The Experts below are selected from a list of 273 Experts worldwide ranked by ideXlab platform
Dionisios G. Vlachos - One of the best experts on this subject based on the ideXlab platform.
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production of renewable oleo furan surfactants by cross ketonization of biomass derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Synthesis of 2-dodecanoyl furan is a crucial step in the formulation of oleo-furan sulfonates as bio-surfactants from biomass-derived furans and vegetable-oil-derived molecules. Herein, cross-ketonization of 2-Furoic Acid and lauric Acid is proposed to produce the bio-surfactant precursor. Among the commonly reported metal oxide ketonization catalysts, the inexpensive and abundant iron oxides are demonstrated as effective and recyclable catalysts, enabling up to 77% selectivity to 2-dodecanoyl furan at 56% lauric Acid conversion. Catalyst characterization by X-ray diffraction, H2 temperature-programmed reduction, and X-ray photoelectron spectroscopy indicates that Fe3O4 is the catalytically active and stable phase. 13C isotopic tracing experiments suggest that cross-ketonization on Fe3O4 proceeds via a β-keto Acid intermediate.
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Production of renewable oleo-furan surfactants by cross-ketonization of biomass-derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Production of an oleo-furan surfactant precursor from biomass-derived Furoic Acid and fatty Acid via cross-ketonization.
Hannah Nguyen - One of the best experts on this subject based on the ideXlab platform.
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production of renewable oleo furan surfactants by cross ketonization of biomass derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Synthesis of 2-dodecanoyl furan is a crucial step in the formulation of oleo-furan sulfonates as bio-surfactants from biomass-derived furans and vegetable-oil-derived molecules. Herein, cross-ketonization of 2-Furoic Acid and lauric Acid is proposed to produce the bio-surfactant precursor. Among the commonly reported metal oxide ketonization catalysts, the inexpensive and abundant iron oxides are demonstrated as effective and recyclable catalysts, enabling up to 77% selectivity to 2-dodecanoyl furan at 56% lauric Acid conversion. Catalyst characterization by X-ray diffraction, H2 temperature-programmed reduction, and X-ray photoelectron spectroscopy indicates that Fe3O4 is the catalytically active and stable phase. 13C isotopic tracing experiments suggest that cross-ketonization on Fe3O4 proceeds via a β-keto Acid intermediate.
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Production of renewable oleo-furan surfactants by cross-ketonization of biomass-derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Production of an oleo-furan surfactant precursor from biomass-derived Furoic Acid and fatty Acid via cross-ketonization.
Weiqing Zheng - One of the best experts on this subject based on the ideXlab platform.
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production of renewable oleo furan surfactants by cross ketonization of biomass derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Synthesis of 2-dodecanoyl furan is a crucial step in the formulation of oleo-furan sulfonates as bio-surfactants from biomass-derived furans and vegetable-oil-derived molecules. Herein, cross-ketonization of 2-Furoic Acid and lauric Acid is proposed to produce the bio-surfactant precursor. Among the commonly reported metal oxide ketonization catalysts, the inexpensive and abundant iron oxides are demonstrated as effective and recyclable catalysts, enabling up to 77% selectivity to 2-dodecanoyl furan at 56% lauric Acid conversion. Catalyst characterization by X-ray diffraction, H2 temperature-programmed reduction, and X-ray photoelectron spectroscopy indicates that Fe3O4 is the catalytically active and stable phase. 13C isotopic tracing experiments suggest that cross-ketonization on Fe3O4 proceeds via a β-keto Acid intermediate.
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Production of renewable oleo-furan surfactants by cross-ketonization of biomass-derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Production of an oleo-furan surfactant precursor from biomass-derived Furoic Acid and fatty Acid via cross-ketonization.
Marat Orazov - One of the best experts on this subject based on the ideXlab platform.
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production of renewable oleo furan surfactants by cross ketonization of biomass derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Synthesis of 2-dodecanoyl furan is a crucial step in the formulation of oleo-furan sulfonates as bio-surfactants from biomass-derived furans and vegetable-oil-derived molecules. Herein, cross-ketonization of 2-Furoic Acid and lauric Acid is proposed to produce the bio-surfactant precursor. Among the commonly reported metal oxide ketonization catalysts, the inexpensive and abundant iron oxides are demonstrated as effective and recyclable catalysts, enabling up to 77% selectivity to 2-dodecanoyl furan at 56% lauric Acid conversion. Catalyst characterization by X-ray diffraction, H2 temperature-programmed reduction, and X-ray photoelectron spectroscopy indicates that Fe3O4 is the catalytically active and stable phase. 13C isotopic tracing experiments suggest that cross-ketonization on Fe3O4 proceeds via a β-keto Acid intermediate.
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Production of renewable oleo-furan surfactants by cross-ketonization of biomass-derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Production of an oleo-furan surfactant precursor from biomass-derived Furoic Acid and fatty Acid via cross-ketonization.
Yunzhu Wang - One of the best experts on this subject based on the ideXlab platform.
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production of renewable oleo furan surfactants by cross ketonization of biomass derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Synthesis of 2-dodecanoyl furan is a crucial step in the formulation of oleo-furan sulfonates as bio-surfactants from biomass-derived furans and vegetable-oil-derived molecules. Herein, cross-ketonization of 2-Furoic Acid and lauric Acid is proposed to produce the bio-surfactant precursor. Among the commonly reported metal oxide ketonization catalysts, the inexpensive and abundant iron oxides are demonstrated as effective and recyclable catalysts, enabling up to 77% selectivity to 2-dodecanoyl furan at 56% lauric Acid conversion. Catalyst characterization by X-ray diffraction, H2 temperature-programmed reduction, and X-ray photoelectron spectroscopy indicates that Fe3O4 is the catalytically active and stable phase. 13C isotopic tracing experiments suggest that cross-ketonization on Fe3O4 proceeds via a β-keto Acid intermediate.
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Production of renewable oleo-furan surfactants by cross-ketonization of biomass-derived Furoic Acid and fatty Acids
Catalysis Science & Technology, 2021Co-Authors: Hannah Nguyen, Yunzhu Wang, David Moglia, Weiqing Zheng, Marat Orazov, Dionisios G. VlachosAbstract:Production of an oleo-furan surfactant precursor from biomass-derived Furoic Acid and fatty Acid via cross-ketonization.
