    Journal of Applied Physics, 1999
    Co-Authors: David P Divincenzo
    Abstract:

    Many things will have to go right for quantum computation to become a reality in the lab. For any of the presently proposed approaches involving spin states in solids, an essential requirement is that these spins should be measured at the single-Bohr-magneton level. Fortunately, quantum computing provides a suggestion for a new approach to this seemingly almost impossible task: convert the magnetization into a charge, and measure the charge. I show how this might be done by exploiting the spin-Filter Effect provided by ferromagnetic tunnel barriers, used in conjunction with one-electron quantum dots.

  • Quantum computing and single-qubit measurements using the spin Filter Effect
    Journal of Applied Physics, 1999
    Co-Authors: David P Divincenzo
    Abstract:

    Many things will have to go right for quantum computation to become a reality in the lab. For any of the presently-proposed approaches involving spin states in solids, an essential requirement is that these spins should be measured at the single-Bohr-magneton level. Fortunately, quantum computing provides a suggestion for a new approach to this seemingly almost impossible task: convert the magnetization into a charge, and measure the charge. I show how this might be done by exploiting the spin Filter Effect provided by ferromagnetic tunnel barriers, used in conjunction with one-electron quantum dots.

Erkang Wang - One of the best experts on this subject based on the ideXlab platform.

  • universal platform for ratiometric sensing based on catalytically induced inner Filter Effect by cu2
    Analytical Chemistry, 2020
    Co-Authors: Chao Peng, Huanhuan Xing, Yuan Xue, Erkang Wang, Yongchao Fan
    Abstract:

    Integrating two kinds of fluorescent probes in one system to develop a ratiometric sensing platform is of prime importance for achieving an accurate assay. Inspired by the efficient overlapped spectrum of 2-aminoterephthalic acid (PTA-NH2) and 2,3-diaminophenazine (DAP), a new sensitive ratiometric fluorescent sensor has been developed for Cu2+ on the basis of in situ converting o-phenylenediamine (OPD) into DAP through the catalysis of Cu2+. Here, the presence of Cu2+ induced the emission of DAP, which acted as an energy acceptor to inhibit the emission of PTA-NH2. This dual-emission reverse change ratiometric profile based on the inner-Filter Effect improved sensitivity and accuracy, and the highly sensitive determination of Cu2+ with a detection limit of 1.7 nmol·L-1 was obtained. The proposed sensing platform displayed the wide range of detection of Cu2+ from 5 to 200 nmol·L-1 by modulating the reaction time between Cu2+ and OPD. Moreover, based on the specific interaction between glutathione (GSH) and Cu2+, this fluorescent sensor showed high response toward GSH in a range of 0.5-80 μmol·L-1 with a detection limit of 0.16 μmol·L-1. The successful construction of this simple ratiometric sensing platform without the participation of enzymes provides a new route for the detection of small biological molecules that are closely related to human health.

  • glutathione regulated inner Filter Effect of mno2 nanosheets on boron nitride quantum dots for sensitive assay
    Analytical Chemistry, 2019
    Co-Authors: Chao Peng, Huanhuan Xing, Xiushuang Fan, Yuan Xue, Erkang Wang
    Abstract:

    Glutathione (GSH) can help the body maintain the function of the normal immune system and its level change is associated with a variety of diseases. To achieve the ultrasensitive assay of GSH, a "switch on" nanosensor is designed on the basis of GSH regulating the inner Filter Effect (IFE) of MnO2 nanosheets (MnO2 NS) on boron nitride quantum dots (BNQDs). Here, the fluorescence of BNQDs is quenched efficiently in the presence of redoxable MnO2 NS because of the superior light absorption capability; however, the introduction of GSH can trigger the decomposition of MnO2 to Mn2+ and weaken the IFE, causing the partial fluorescence recovery. The recovered fluorescence is dependent on the concentration of GSH. Under the optimal conditions, this sensing platform shows the response to GSH in the range of 0.5-250 μM with the detection limit of 160 nM. On the basis of the GSH activated reduction of MnO2 NS, the MnO2 NS/BNQDs nanoprobes exhibit good selectivity to GSH. The practical application of the proposed system is demonstrated by detecting the GSH in human plasma samples with satisfying results.

Junyong Sun - One of the best experts on this subject based on the ideXlab platform.

  • colorimetric and phosphorimetric dual signaling strategy mediated by inner Filter Effect for highly sensitive assay of organophosphorus pesticides
    Journal of Agricultural and Food Chemistry, 2015
    Co-Authors: Rong Zhang, Junyong Sun, Feng Gao
    Abstract:

    We describe here a colorimetric and phosphorimetric dual-signaling strategy for sensitive assay of organophosphorus pesticides (OPPs). The principle for assay depends on the phenomenon that the phosphorescence of Mn-ZnS quantum dots (QDs) can be dramatically quenched by Au nanoparticles (AuNPs) through the inner Filter Effect (IFE) and the activity of acetylcholinesterase (AChE), an enzyme that catalytically hydrolyzes acetylthiocholine to thiocholine that can be inhibited by OPPs. By virtue of the variations of absorbance and phosphorescence of the analytical system, a dual-readout assay for OPPs has been proposed. The limits of detection for different OPPs including paraoxon, parathion, omethoate, and dimethyl dichlorovinyl phosphate (DDVP) are found to be 0.29, 0.59, 0.67, and 0.44 ng/L, respectively. The proposed assay was allowed to detect pesticides in real spiked samples and authentic contaminated apples with satisfactory results, suggesting its potential applications to detect pesticides in complicated samples.

  • colorimetric and phosphorimetric dual signaling strategy mediated by inner Filter Effect for highly sensitive assay of organophosphorus pesticides
    Journal of Agricultural and Food Chemistry, 2015
    Co-Authors: Rong Zhang, Junyong Sun, Feng Gao
    Abstract:

    We describe here a colorimetric and phosphorimetric dual-signaling strategy for sensitive assay of organophosphorus pesticides (OPPs). The principle for assay depends on the phenomenon that the phosphorescence of Mn-ZnS quantum dots (QDs) can be dramatically quenched by Au nanoparticles (AuNPs) through the inner Filter Effect (IFE) and the activity of acetylcholinesterase (AChE), an enzyme that catalytically hydrolyzes acetylthiocholine to thiocholine that can be inhibited by OPPs. By virtue of the variations of absorbance and phosphorescence of the analytical system, a dual-readout assay for OPPs has been proposed. The limits of detection for different OPPs including paraoxon, parathion, omethoate, and dimethyl dichlorovinyl phosphate (DDVP) are found to be 0.29, 0.59, 0.67, and 0.44 ng/L, respectively. The proposed assay was allowed to detect pesticides in real spiked samples and authentic contaminated apples with satisfactory results, suggesting its potential applications to detect pesticides in compli...

  • Colorimetric and Phosphorimetric Dual-Signaling Strategy Mediated by Inner Filter Effect for Highly Sensitive Assay of Organophosphorus Pesticides
    2015
    Co-Authors: Rong Zhang, Junyong Sun, Feng Gao
    Abstract:

    We describe here a colorimetric and phosphorimetric dual-signaling strategy for sensitive assay of organophosphorus pesticides (OPPs). The principle for assay depends on the phenomenon that the phosphorescence of Mn-ZnS quantum dots (QDs) can be dramatically quenched by Au nanoparticles (AuNPs) through the inner Filter Effect (IFE) and the activity of acetylcholinesterase (AChE), an enzyme that catalytically hydrolyzes acetylthiocholine to thiocholine that can be inhibited by OPPs. By virtue of the variations of absorbance and phosphorescence of the analytical system, a dual-readout assay for OPPs has been proposed. The limits of detection for different OPPs including paraoxon, parathion, omethoate, and dimethyl dichlorovinyl phosphate (DDVP) are found to be 0.29, 0.59, 0.67, and 0.44 ng/L, respectively. The proposed assay was allowed to detect pesticides in real spiked samples and authentic contaminated apples with satisfactory results, suggesting its potential applications to detect pesticides in complicated samples