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Aldehyde

The Experts below are selected from a list of 74340 Experts worldwide ranked by ideXlab platform

Yuan Xu – One of the best experts on this subject based on the ideXlab platform.

  • synthesis of tert butyl peresters from Aldehydes by bu4ni catalyzed metal free oxidation and its combination with the kharasch sosnovsky reaction
    ChemInform, 2012
    Co-Authors: Chao Zhang, Yuan Xu

    Abstract:

    A new tert-butyl perester synthesis directly from Aldehydes (I) and tert-butyl hydroperoxide (II) is developed via Bu4NI-catalyzed Aldehyde C—H oxidation.

  • synthesis of tert butyl peresters from Aldehydes by bu4ni catalyzed metal free oxidation and its combination with the kharasch sosnovsky reaction
    Chemical Communications, 2011
    Co-Authors: Chao Zhang, Yuan Xu

    Abstract:

    A new tert-butyl peresters synthesis directly from Aldehydes and TBHP was developed viaBu4NI-catalyzed Aldehyde C−H oxidation. Mechanistic studies suggest that the protocol proceeds via a radical process. Combining the method with the Kharasch–Sosnovsky reaction offers a practical approach for the synthesis of allylic esters from simple Aldehydes and alkenesvia a two-step one-pot procedure.

Chao Zhang – One of the best experts on this subject based on the ideXlab platform.

  • synthesis of tert butyl peresters from Aldehydes by bu4ni catalyzed metal free oxidation and its combination with the kharasch sosnovsky reaction
    ChemInform, 2012
    Co-Authors: Chao Zhang, Yuan Xu

    Abstract:

    A new tert-butyl perester synthesis directly from Aldehydes (I) and tert-butyl hydroperoxide (II) is developed via Bu4NI-catalyzed Aldehyde C—H oxidation.

  • synthesis of tert butyl peresters from Aldehydes by bu4ni catalyzed metal free oxidation and its combination with the kharasch sosnovsky reaction
    Chemical Communications, 2011
    Co-Authors: Chao Zhang, Yuan Xu

    Abstract:

    A new tert-butyl peresters synthesis directly from Aldehydes and TBHP was developed viaBu4NI-catalyzed Aldehyde C−H oxidation. Mechanistic studies suggest that the protocol proceeds via a radical process. Combining the method with the Kharasch–Sosnovsky reaction offers a practical approach for the synthesis of allylic esters from simple Aldehydes and alkenesvia a two-step one-pot procedure.

Christian Wolf – One of the best experts on this subject based on the ideXlab platform.

  • metal free one pot oxidative amination of Aldehydes to amides
    Organic Letters, 2007
    Co-Authors: Kekeli Ekouekovi, Christian Wolf

    Abstract:

    Metal-free oxidative amination of aromatic Aldehydes in the presence of TBHP provides convenient access to amides in 85−99% under mild reaction conditions within 5 h. This method avoids free carboxylic acid intermediates and integrates Aldehyde oxidation and amide bond formation, which are usually accomplished separately, into a single operation. Proline-derived amides can be prepared in excellent yields without noticeable racemization.