The Experts below are selected from a list of 117 Experts worldwide ranked by ideXlab platform
Youquan Deng - One of the best experts on this subject based on the ideXlab platform.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Shimin Liu, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Liujin Lu, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
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efficient synthesis of dimethyl carbonate via transesterification of ethylene carbonate with methanol over binary zinc Yttrium Oxides
Catalysis Communications, 2011Co-Authors: Liguo Wang, Liujin Lu, Ying Wang, Youquan DengAbstract:Abstract The binary zinc–Yttrium Oxides were prepared by co-precipitation method, characterized and tested in the synthesis of DMC via transesterification of ethylene carbonate with methanol. The catalytic results showed that the catalyst with Zn/Y molar ratio of 3 and calcined at 400 °C exhibited superior catalytic activity, corresponding to TOF of 236 mmol/g cat h. Appropriate content of Yttrium in the catalyst enhanced the catalytic activity remarkably. Moreover, the abundance of medium basic sites (7.2
Peixue Wang - One of the best experts on this subject based on the ideXlab platform.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Shimin Liu, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Liujin Lu, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
Ahmad S Alshammari - One of the best experts on this subject based on the ideXlab platform.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Shimin Liu, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Liujin Lu, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
Benqun Yang - One of the best experts on this subject based on the ideXlab platform.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Shimin Liu, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Liujin Lu, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
Feng Zhou - One of the best experts on this subject based on the ideXlab platform.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Shimin Liu, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
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two step synthesis of dimethyl carbonate from urea ethylene glycol and methanol using acid base bifunctional zinc Yttrium Oxides
Fuel Processing Technology, 2014Co-Authors: Peixue Wang, Feng Zhou, Benqun Yang, Ahmad S Alshammari, Liujin Lu, Youquan DengAbstract:Abstract The binary zinc-Yttrium Oxides with different precursors were prepared by co-precipitation method and used in the catalytic synthesis of dimethyl carbonate (DMC) via a two-step process using urea, ethylene glycol and methanol as raw feed-stocks. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC), and 96% conversion of urea with 98% selectivity of EC was obtained. In the second step, namely transesterification of EC formed with methanol to give DMC and EG, the conversion of EC was up to 72% in 15 min with a 99% selectivity of DMC, corresponding to a TOF of 864 mmol/h g cat . XRD results showed that the catalyst with a zinc nitrate precursor has a remarkable interaction between zinc and Yttrium Oxides. TPD characterization indicated that in the catalyst with a zinc nitrate precursor there was a cooperative effect between weak acid and medium base sites on the surface of the catalyst, suggesting that the prepared catalysts are acid–base bifunctional. The synergistic effect between zinc and Yttrium Oxides, in combination with acidity of zinc oxide and basicity of Yttrium oxide, may be responsible to the high catalytic activity and selectivity.
