Irreversible Deformation

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K Komvopoulos - One of the best experts on this subject based on the ideXlab platform.

Vanessa Fierro - One of the best experts on this subject based on the ideXlab platform.

  • Irreversible Deformation of hyper crosslinked polymers after hydrogen adsorption
    Journal of Colloid and Interface Science, 2022
    Co-Authors: Pamela Ramirezvidal, F Suarezgarcia, Rafael Luan Sehn Canevesi, Alberto Castromuniz, Philippe Gadonneix, J I Paredes, Alain Celzard, Vanessa Fierro
    Abstract:

    Hyper-crosslinked polymers (HCPs) have been produced by the Friedel-Crafts reaction using anthracene, benzene, carbazole or dibenzothiophene as precursors and dimethoxymethane as crosslinker, and the effect of graphene oxide (GO) addition has been studied. The resulting HCPs were highly microporous with BET areas (A BET) between 590 and 1120 m 2 g A1. The benzene-derived HCP (B1FeM2) and the corresponding composite with GO (B1FM2-GO) exhibited the highest A BET and were selected to study their hydrogen adsorption capacities in the pressure range of 0.1-14 MPa at 77 K. The maximum H 2 excess uptake was 2.1 and 2.0 wt% for B1FeM2 and B1FeM2-GO, respectively, at 4 MPa and 77 K. The addition of GO reduced the specific surface area but increased the density of the resultant HCP-GO composites, which is beneficial for practical applications and proves that materials giving higher gravimetric storage capacities are not necessarily those that offer higher volumetric capacities. H 2 adsorption-desorption cycles up to 14 MPa showed Irreversible Deformation of both HCP and HCP-GO materials, which calls into question their application for hydrogen adsorption at pressures above 4 MPa.

F D Fischer - One of the best experts on this subject based on the ideXlab platform.

  • The Irreversible Deformation of a duplex stainless steel under thermal cycling
    Materials Science and Engineering A, 1993
    Co-Authors: Thomas Siegmund, E Werner, F D Fischer
    Abstract:

    In duplex stainless steels the constituent phases austenite and ferrite have different coefficients of thermal expansion. On varying the temperature a remarkable stress state develops which changes in sign from phase to phase. On pure thermal cycling the yield strength of the phases can be exceeded. Specimens of a forged duplex steel with uniaxial anisotropic microstructure were investigated in dilatometer experiments. Under repeated thermal cycles specimens deformed irreversibly with a monotonic accumulation of strains. In longitudinal specimens an increase in length was observed. Transverse specimens, however, decrease in length. A micromechanical model applying the finite element method is used to calculate the thermal properties of the duplex steel from the properties of its constituent phases. A mechanism driving the ratchet effect is proposed. The temperature dependent yield strength of the phases is responsible for the Irreversible Deformations. The model points out the importance of correct representation of the spatial distribution of the constituent phases in the micromechanical model. A systematic quantitative investigation of the effects of microstructure on the overall material behavior is based on a description of real and model microstructures by the same stereological parameters. Results from model calculations are in good agreement with results from experiments. © 1993.

K Rusinko - One of the best experts on this subject based on the ideXlab platform.

  • synthetic theory of Irreversible Deformation in the context of fundamental bases of plasticity
    Mechanics of Materials, 2009
    Co-Authors: A Rusinko, K Rusinko
    Abstract:

    Abstract A new theory, the synthetic theory of Irreversible Deformation, is presented. This theory is based on the Sanders variant of flow plasticity theory and the Batdorf–Budiansky slip concept and concerns with small plastic strains of work-hardening materials. The synthetic theory is considered in the context of the main requirements imposed on theories of plasticity. Therefore, first, the disagreements of classical theories (flow plasticity theories and the slip concept) with these requirements are indicated and then it is shown how the synthetic theory removes these shortcomings. One of the most important features of the proposed theory is the arising of corner point on a loading surface during loading. This fact considerably widens the applicability of the synthetic theory, especially for the cases of non-smooth (angular) loading trajectories.

Ben P Kirtman - One of the best experts on this subject based on the ideXlab platform.