The Experts below are selected from a list of 276 Experts worldwide ranked by ideXlab platform

B W Brooks - One of the best experts on this subject based on the ideXlab platform.

  • kinetic studies of aqueous polymerization of acrylic acid initiated using Potassium Bromate sodium metabisulphite redox pair
    Polymer International, 1998
    Co-Authors: B W Brooks
    Abstract:

    Aqueous polymerization of acrylic acid was conducted using Potassium Bromate/sodium metabisulphite redox initiators under isothermal conditions. The initial polymerization rates were determined with variation in temperature and in the initial concentrations of acrylic acid, Potassium Bromate and sodium metabisulphite. The effect of pH on polymerization was also investigated. An overall activation energy of 28·62kJmol-1 was obtained over the temperature range 13–43°C. The polymerization is initiated by free radicals and terminated by a combination of monomolecular and bimolecular modes. The cage effect and chain transfer to bisulphite anion are probably both significant. © 1998 SCI.

  • Kinetic studies of aqueous polymerization of acrylic acid initiated using Potassium Bromate/sodium metabisulphite redox pair
    Polymer International, 1998
    Co-Authors: Zuifang Liu, B W Brooks
    Abstract:

    Aqueous polymerization of acrylic acid was conducted using Potassium Bromate/sodium metabisulphite redox initiators under isothermal conditions. The initial polymerization rates were determined with variation in temperature and in the initial concentrations of acrylic acid, Potassium Bromate and sodium metabisulphite. The effect of pH on polymerization was also investigated. An overall activation energy of 28·62kJmol-1 was obtained over the temperature range 13–43°C. The polymerization is initiated by free radicals and terminated by a combination of monomolecular and bimolecular modes. The cage effect and chain transfer to bisulphite anion are probably both significant. © 1998 SCI.

Zuifang Liu - One of the best experts on this subject based on the ideXlab platform.

  • Kinetic studies of aqueous polymerization of acrylic acid initiated using Potassium Bromate/sodium metabisulphite redox pair
    Polymer International, 1998
    Co-Authors: Zuifang Liu, B W Brooks
    Abstract:

    Aqueous polymerization of acrylic acid was conducted using Potassium Bromate/sodium metabisulphite redox initiators under isothermal conditions. The initial polymerization rates were determined with variation in temperature and in the initial concentrations of acrylic acid, Potassium Bromate and sodium metabisulphite. The effect of pH on polymerization was also investigated. An overall activation energy of 28·62kJmol-1 was obtained over the temperature range 13–43°C. The polymerization is initiated by free radicals and terminated by a combination of monomolecular and bimolecular modes. The cage effect and chain transfer to bisulphite anion are probably both significant. © 1998 SCI.

R.c. Agu - One of the best experts on this subject based on the ideXlab platform.

S. A. Brown - One of the best experts on this subject based on the ideXlab platform.

  • Assessment of bread safety in Nigeria: Quantitative determination of Potassium Bromate and lead
    African Journal of Food Science, 2010
    Co-Authors: Martins Emeje, Sabinus I. Ofoefule, A. C. Nnaji, A. U. Ofoefule, S. A. Brown
    Abstract:

    Potassium Bromate is an additive widely employed by bread makers to improve bread quality. On account of its deleterious effect and carcinogenicity in humans, certain levels of Potassium Bromate are not allowed in bread. Use of Potassium Bromate in bread is banned in many countries including Nigeria. The present evaluation was carried out in eastern part of Nigeria where consumption of bread is high. Twenty-three different brands of breads were sampled. Quality assessment shows that, all the brands contained Potassium Bromate in a quantity that exceeded the minimum allowed by the FDA. In addition, all the sampled breads contained trace amount of lead, a substance which is harmful to health. On the basis of these, all twenty three bread brands sampled were considered unsafe for human consumption and bread makers should be discouraged from using Potassium Bromate as bread improver. Key words:

Yukiko Morii - One of the best experts on this subject based on the ideXlab platform.

  • Polymerization of acrylamide in aqueous medium initiated with a redox system composed of cysteine and Potassium Bromate
    Macromolecular Chemistry and Physics, 1997
    Co-Authors: Takuji Okaya, Kenji Kikuchi, Yukiko Morii
    Abstract:

    Aqueous polymerization of acrylamide initiated with a redox initiator system composed of cysteine and Potassium Bromate was investigated as a model of the redox initiator system composed of poly(vinyl alcohol) having a thiol groups at one end and Potassium Bromate. The rate of polymerization was proportional to almost the square root of cysteine and Potassium Bromate concentration, indicating the initiation system is a usual free radical polymerization initiator. On the other hand, the rate was proportional to the 1.8th power of the monomer concentration. The activation energy of the rate of polymerization was about 5 kcal. mol -1 , indicating also a typical redox initiation system. Chain transfer constant of polyacrylamide radical to cysteine was calculated to be 0.4. From these results, it is concluded that cysteine exerts two important roles: (1) as a reductant of the redox initiation and (2) as a powerful chain transfer reagent.