The Experts below are selected from a list of 6 Experts worldwide ranked by ideXlab platform
Jack F. Morgan - One of the best experts on this subject based on the ideXlab platform.
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Organic Reactions - The Preparation of Aromatic Arsonic and Arsinic Acids by the Bart, Bechamp, and Rosenmund Reactions
Organic Reactions, 2011Co-Authors: Cliff S. Hamilton, Jack F. MorganAbstract:Arsonic acids may be regarded as derived from orthoarsenic acid, by replacement of one of the hydroxyl groups with an organic residue, the arsenic acids are similarly derived by replacement of the two hydroxyl groups. The preparation of aromatic arsenic acids is described in this chapter. The most widely used is the Bart Reaction, which involves the interaction of a diazonium salt with an inorganic arsenic compound. Arsenic acids are also obtained as by-products in the Bechamp synthesis. In the Rosenmund synthesis, salts of arsenic acids are obtained by treatment of aryl halides with sodium or potassium arsenite. Keywords: aromatic arsenic acid; arsinic acid; Bart Reaction; Bechamp Reaction; Rosenmund Reaction; limitations; side Reactions; procedures; arsonation
Cliff S. Hamilton - One of the best experts on this subject based on the ideXlab platform.
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Organic Reactions - The Preparation of Aromatic Arsonic and Arsinic Acids by the Bart, Bechamp, and Rosenmund Reactions
Organic Reactions, 2011Co-Authors: Cliff S. Hamilton, Jack F. MorganAbstract:Arsonic acids may be regarded as derived from orthoarsenic acid, by replacement of one of the hydroxyl groups with an organic residue, the arsenic acids are similarly derived by replacement of the two hydroxyl groups. The preparation of aromatic arsenic acids is described in this chapter. The most widely used is the Bart Reaction, which involves the interaction of a diazonium salt with an inorganic arsenic compound. Arsenic acids are also obtained as by-products in the Bechamp synthesis. In the Rosenmund synthesis, salts of arsenic acids are obtained by treatment of aryl halides with sodium or potassium arsenite. Keywords: aromatic arsenic acid; arsinic acid; Bart Reaction; Bechamp Reaction; Rosenmund Reaction; limitations; side Reactions; procedures; arsonation
Joakim Bergman - One of the best experts on this subject based on the ideXlab platform.
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Celebrating 100 years of the Rosenmund Reaction
Nature Catalysis, 2018Co-Authors: Andrei V. Iosub, Carl-johan Wallentin, Joakim BergmanAbstract:This year marks a century since the pioneering work leading to what is now known as the Rosenmund reduction. We celebrate this landmark, reflecting upon the evolution of synthetic methodologies for reductive aldehyde synthesis from carboxylic acid derivatives and highlighting modern, improved strategies.
Andrei V. Iosub - One of the best experts on this subject based on the ideXlab platform.
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Celebrating 100 years of the Rosenmund Reaction
Nature Catalysis, 2018Co-Authors: Andrei V. Iosub, Carl-johan Wallentin, Joakim BergmanAbstract:This year marks a century since the pioneering work leading to what is now known as the Rosenmund reduction. We celebrate this landmark, reflecting upon the evolution of synthetic methodologies for reductive aldehyde synthesis from carboxylic acid derivatives and highlighting modern, improved strategies.
Carl-johan Wallentin - One of the best experts on this subject based on the ideXlab platform.
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Celebrating 100 years of the Rosenmund Reaction
Nature Catalysis, 2018Co-Authors: Andrei V. Iosub, Carl-johan Wallentin, Joakim BergmanAbstract:This year marks a century since the pioneering work leading to what is now known as the Rosenmund reduction. We celebrate this landmark, reflecting upon the evolution of synthetic methodologies for reductive aldehyde synthesis from carboxylic acid derivatives and highlighting modern, improved strategies.