The Experts below are selected from a list of 8424 Experts worldwide ranked by ideXlab platform
Weisheng Tian - One of the best experts on this subject based on the ideXlab platform.
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Total synthesis of (±)-spiniferin-1 via a polyfluoroalkanosulfonyl fluoride induced homoallylic carbocation Rearrangement Reaction.
Journal of Organic Chemistry, 2011Co-Authors: Kai Ding, Weisheng TianAbstract:A facile total synthesis of marine natural product (±)-spiniferin-1 has been accomplished in eight steps with 28.9% overall yield, involving a Rearrangement Reaction initiated by polyfluoroalkanosulfonyl fluoride to construct the 1,6-methano[10]annulene core of the natural product as a key step.
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Total synthesis of (±)-dihydrospiniferin-1 via a polyfluoro alkanosulfonyl fluoride induced tandem carbonium ion Rearrangement Reaction
Chemical Communications, 2003Co-Authors: Ling Chen, Kai Ding, Weisheng TianAbstract:A novel polyfluoroalkanosulfonyl fluoride induced carbonium ion Rearrangement Reaction of γ-hydroxymethyl cyclohexenone has been used for the total synthesis of (±)dihydrospiniferin 1
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total synthesis of dihydrospiniferin 1 via a polyfluoro alkanosulfonyl fluoride induced tandem carbonium ion Rearrangement Reaction
Chemical Communications, 2003Co-Authors: Ling Chen, Kai Ding, Weisheng TianAbstract:A novel polyfluoroalkanosulfonyl fluoride induced carbonium ion Rearrangement Reaction of γ-hydroxymethyl cyclohexenone has been used for the total synthesis of (±)dihydrospiniferin 1
Ling Chen - One of the best experts on this subject based on the ideXlab platform.
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Total synthesis of (±)-dihydrospiniferin-1 via a polyfluoro alkanosulfonyl fluoride induced tandem carbonium ion Rearrangement Reaction
Chemical Communications, 2003Co-Authors: Ling Chen, Kai Ding, Weisheng TianAbstract:A novel polyfluoroalkanosulfonyl fluoride induced carbonium ion Rearrangement Reaction of γ-hydroxymethyl cyclohexenone has been used for the total synthesis of (±)dihydrospiniferin 1
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total synthesis of dihydrospiniferin 1 via a polyfluoro alkanosulfonyl fluoride induced tandem carbonium ion Rearrangement Reaction
Chemical Communications, 2003Co-Authors: Ling Chen, Kai Ding, Weisheng TianAbstract:A novel polyfluoroalkanosulfonyl fluoride induced carbonium ion Rearrangement Reaction of γ-hydroxymethyl cyclohexenone has been used for the total synthesis of (±)dihydrospiniferin 1
Kai Ding - One of the best experts on this subject based on the ideXlab platform.
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Total synthesis of (±)-spiniferin-1 via a polyfluoroalkanosulfonyl fluoride induced homoallylic carbocation Rearrangement Reaction.
Journal of Organic Chemistry, 2011Co-Authors: Kai Ding, Weisheng TianAbstract:A facile total synthesis of marine natural product (±)-spiniferin-1 has been accomplished in eight steps with 28.9% overall yield, involving a Rearrangement Reaction initiated by polyfluoroalkanosulfonyl fluoride to construct the 1,6-methano[10]annulene core of the natural product as a key step.
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Total synthesis of (±)-dihydrospiniferin-1 via a polyfluoro alkanosulfonyl fluoride induced tandem carbonium ion Rearrangement Reaction
Chemical Communications, 2003Co-Authors: Ling Chen, Kai Ding, Weisheng TianAbstract:A novel polyfluoroalkanosulfonyl fluoride induced carbonium ion Rearrangement Reaction of γ-hydroxymethyl cyclohexenone has been used for the total synthesis of (±)dihydrospiniferin 1
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total synthesis of dihydrospiniferin 1 via a polyfluoro alkanosulfonyl fluoride induced tandem carbonium ion Rearrangement Reaction
Chemical Communications, 2003Co-Authors: Ling Chen, Kai Ding, Weisheng TianAbstract:A novel polyfluoroalkanosulfonyl fluoride induced carbonium ion Rearrangement Reaction of γ-hydroxymethyl cyclohexenone has been used for the total synthesis of (±)dihydrospiniferin 1
Kazunori Tsubaki - One of the best experts on this subject based on the ideXlab platform.
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Formation of Phenalenone Skeleton by an Unusual Rearrangement Reaction
Organic Letters, 2017Co-Authors: Sayaka Sasaki, Eriko Azuma, Takahiro Sasamori, Norihiro Tokitoh, Kouji Kuramochi, Kazunori TsubakiAbstract:The frame Rearrangement Reaction of dinaphthyl ketones, possessing hydroxy groups at appropriate positions, into phenalenone derivatives under acidic conditions was discovered serendipitously. Although this Rearrangement had limited scope, its mechanism was unusual, involving the division of naphthalene rings into one phenalenone ring and one benzene ring. The Reaction mechanism was elucidated by direct determination of intermediate structures using 1H NMR measurements. The generated phenalenones are expected to be key intermediates toward natural products and functional materials.
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synthesis of spiro compounds through tandem oxidative coupling and a framework Rearrangement Reaction
Organic Letters, 2010Co-Authors: Takeo Kawabata, Takahiro Sasamori, N Tokitoh, Kazunori TsubakiAbstract:A highly efficient oxidative coupling of 2-naphthols and a Rearrangement tandem Reaction to afford unique spiro compounds in the presence of FeCl3·6H2O in up to 88% yield have been developed.
John L Wood - One of the best experts on this subject based on the ideXlab platform.
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total synthesis of ingenol
Journal of the American Chemical Society, 2003Co-Authors: Andrew Nickel, Toru Maruyama, Haifeng Tang, Prescott D Murphy, Blake Greene, Naeem Yusuff, John L WoodAbstract:Total synthesis of ingenol, a diterpene isolated from the genus Euphorbia, was accomplished on the basis of the novel key Reactions. The highly strained ingenane skeleton was constructed through an intramolecular cyclization Reaction of an acetylene dicobalt complex followed by a Rearrangement Reaction of an epoxy alcohol. The C(3),C(4),C(5)-triol moiety was introduced by a stereoselective double dihydroxylation Reaction of a diene having C(2)−C(3) and C(4)−C(5) double bonds.